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Synthesis of chiral gamma-sultams through intramolecular reductive amination with sulfonylcarbamate as N-source
Song, Bo1,2; Ji, Yue1; Hu, Shu-Bo1; Yu, Chang-Bin1; Zhou, Yong-Gui1
关键词Palladium Reductive Amination Sulfonylcarbamate Chiral Gamma-sultams
刊名TETRAHEDRON LETTERS
2017-04-12
DOI10.1016/j.tetlet.2017.03.012
58页:1528-1530
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]CATALYZED ASYMMETRIC HYDROGENATION ; ENANTIOSELECTIVE SYNTHESIS ; HETEROAROMATIC-COMPOUNDS ; KETONES ; ALCOHOLS
英文摘要An efficient and enantioselective palladium-catalyzed intramolecular asymmetric reductive amination with sulfonylcarbamates as N-sources was reported, providing a facile and general access to the chiral gamma-sultam derivatives with up to 97% of enantioselectivity. This tandem process avoids additional deprotection manipulation and arduous isolation of the N-sulfonyl-imine intermediates. (C) 2017 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000399517600026
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/152320
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Song, Bo,Ji, Yue,Hu, Shu-Bo,et al. Synthesis of chiral gamma-sultams through intramolecular reductive amination with sulfonylcarbamate as N-source[J]. TETRAHEDRON LETTERS,2017,58:1528-1530.
APA Song, Bo,Ji, Yue,Hu, Shu-Bo,Yu, Chang-Bin,&Zhou, Yong-Gui.(2017).Synthesis of chiral gamma-sultams through intramolecular reductive amination with sulfonylcarbamate as N-source.TETRAHEDRON LETTERS,58,1528-1530.
MLA Song, Bo,et al."Synthesis of chiral gamma-sultams through intramolecular reductive amination with sulfonylcarbamate as N-source".TETRAHEDRON LETTERS 58(2017):1528-1530.
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