DICP OpenIR
Fabrication of Hydrazone-Linked Covalent Organic Frameworks Using Alkyl Amine as Building Block for High Adsorption Capacity of Metal Ions
Li, Ya1,2; Wang, Chang1; Ma, Shujuan1,2; Zhang, Haiyang1,2; Ou, Junjie1; Wei, Yinmao2; Ye, Mingliang1
Corresponding AuthorOu, Junjie(junjieou@dicp.ac.cn) ; Wei, Yinmao(ymwei@nwu.edu.cn)
Keywordflexible alkyl amine covalent organic frameworks intramolecular hydrogen bonding metal ions adsorption high capacity selectivity adsorption
Source PublicationACS APPLIED MATERIALS & INTERFACES
2019-03-27
ISSN1944-8244
DOI10.1021/acsami.8b18502
Volume11Issue:12Pages:11706-11714
Funding ProjectChina State Key Basic Research Program Grant[2016YFA0501402] ; National Science Fund for Distinguished Young Scholars[21525524] ; National Natural Sciences Foundation of China[21575141] ; CAS-Weigao Research & Development Program[[2017]-009]
Funding OrganizationChina State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program
WOS SubjectNanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS Research AreaScience & Technology - Other Topics ; Materials Science
WOS KeywordAQUEOUS-SOLUTIONS ; CRYSTALLINE ; REMOVAL ; EFFICIENT ; CU2+ ; HYDROGEN ; PB(II) ; CD2+ ; CONSTRUCTION ; NANOSHEETS
AbstractThere are several researches on the preparation and application of hydrazone-linked covalent organic frameworks (COFs), and all of them generally necessitate rigid aromatic amines. Herein, we report a strategy for design and synthesis of COF with flexible alkyl amine as a building block and intramolecular hydrogen bonding as a knot in the network. The proof-of-concept design was demonstrated by exploring 1,3,5-triformylphloroglucinol and oxalyldihydrazide (ODH) as precursors to synthesize a novel COF material (TpODH), in which different organic building units are combined through hydrazone bonds to form two-dimensional porous frameworks. It should be pointed that irreversible enol-to-keto tautomerism and intramolecular N-H center dot center dot center dot O=C hydrogen bonding of TpODH would enhance the crystallinity and chemical stability, leading to large specific surface area of 835 m(2) g(-1). However, another COF synthesized with 1,3,5-triformylbenzene and ODH exhibited less crystallinity and low special surface area (94 m(2) g(-1)). Representatively, the resulting TpODH afforded Cu(II) and Hg(II) capacities of 324 and 1692 mg g(-1), respectively, which exceeded that of most COFs previously reported. Moreover, the Fourier-transform infrared and X-ray photoelectron spectroscopy spectra analyses were taken to demonstrate the adsorption mechanism. These results suggested that the materials could be applied to the removal of metallic ions in the future.
Language英语
Funding OrganizationChina State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program
WOS IDWOS:000462950600067
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165565
Collection中国科学院大连化学物理研究所
Corresponding AuthorOu, Junjie; Wei, Yinmao
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China
2.Northwest Univ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian 710069, Shaanxi, Peoples R China
Recommended Citation
GB/T 7714
Li, Ya,Wang, Chang,Ma, Shujuan,et al. Fabrication of Hydrazone-Linked Covalent Organic Frameworks Using Alkyl Amine as Building Block for High Adsorption Capacity of Metal Ions[J]. ACS APPLIED MATERIALS & INTERFACES,2019,11(12):11706-11714.
APA Li, Ya.,Wang, Chang.,Ma, Shujuan.,Zhang, Haiyang.,Ou, Junjie.,...&Ye, Mingliang.(2019).Fabrication of Hydrazone-Linked Covalent Organic Frameworks Using Alkyl Amine as Building Block for High Adsorption Capacity of Metal Ions.ACS APPLIED MATERIALS & INTERFACES,11(12),11706-11714.
MLA Li, Ya,et al."Fabrication of Hydrazone-Linked Covalent Organic Frameworks Using Alkyl Amine as Building Block for High Adsorption Capacity of Metal Ions".ACS APPLIED MATERIALS & INTERFACES 11.12(2019):11706-11714.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Li, Ya]'s Articles
[Wang, Chang]'s Articles
[Ma, Shujuan]'s Articles
Baidu academic
Similar articles in Baidu academic
[Li, Ya]'s Articles
[Wang, Chang]'s Articles
[Ma, Shujuan]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Li, Ya]'s Articles
[Wang, Chang]'s Articles
[Ma, Shujuan]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.