DICP OpenIR
Catalytic selective hydrogenation and rearrangement of 5-hydroxymethylfurfural to 3-hydroxymethyl-cyclopentone over a bimetallic nickel-copper catalyst in water
Zhang, Shujing1,2; Ma, Hong1; Sun, Yuxia1,2; Luo, Yang1,2; Liu, Xin1,2; Zhang, Meiyun1,2; Gao, Jin1; Xu, Jie1
Corresponding AuthorMa, Hong(mahong@dicp.ac.cn) ; Xu, Jie(xujie@dicp.ac.cn)
Source PublicationGREEN CHEMISTRY
2019-04-07
ISSN1463-9262
DOI10.1039/c8gc04009e
Volume21Issue:7Pages:1702-1709
Funding ProjectNational Natural Science Foundation of China[21790331] ; National Natural Science Foundation of China[21872138] ; National Natural Science Foundation of China[21690084] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21030400] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020300]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences
WOS SubjectChemistry, Multidisciplinary ; Green & Sustainable Science & Technology
WOS Research AreaChemistry ; Science & Technology - Other Topics
WOS KeywordAEROBIC OXIDATION ; RING-REARRANGEMENT ; CONVERSION ; CARBON ; HYDROGENOLYSIS ; CYCLOPENTANONE ; FRUCTOSE ; COBALT ; HMF ; 2,5-HEXANEDIONE
AbstractThe selective hydrogenation and rearrangement of 5-hydroxymethylfurfural (5-HMF) to 3-hydroxymethyl-cyclopentone (HCPN) were studied over a MOF-derived bimetallic nickel-copper catalyst in water. The combination of nickel and copper dramatically improved the efficiency in both the selective hydrogenation of the carbonyl group of 5-HMF and the hydrogenative ring-rearrangement of the C5 ring, affording 70.3% yield for HCPN and 99.8% yield for the rearrangement products. Moreover, it was indicated that water acted as a solvent, reactant, and proton donor by dissociation at an elevated temperature, which supplied slightly acidic conditions and promoted the rearrangement reaction.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences
WOS IDWOS:000464318800012
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165543
Collection中国科学院大连化学物理研究所
Corresponding AuthorMa, Hong; Xu, Jie
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Shujing,Ma, Hong,Sun, Yuxia,et al. Catalytic selective hydrogenation and rearrangement of 5-hydroxymethylfurfural to 3-hydroxymethyl-cyclopentone over a bimetallic nickel-copper catalyst in water[J]. GREEN CHEMISTRY,2019,21(7):1702-1709.
APA Zhang, Shujing.,Ma, Hong.,Sun, Yuxia.,Luo, Yang.,Liu, Xin.,...&Xu, Jie.(2019).Catalytic selective hydrogenation and rearrangement of 5-hydroxymethylfurfural to 3-hydroxymethyl-cyclopentone over a bimetallic nickel-copper catalyst in water.GREEN CHEMISTRY,21(7),1702-1709.
MLA Zhang, Shujing,et al."Catalytic selective hydrogenation and rearrangement of 5-hydroxymethylfurfural to 3-hydroxymethyl-cyclopentone over a bimetallic nickel-copper catalyst in water".GREEN CHEMISTRY 21.7(2019):1702-1709.
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