DICP OpenIR
Chiral BINAP-based hierarchical porous polymers as platforms for efficient heterogeneous asymmetric catalysis
Wang, Tao1,3; Lyu, Yuan1; Xiong, Kai4; Wang, Wenlong1; Zheng, Hao5; Zhan, Zhuangping4; Jiang, Zheng5; Ding, Yunjie1,2
关键词(s)-4 Porous Organic Polymers Supported Ruthenium 4'-divinyl-binap (s)-5 Heterogeneous Asymmetric Hydrogenation 5'-divinyl-binap Beta-keto Esters
刊名CHINESE JOURNAL OF CATALYSIS
2017-05-01
DOI10.1016/S1872-2067(17)62826-2
38页:890-898
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]COVALENT ORGANIC FRAMEWORKS ; HYDROGENATION ; LIGAND ; KETONES ; HYDROFORMYLATION ; RHODIUM ; CHALLENGES
英文摘要Two vinyl-functionalized chiral 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) ligands, (S)-4,4'-divinyl-BINAP and (S)-5,5'-divinyl-BINAP, were successfully synthesized. Chiral BINAP-based porous organic polymers (POPs), denoted as 4-BINAP@POPs and 5-BINAP@POPs, were efficiently prepared via the copolymerization of vinyl-functionalized BINAP with divinyl benzene under solvothermal conditions. Thorough characterization using nuclear magnetic resonance spectroscopy, thermogravimetric analysis, extended X-ray absorption fine structure analysis, and high-angle annular dark-field scanning transmission electron microscopy, we confirmed that chiral BINAP groups were successfully incorporated into the structure of the materials considered to contain hierarchical pores. Ru was introduced as a catalytic species into the POPs using different synthetic routes. Systematic investigation of the resultant chiral Ru/POP catalysts for heterogeneous-asymmetric hydrogenation of beta-keto esters revealed their excellent chiral inducibility as well as high activity and stability. Our work thereby paves a path towards the use of advanced hierarchical porous polymers as solid chiral platforms for heterogeneous asymmetric catalysis. (c) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000402346400014
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/152270
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Fujian, Peoples R China
5.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
推荐引用方式
GB/T 7714
Wang, Tao,Lyu, Yuan,Xiong, Kai,et al. Chiral BINAP-based hierarchical porous polymers as platforms for efficient heterogeneous asymmetric catalysis[J]. CHINESE JOURNAL OF CATALYSIS,2017,38:890-898.
APA Wang, Tao.,Lyu, Yuan.,Xiong, Kai.,Wang, Wenlong.,Zheng, Hao.,...&Ding, Yunjie.(2017).Chiral BINAP-based hierarchical porous polymers as platforms for efficient heterogeneous asymmetric catalysis.CHINESE JOURNAL OF CATALYSIS,38,890-898.
MLA Wang, Tao,et al."Chiral BINAP-based hierarchical porous polymers as platforms for efficient heterogeneous asymmetric catalysis".CHINESE JOURNAL OF CATALYSIS 38(2017):890-898.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Wang, Tao]的文章
[Lyu, Yuan]的文章
[Xiong, Kai]的文章
百度学术
百度学术中相似的文章
[Wang, Tao]的文章
[Lyu, Yuan]的文章
[Xiong, Kai]的文章
必应学术
必应学术中相似的文章
[Wang, Tao]的文章
[Lyu, Yuan]的文章
[Xiong, Kai]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。