DICP OpenIR
Selective photoelectrochemical oxidation of glycerol to high value-added dihydroxyacetone
Liu, Dong1; Liu, Jin-Cheng2,3; Cai, Weizheng1; Ma, Jun4; Yang, Hong Bin1,5; Xiao, Hai2,3; Li, Jun2,3; Xiong, Yujie4; Huang, Yanqiang6; Liu, Bin1
Corresponding AuthorXiao, Hai(haixiao@tsinghua.edu.cn) ; Xiong, Yujie(yjxiong@ustc.edu.cn) ; Liu, Bin(liubin@ntu.edu.sg)
Source PublicationNATURE COMMUNICATIONS
2019-04-16
ISSN2041-1723
DOI10.1038/s41467-019-09788-5
Volume10Pages:8
Funding ProjectSingapore Ministry of Education[RG115/18] ; Singapore Ministry of Education[RG115/17] ; Singapore Ministry of Education[RG9/17] ; Singapore Ministry of Education[MOE2016-T2-2-004] ; National Key Projects for Fundamental Research and Development of China[2017YFA0207301] ; National Key Projects for Fundamental Research and Development of China[2016YFA0202804] ; Strategic Priority Research Programme of the Chinese Academy of Sciences[XDB17020400] ; National Nature Science Foundation of China[21725102]
Funding OrganizationSingapore Ministry of Education ; Singapore Ministry of Education ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Singapore Ministry of Education ; Singapore Ministry of Education ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Singapore Ministry of Education ; Singapore Ministry of Education ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Singapore Ministry of Education ; Singapore Ministry of Education ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; National Nature Science Foundation of China
WOS SubjectMultidisciplinary Sciences
WOS Research AreaScience & Technology - Other Topics
WOS KeywordTOTAL-ENERGY CALCULATIONS ; ELECTROCATALYTIC OXIDATION ; WATER OXIDATION ; ELECTROOXIDATION ; BIODIESEL ; CATALYSTS ; CONVERSION ; CHEMICALS ; PLATINUM ; MECHANISM
AbstractIt is highly profitable to transform glycerol - the main by-product from biodiesel production to high value-added chemicals. In this work, we develop a photoelectrochemical system based on nanoporous BiVO4 for selective oxidation of glycerol to 1,3-dihydroxyacetone - one of the most valuable derivatives of glycerol. Under AM 1.5G front illumination (100 mW cm(-2)) in an acidic medium (pH = 2) without adscititious oxidant, the nanoporous BiVO4 photoanode achieves a glycerol oxidation photocurrent density of 3.7 mA cm(-2) at a potential of 1.2 V versus RHE with 51% 1,3-dihydroxyacetone selectivity, equivalent to a production rate of 200 mmol of 1,3-dihydroxyacetone per m(2) of illumination area in one hour.
Language英语
Funding OrganizationSingapore Ministry of Education ; Singapore Ministry of Education ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Singapore Ministry of Education ; Singapore Ministry of Education ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Singapore Ministry of Education ; Singapore Ministry of Education ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Singapore Ministry of Education ; Singapore Ministry of Education ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; Strategic Priority Research Programme of the Chinese Academy of Sciences ; National Nature Science Foundation of China ; National Nature Science Foundation of China
WOS IDWOS:000464654700018
PublisherNATURE PUBLISHING GROUP
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165575
Collection中国科学院大连化学物理研究所
Corresponding AuthorXiao, Hai; Xiong, Yujie; Liu, Bin
Affiliation1.Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore
2.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
3.Tsinghua Univ, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China
4.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Sch Chem & Mat Sci, Collaborat Innovat Ctr Chem Energy Mat iChEM, Hefei 230026, Anhui, Peoples R China
5.Suzhou Univ Sci & Technol, Inst Mat Sci & Devices, Suzhou 215009, Peoples R China
6.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Liu, Dong,Liu, Jin-Cheng,Cai, Weizheng,et al. Selective photoelectrochemical oxidation of glycerol to high value-added dihydroxyacetone[J]. NATURE COMMUNICATIONS,2019,10:8.
APA Liu, Dong.,Liu, Jin-Cheng.,Cai, Weizheng.,Ma, Jun.,Yang, Hong Bin.,...&Liu, Bin.(2019).Selective photoelectrochemical oxidation of glycerol to high value-added dihydroxyacetone.NATURE COMMUNICATIONS,10,8.
MLA Liu, Dong,et al."Selective photoelectrochemical oxidation of glycerol to high value-added dihydroxyacetone".NATURE COMMUNICATIONS 10(2019):8.
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