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题名: A Fe5C2 nanocatalyst for the preferential synthesis of ethanol via dimethyl oxalate hydrogenation
作者: He, Jia1;  Zhao, Yujun1, 2;  Wang, Yue1;  Wang, Junhu3;  Zheng, Jian2;  Zhang, Hanlei4, 5;  Zhou, Guangwen4, 5;  Wang, Chongmin6;  Wang, Shengping1;  Ma, Xinbin1
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2017-05-14
DOI: 10.1039/c7cc01644a
卷: 53, 页:5376-5379
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: A Fe-based catalyst exhibits extremely high selectivity (89.6%) besides excellent catalytic activity in gas-phase dimethyl oxalate hydrogenation. The ethanol formation occurs via hydrogenation of methyl acetate instead of ethylene glycol over the active species Fe5C2.
关键词[WOS]: FISCHER-TROPSCH SYNTHESIS ;  NANOPARTICLES ;  CATALYSTS ;  SITES
语种: 英语
WOS记录号: WOS:000401118400004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/152261
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Tianjin Univ, Sch Chem Engn & Technol, Collaborat Innovat Ctr Chem Sci & Engn, Key Lab Green Chem Technol,Minist Educ, Tianjin 300072, Peoples R China
2.Pacific Northwest Natl Lab, Inst Integrated Catalysis, Richland, WA 99352 USA
3.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian, Peoples R China
4.SUNY Binghamton, Mat Sci & Engn Program, Binghamton, NY 13902 USA
5.SUNY Binghamton, Dept Mech, Binghamton, NY 13902 USA
6.Pacific Northwest Natl Lab, Environm Mol Sci Lab, Richland, WA 99352 USA

Recommended Citation:
He, Jia,Zhao, Yujun,Wang, Yue,et al. A Fe5C2 nanocatalyst for the preferential synthesis of ethanol via dimethyl oxalate hydrogenation[J]. CHEMICAL COMMUNICATIONS,2017,53:5376-5379.
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