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Synthesis of 2-Substituted Quinolines via Rhodium(III)-Catalyzed C-H Activation of Imidamides and Coupling with Cyclopropanols
Zhou, Xukai1,2; Qi, Zisong1; Yu, Songjie1; Kong, Lingheng1,2; Li, Yang3; Tian, Wan-Fa3; Li, Xingwei1
关键词C-h Activation C-n Bond Formation Cyclopropanols Imidamides 2-substituted Quinolines
刊名ADVANCED SYNTHESIS & CATALYSIS
2017-05-17
DOI10.1002/adsc.201601278
359页:1620-1625
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Applied ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]N BOND FORMATION ; ONE-POT SYNTHESIS ; INTERNAL ALKYNES ; RING EXPANSION ; OXIME ESTERS ; HETEROCYCLES ; ANNULATION ; METAL ; ARYL ; FUNCTIONALIZATION
英文摘要An efficient synthesis of 2-substituted quinolines from readily available cyclopropanols and imidamides has been developed, where the cyclopropanol acts as a C-3 synthon. With the assistance of a bifunctional imidamide directing group, the reaction occurred via sequential C-H/C-C cleavage and C-C/C-N bond formation.
语种英语
WOS记录号WOS:000401528100003
引用统计
被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/152253
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Xi An Jiao Tong Univ, Frontier Inst Sci & Technol, Ctr Organ Chem, Xian 710054, Peoples R China
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Zhou, Xukai,Qi, Zisong,Yu, Songjie,et al. Synthesis of 2-Substituted Quinolines via Rhodium(III)-Catalyzed C-H Activation of Imidamides and Coupling with Cyclopropanols[J]. ADVANCED SYNTHESIS & CATALYSIS,2017,359:1620-1625.
APA Zhou, Xukai.,Qi, Zisong.,Yu, Songjie.,Kong, Lingheng.,Li, Yang.,...&Li, Xingwei.(2017).Synthesis of 2-Substituted Quinolines via Rhodium(III)-Catalyzed C-H Activation of Imidamides and Coupling with Cyclopropanols.ADVANCED SYNTHESIS & CATALYSIS,359,1620-1625.
MLA Zhou, Xukai,et al."Synthesis of 2-Substituted Quinolines via Rhodium(III)-Catalyzed C-H Activation of Imidamides and Coupling with Cyclopropanols".ADVANCED SYNTHESIS & CATALYSIS 359(2017):1620-1625.
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