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题名: Synthesis of chiral gamma-sultams through intramolecular reductive amination with sulfonylcarbamate as N-source
作者: Song, Bo1, 2;  Ji, Yue1;  Hu, Shu-Bo1;  Yu, Chang-Bin1;  Zhou, Yong-Gui1
关键词: Palladium ;  Reductive amination ;  Sulfonylcarbamate ;  Chiral gamma-sultams
刊名: TETRAHEDRON LETTERS
发表日期: 2017-04-12
DOI: 10.1016/j.tetlet.2017.03.012
卷: 58, 页:1528-1530
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: An efficient and enantioselective palladium-catalyzed intramolecular asymmetric reductive amination with sulfonylcarbamates as N-sources was reported, providing a facile and general access to the chiral gamma-sultam derivatives with up to 97% of enantioselectivity. This tandem process avoids additional deprotection manipulation and arduous isolation of the N-sulfonyl-imine intermediates. (C) 2017 Elsevier Ltd. All rights reserved.
关键词[WOS]: CATALYZED ASYMMETRIC HYDROGENATION ;  ENANTIOSELECTIVE SYNTHESIS ;  HETEROAROMATIC-COMPOUNDS ;  KETONES ;  ALCOHOLS
语种: 英语
WOS记录号: WOS:000399517600026
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/152320
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Song, Bo,Ji, Yue,Hu, Shu-Bo,et al. Synthesis of chiral gamma-sultams through intramolecular reductive amination with sulfonylcarbamate as N-source[J]. TETRAHEDRON LETTERS,2017,58:1528-1530.
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