DICP OpenIR
Fast fabrication of a hybrid monolithic column containing cyclic and aliphatic hydrophobic ligands via photo-initiated thiol-ene polymerization
Wang, Yan1,2; Ma, Shujuan1,2; Zhang, Luwei1,2; Zhang, Na1,3; Li, Yanan1,3; Ou, Junjie1; Shen, Yehua2; Ye, Mingliang1
Corresponding AuthorOu, Junjie(junjieou@dicp.ac.cn) ; Shen, Yehua(yhshen@nwu.edu.cn)
Keywordcapillary liquid chromatography click chemistry hybrid monolithic column
Source PublicationJOURNAL OF SEPARATION SCIENCE
2019-04-01
ISSN1615-9306
DOI10.1002/jssc.201801033
Volume42Issue:7Pages:1332-1340
Funding ProjectChina State Key Basic Research Program Grant[2016YFA0501402] ; National Science Fund for Distinguished Young Scholars[21525524] ; National Natural Sciences Foundation of China[21575141] ; CAS Weigao Research & Development Program[[2017]-009]
Funding OrganizationChina State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS Weigao Research & Development Program ; CAS Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS Weigao Research & Development Program ; CAS Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS Weigao Research & Development Program ; CAS Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS Weigao Research & Development Program ; CAS Weigao Research & Development Program
WOS SubjectChemistry, Analytical
WOS Research AreaChemistry
WOS KeywordPOLYHEDRAL OLIGOMERIC SILSESQUIOXANE ; RING-OPENING POLYMERIZATION ; CLICK CHEMISTRY ; PHOTOPOLYMERIZATION ; PERFORMANCE ; IMPACT
AbstractThree monomers, octakis (3-mercaptopropyl) octasilsesquioxane, 1,2,4-trivinylcyclohexane and isophytol were employed to synthesize a novel monolithic stationary phase via photo-initiated thiol-ene click polymerization for reversed-phase liquid chromatography. Several factors such as porogenic system, reaction time and the molar ratio of functional groups were investigated in detail. The resulting poly(POSS-co-TVCH-co-isophytol) monolithic column exhibited suitable permeability for fast separation and outstanding thermal stability. Five alkylbenzenes were employed to evaluate the ability of chromatographic separation of the resulting monolithic columns at different flow rates, and showed the highest column efficiencies of 90,200-93,100 N/m (corresponding to 10.4-10.6 mu m of plate height) at a velocity of 0.41 mm/s. The baseline separations of five anilines and eight phenols further proved the applicability of poly(POSS-co-TVCH-co-isophytol) monolithic column in the separation of small molecules.
Language英语
Funding OrganizationChina State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS Weigao Research & Development Program ; CAS Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS Weigao Research & Development Program ; CAS Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS Weigao Research & Development Program ; CAS Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS Weigao Research & Development Program ; CAS Weigao Research & Development Program
WOS IDWOS:000466423100004
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165535
Collection中国科学院大连化学物理研究所
Corresponding AuthorOu, Junjie; Shen, Yehua
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China
2.Northwest Univ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian, Shaanxi, Peoples R China
3.Univ Chinese Acad Sci, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Wang, Yan,Ma, Shujuan,Zhang, Luwei,et al. Fast fabrication of a hybrid monolithic column containing cyclic and aliphatic hydrophobic ligands via photo-initiated thiol-ene polymerization[J]. JOURNAL OF SEPARATION SCIENCE,2019,42(7):1332-1340.
APA Wang, Yan.,Ma, Shujuan.,Zhang, Luwei.,Zhang, Na.,Li, Yanan.,...&Ye, Mingliang.(2019).Fast fabrication of a hybrid monolithic column containing cyclic and aliphatic hydrophobic ligands via photo-initiated thiol-ene polymerization.JOURNAL OF SEPARATION SCIENCE,42(7),1332-1340.
MLA Wang, Yan,et al."Fast fabrication of a hybrid monolithic column containing cyclic and aliphatic hydrophobic ligands via photo-initiated thiol-ene polymerization".JOURNAL OF SEPARATION SCIENCE 42.7(2019):1332-1340.
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