DICP OpenIR
Mild Redox-Neutral Depolymerization of Lignin with a Binuclear Rh Complex in Water
Liu, Yuxuan1,2; Li, Changzhi2,4; Miao, Wang1; Tang, Weijun1; Xue, Dong1; Li, Chaoqun1; Zhang, Bo2; Xiao, Jianliang1,3; Wang, Aiqin2,4; Zhang, Tao2; Wang, Chao1
Corresponding AuthorLi, Changzhi(licz@dicp.ac.cn) ; Wang, Chao(c.wang@snnu.edu.cn)
Keywordlignin depolymerization redox-neutral rhodium complex lignin-first biorefinery aqueous reaction
Source PublicationACS CATALYSIS
2019-05-01
ISSN2155-5435
DOI10.1021/acscatal.9b00669
Volume9Issue:5Pages:4441-4447
Funding Project2017 Royal Society International Collaboration Award[IC170044] ; National Natural Science Foundation of China[21773145] ; National Natural Science Foundation of China[21473109] ; National Natural Science Foundation of China[21690080] ; National Natural Science Foundation of China[21690083] ; National Natural Science Foundation of China[21878288] ; Science and Technology Program of Shaanxi Province[2016KJXX-26] ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University[16QNGG008] ; 111 project[B14041] ; Fundamental Research Funds for the Central Universities[GK201803079] ; DNL cooperation fund CAS[DNL180302]
Funding Organization2017 Royal Society International Collaboration Award ; 2017 Royal Society International Collaboration Award ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Program of Shaanxi Province ; Science and Technology Program of Shaanxi Province ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; 111 project ; 111 project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; DNL cooperation fund CAS ; DNL cooperation fund CAS ; 2017 Royal Society International Collaboration Award ; 2017 Royal Society International Collaboration Award ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Program of Shaanxi Province ; Science and Technology Program of Shaanxi Province ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; 111 project ; 111 project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; DNL cooperation fund CAS ; DNL cooperation fund CAS ; 2017 Royal Society International Collaboration Award ; 2017 Royal Society International Collaboration Award ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Program of Shaanxi Province ; Science and Technology Program of Shaanxi Province ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; 111 project ; 111 project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; DNL cooperation fund CAS ; DNL cooperation fund CAS ; 2017 Royal Society International Collaboration Award ; 2017 Royal Society International Collaboration Award ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Program of Shaanxi Province ; Science and Technology Program of Shaanxi Province ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; 111 project ; 111 project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; DNL cooperation fund CAS ; DNL cooperation fund CAS
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordO BOND-CLEAVAGE ; HYDROGEN TRANSFER HYDROGENOLYSIS ; AEROBIC OXIDATION ; SELECTIVE OXIDATION ; BETA-O-4 LINKAGES ; ALCOHOL OXIDATION ; MODEL COMPOUNDS ; C-C ; CONVERSION ; CATALYST
AbstractA mild redox-neutral lignin depolymerization system featuring a water-soluble binuclear Rh complex has been developed. The catalytic system could be successfully applied to the depolymerization of a lignin-like polymer, alkaline lignin, as well as raw lignocellulose samples to produce aromatic ketones, providing a homogeneous catalytic system for "lignin-first" biorefinery in water. Mechanistic studies on the model substrate suggest that the reaction proceeds via a metal-catalyzed dehydrogenation step to afford a carbonyl intermediate, followed by C-O bond cleavage to afford ketone and phenol products. Deuterium labeling study shows that the hydrogen used for cleavage of the C-O bond originates from the alcohol moiety in the substrate.
Language英语
Funding Organization2017 Royal Society International Collaboration Award ; 2017 Royal Society International Collaboration Award ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Program of Shaanxi Province ; Science and Technology Program of Shaanxi Province ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; 111 project ; 111 project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; DNL cooperation fund CAS ; DNL cooperation fund CAS ; 2017 Royal Society International Collaboration Award ; 2017 Royal Society International Collaboration Award ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Program of Shaanxi Province ; Science and Technology Program of Shaanxi Province ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; 111 project ; 111 project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; DNL cooperation fund CAS ; DNL cooperation fund CAS ; 2017 Royal Society International Collaboration Award ; 2017 Royal Society International Collaboration Award ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Program of Shaanxi Province ; Science and Technology Program of Shaanxi Province ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; 111 project ; 111 project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; DNL cooperation fund CAS ; DNL cooperation fund CAS ; 2017 Royal Society International Collaboration Award ; 2017 Royal Society International Collaboration Award ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Program of Shaanxi Province ; Science and Technology Program of Shaanxi Province ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; Projects for the Academic Leaders and Academic Backbones, Shaanxi Normal University ; 111 project ; 111 project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; DNL cooperation fund CAS ; DNL cooperation fund CAS
WOS IDWOS:000467335600067
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165453
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Changzhi; Wang, Chao
Affiliation1.Shaanxi Normal Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710062, Shaanxi, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
4.Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Liu, Yuxuan,Li, Changzhi,Miao, Wang,et al. Mild Redox-Neutral Depolymerization of Lignin with a Binuclear Rh Complex in Water[J]. ACS CATALYSIS,2019,9(5):4441-4447.
APA Liu, Yuxuan.,Li, Changzhi.,Miao, Wang.,Tang, Weijun.,Xue, Dong.,...&Wang, Chao.(2019).Mild Redox-Neutral Depolymerization of Lignin with a Binuclear Rh Complex in Water.ACS CATALYSIS,9(5),4441-4447.
MLA Liu, Yuxuan,et al."Mild Redox-Neutral Depolymerization of Lignin with a Binuclear Rh Complex in Water".ACS CATALYSIS 9.5(2019):4441-4447.
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