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Probing the bonding of CO to heteronuclear group 4 metal-nickel clusters by photoelectron spectroscopy
Zou, Jinghan1,2; Xie, Hua1; Yuan, Qinqin1,2; Zhang, Jumei1,2; Dai, Dongxu1; Fan, Hongjun1; Tang, Zichao3; Jiang, Ling1
Source PublicationPHYSICAL CHEMISTRY CHEMICAL PHYSICS
2017-04-21
DOI10.1039/c7cp00171a
Volume19Pages:9790-9797
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS KeywordINFRARED PHOTODISSOCIATION SPECTROSCOPY ; DENSITY-FUNCTIONAL-THEORY ; GAS-PHASE ; CARBONYL CATIONS ; ANIONS ; MOLECULES ; SURFACE ; PHOTOCONVERSION ; DISSOCIATION ; MONOXIDE
AbstractA series of heterobinuclear group 4 metal-nickel carbonyls MNi(CO)(n)(-) (M = Ti, Zr, Hf; n = 3-7) has been generated via a laser vaporization supersonic cluster source and characterized by mass-selected photoelectron velocity-map imaging spectroscopy. Quantum chemical calculations have been carried out to elucidate the geometric and electronic structures and support the spectral assignments. The n = 3 cluster is determined to be capable of simultaneously accommodating three different types of CO bonds (i.e., side-on-bonded, bridging, and terminal modes), resulting in a MNi[eta(2)(mu(2)-C, O)](mu-CO)(CO)(-) structure, which represents the smallest metal carbonyl with the involvement of all the main modes of metal-CO coordination to date. The building block of three bridging CO molecules is favored at n = 4, the structure of which persists up to n = 7. The additional CO ligands are bonded terminally to the metal atoms. The present findings provide important new insight into the structure and bonding mechanisms of CO molecules with heteronuclear transition metals, which would have important implications for understanding chemisorbed CO molecules on alloy surfaces.
Language英语
WOS IDWOS:000399383100011
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/152325
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy & Mat iChEM, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
3.Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
Recommended Citation
GB/T 7714
Zou, Jinghan,Xie, Hua,Yuan, Qinqin,et al. Probing the bonding of CO to heteronuclear group 4 metal-nickel clusters by photoelectron spectroscopy[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2017,19:9790-9797.
APA Zou, Jinghan.,Xie, Hua.,Yuan, Qinqin.,Zhang, Jumei.,Dai, Dongxu.,...&Jiang, Ling.(2017).Probing the bonding of CO to heteronuclear group 4 metal-nickel clusters by photoelectron spectroscopy.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,19,9790-9797.
MLA Zou, Jinghan,et al."Probing the bonding of CO to heteronuclear group 4 metal-nickel clusters by photoelectron spectroscopy".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 19(2017):9790-9797.
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