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题名: Cruciform Electron Acceptors Based on Tetraindeno-Fused Spirofluorene
作者: Xia, Debin1, 2;  Guo, Xin3;  Wagner, Manfred2;  Baumgarten, Martin2;  Schollmeyer, Dieter4;  Muellen, Klaus4
刊名: CRYSTAL GROWTH & DESIGN
发表日期: 2017-05-01
DOI: 10.1021/acs.cgd.7b00272
卷: 17, 页:2816-2821
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Multidisciplinary ;  Crystallography ;  Materials Science, Multidisciplinary
研究领域[WOS]: Chemistry ;  Crystallography ;  Materials Science
英文摘要: Two cruciform tetraindenospirofluorene-based acceptors embedding carbonyl (Spiro-4O) and dicyano-vinylene (Spiro-8CN) functionalities are synthesized in high yields. Single-crystal X-ray analysis reveals a one-dimensional pi-pi stacking arrangement for Spiro-4O, while Spiro-8CN adopts a unique two-dimensional isotropic a-interaction. Cyclic voltammetry suggests a high electron affinity of -3.76 eV for Spiro-8CN. Such a packing motif and low LUMO energy for Spiro-8CN are important for bulk electron transport.
关键词[WOS]: FIELD-EFFECT TRANSISTORS ;  ORGANIC SEMICONDUCTORS ;  BAND-GAP ;  N-TYPE ;  PHOTOVOLTAICS ;  DONOR
语种: 英语
WOS记录号: WOS:000400802500060
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/152318
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Peoples R China
2.Max Planck Inst Polymer Res, Ackermannweg 10, D-55128 Mainz, Germany
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
4.Johannes Gutenberg Univ Mainz, Duesbergweg 10-14, D-55128 Mainz, Germany

Recommended Citation:
Xia, Debin,Guo, Xin,Wagner, Manfred,et al. Cruciform Electron Acceptors Based on Tetraindeno-Fused Spirofluorene[J]. CRYSTAL GROWTH & DESIGN,2017,17:2816-2821.
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