DICP OpenIR
Chemoselectivity of Pristine Cellulose Nanocrystal Films Driven by Carbohydrate-Carbohydrate Interactions
Zhang, Fusheng1; Wang, Dongdong1; Qin, Haijuan2; Feng, Liang1; Liang, Xinmiao1; Qing, Guangyan1
Corresponding AuthorLiang, Xinmiao(liangxm@dicp.ac.cn) ; Qing, Guangyan(qinggy@dicp.ac.cn)
Keywordcellulose nanocrystal saccharides color variation hydrogen bond mesoporous carbon
Source PublicationACS APPLIED MATERIALS & INTERFACES
2019-04-10
ISSN1944-8244
DOI10.1021/acsami.9b00471
Volume11Issue:14Pages:13114-13122
Funding ProjectNational Natural Science Foundation of China[51473131] ; National Natural Science Foundation of China[51533007] ; National Natural Science Foundation of China[21775116] ; DICP Innovation Funding[DICP-RC201801] ; Wuhan Morning Light Plan of Youth Science and Technology
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP Innovation Funding ; DICP Innovation Funding ; Wuhan Morning Light Plan of Youth Science and Technology ; Wuhan Morning Light Plan of Youth Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP Innovation Funding ; DICP Innovation Funding ; Wuhan Morning Light Plan of Youth Science and Technology ; Wuhan Morning Light Plan of Youth Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP Innovation Funding ; DICP Innovation Funding ; Wuhan Morning Light Plan of Youth Science and Technology ; Wuhan Morning Light Plan of Youth Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP Innovation Funding ; DICP Innovation Funding ; Wuhan Morning Light Plan of Youth Science and Technology ; Wuhan Morning Light Plan of Youth Science and Technology
WOS SubjectNanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS Research AreaScience & Technology - Other Topics ; Materials Science
WOS KeywordRECOGNITION ; POLYMER ; COLOR ; OLIGOSACCHARIDES ; SEPARATION ; PHASE
AbstractBiological photonic nanostructures comprising a hierarchically self-assembled cellulose nanocrystal (CNC) have been exploited for the development of sensing, optoelectronics, and energy materials. Although multiple techniques are used for controlling the optical response and chiral nematic structure of CNC-derived materials, the presence of external studies that pristine CNC has chemoselectivity is not yet reported to implement this destination. Here, we report that the CNC film without modification shows a high optical sensitivity for glucose through color variation from blue to red. Moreover, various glucose homologs or analogs that only differ in terms of the orientation of a hydroxyl group are selectively distinguished through the naked eye. The excellent chemoselectivity of CNC is attributed to carbohydrate-carbohydrate selective hydrogen-bonding interactions. Close binding with glucose induces the rearrangement of a CNC chain and strengthens the repulsive interaction, thus increasing the helical pitch of the chiral nematic structure of the CNC film and changing its macroscopic color. This CNC chemoselectivity presents an unprecedented control of chiral nematic mesoporous carbon through monosaccharide species. The results provide a simple but highly efficient method to tune the optical and structural properties of CNC nanomaterials and to apply them for practical biosensors, chiral separation, and energy applications.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP Innovation Funding ; DICP Innovation Funding ; Wuhan Morning Light Plan of Youth Science and Technology ; Wuhan Morning Light Plan of Youth Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP Innovation Funding ; DICP Innovation Funding ; Wuhan Morning Light Plan of Youth Science and Technology ; Wuhan Morning Light Plan of Youth Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP Innovation Funding ; DICP Innovation Funding ; Wuhan Morning Light Plan of Youth Science and Technology ; Wuhan Morning Light Plan of Youth Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP Innovation Funding ; DICP Innovation Funding ; Wuhan Morning Light Plan of Youth Science and Technology ; Wuhan Morning Light Plan of Youth Science and Technology
WOS IDWOS:000464769400007
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165559
Collection中国科学院大连化学物理研究所
Corresponding AuthorLiang, Xinmiao; Qing, Guangyan
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Tianjin Univ Sci & Technol, Res Ctr Modern Analyt Technol, 26 Yingkou Rd, Tianjin 300000, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Fusheng,Wang, Dongdong,Qin, Haijuan,et al. Chemoselectivity of Pristine Cellulose Nanocrystal Films Driven by Carbohydrate-Carbohydrate Interactions[J]. ACS APPLIED MATERIALS & INTERFACES,2019,11(14):13114-13122.
APA Zhang, Fusheng,Wang, Dongdong,Qin, Haijuan,Feng, Liang,Liang, Xinmiao,&Qing, Guangyan.(2019).Chemoselectivity of Pristine Cellulose Nanocrystal Films Driven by Carbohydrate-Carbohydrate Interactions.ACS APPLIED MATERIALS & INTERFACES,11(14),13114-13122.
MLA Zhang, Fusheng,et al."Chemoselectivity of Pristine Cellulose Nanocrystal Films Driven by Carbohydrate-Carbohydrate Interactions".ACS APPLIED MATERIALS & INTERFACES 11.14(2019):13114-13122.
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