DICP OpenIR
Access to green primary explosives via constructing coordination polymers based on bis-tetrazole oxide and non-lead metals
Zhang, Qi1; Chen, Dong1; Jing, Dong2; Fan, Guijuan1; He, Liu1; Li, Hongzhen1; Wang, Wentao3; Nie, Fude1
Corresponding AuthorZhang, Qi(jackzhang531@caep.cn) ; Wang, Wentao()
Source PublicationGREEN CHEMISTRY
2019-04-21
ISSN1463-9262
DOI10.1039/c8gc03973a
Volume21Issue:8Pages:1947-1955
Funding ProjectNational Natural Science Foundation of China[21302176] ; National Natural Science Foundation of China[21672210] ; National Natural Science Foundation of China[11302200] ; Development Foundation of CAEP[2013B0302038]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Development Foundation of CAEP ; Development Foundation of CAEP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Development Foundation of CAEP ; Development Foundation of CAEP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Development Foundation of CAEP ; Development Foundation of CAEP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Development Foundation of CAEP ; Development Foundation of CAEP
WOS SubjectChemistry, Multidisciplinary ; Green & Sustainable Science & Technology
WOS Research AreaChemistry ; Science & Technology - Other Topics
WOS KeywordHIGH-ENERGY-DENSITY ; ORGANIC FRAMEWORKS ; CRYSTAL PACKING ; DETONATION ; SENSITIVITY ; SAFER ; MOFS
AbstractAn environmentally friendly method to prepare new-generation green primary explosives with excellent performances has been developed on the basis of a coordination chemistry strategy. In the present work, constructing energetic coordination polymers (ECPs) based on tetrazole oxide 1H, 1' H-[ 5,5'-bitetrazole]1,1'- diol (H2BTO) with non-heavy metal cations Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) led to five novel green primary explosives without metal ion and organic pollution. Systematic research is conducted to prove these green ECPs as a novel class of lead-free primary explosives. For example, a thermal stability experiment shows that their thermal decomposition temperatures are all beyond 200 degrees C, while the thermalresistance experiment demonstrates that compounds 1 and 5 can maintain long-term stability under 100 degrees C. And the results based on sensitivity tests and detonation parameter simulation reveal that all these compounds possess excellent detonation and safety properties, far outperforming classical primary explosives such as lead azide. Moreover, a modified Koenen test has been conducted to characterize the explosion capacity of these ECPs and by this method compounds 1, 2, 3, and 5 were demonstrated with fast deflagration-to-detonation transition ability.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Development Foundation of CAEP ; Development Foundation of CAEP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Development Foundation of CAEP ; Development Foundation of CAEP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Development Foundation of CAEP ; Development Foundation of CAEP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Development Foundation of CAEP ; Development Foundation of CAEP
WOS IDWOS:000465398000033
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165557
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhang, Qi; Wang, Wentao
Affiliation1.China Acad Engn Phys, Inst Chem Mat, Mianyang 621900, Sichuan, Peoples R China
2.Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Qi,Chen, Dong,Jing, Dong,et al. Access to green primary explosives via constructing coordination polymers based on bis-tetrazole oxide and non-lead metals[J]. GREEN CHEMISTRY,2019,21(8):1947-1955.
APA Zhang, Qi.,Chen, Dong.,Jing, Dong.,Fan, Guijuan.,He, Liu.,...&Nie, Fude.(2019).Access to green primary explosives via constructing coordination polymers based on bis-tetrazole oxide and non-lead metals.GREEN CHEMISTRY,21(8),1947-1955.
MLA Zhang, Qi,et al."Access to green primary explosives via constructing coordination polymers based on bis-tetrazole oxide and non-lead metals".GREEN CHEMISTRY 21.8(2019):1947-1955.
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