DICP OpenIR
Ligand-Mediated Reactivity in CO Oxidation of Niobium-Nickel Monoxide Carbonyl Complexes: The Crucial Roles of the Multiple Adsorption of CO Molecules
Zhang, Jumei1,3; Li, Ya2; Liu, Zhiling2; Li, Gang1; Fan, Hongjun1; Jiang, Ling1; Xie, Hua1
Corresponding AuthorLiu, Zhiling(lzling@sxnu.edu.cn) ; Jiang, Ling(Ijiang@dicp.ac.cn) ; Xie, Hua(xiehua@dicp.ac.cn)
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY LETTERS
2019-04-04
ISSN1948-7185
DOI10.1021/acs.jpclett.9b00205
Volume10Issue:7Pages:1566-1573
Funding ProjectNational Natural Science Foundation of China[21603130] ; National Natural Science Foundation of China[21673231] ; National Natural Science Foundation of China[21688102] ; National Natural Science Foundation of China[21873097] ; Key Research Program[KGZD-EW-T05] ; Strategic Priority Research Program of the Chinese Academy of Science[XDB17000000]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program ; Key Research Program ; Strategic Priority Research Program of the Chinese Academy of Science ; Strategic Priority Research Program of the Chinese Academy of Science ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program ; Key Research Program ; Strategic Priority Research Program of the Chinese Academy of Science ; Strategic Priority Research Program of the Chinese Academy of Science ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program ; Key Research Program ; Strategic Priority Research Program of the Chinese Academy of Science ; Strategic Priority Research Program of the Chinese Academy of Science ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program ; Key Research Program ; Strategic Priority Research Program of the Chinese Academy of Science ; Strategic Priority Research Program of the Chinese Academy of Science
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS KeywordLOW-TEMPERATURE OXIDATION ; OXIDE CLUSTERS ; CHARGE-STATE ; BASIS-SETS ; GOLD ; ANIONS ; CHEMISTRY ; CATALYSIS ; STOICHIOMETRY ; INSIGHTS
AbstractThe heteronuclear metal oxide complexes are of great significance in heterogeneous catalytic oxidation of CO. However, previous studies are mainly focused on the composition of metal oxide, charge state, the support and the active oxygen species, with little attention paid to adsorbed CO ligands. Herein, the ligand-mediated reactivity in CO oxidation of niobium-nickel monoxide carbonyl complexes has been successfully identified. The NbNiO(CO)(n)(-) (n = 5-6) anions are determined to be O-bridged complexes. In contrast, the NbNiO(CO)(n)(-) (n = 7-8) anions are characterized to be eta(2)-CO2-tagged complexes. The crucial roles of the multiply adsorbed CO molecules that can facilitate not only the competitive binding with bridging oxygen atom to the transition metal centers but also the electron accumulation of transition metal atoms have been discovered. The fascinating results are of substantial importance to understand the mechanisms of CO oxidation over heteronuclear metal oxide under CO-rich feed condition.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program ; Key Research Program ; Strategic Priority Research Program of the Chinese Academy of Science ; Strategic Priority Research Program of the Chinese Academy of Science ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program ; Key Research Program ; Strategic Priority Research Program of the Chinese Academy of Science ; Strategic Priority Research Program of the Chinese Academy of Science ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program ; Key Research Program ; Strategic Priority Research Program of the Chinese Academy of Science ; Strategic Priority Research Program of the Chinese Academy of Science ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program ; Key Research Program ; Strategic Priority Research Program of the Chinese Academy of Science ; Strategic Priority Research Program of the Chinese Academy of Science
WOS IDWOS:000463960700021
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165611
Collection中国科学院大连化学物理研究所
Corresponding AuthorLiu, Zhiling; Jiang, Ling; Xie, Hua
Affiliation1.Chinese Acad Sci, State Key Lab Mol React Dynam, Collaborat Innovat Ctr Chem Energy & Mat iChEM, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Shanxi Normal Univ, Sch Chem & Mat Sci, Key Lab Magnet Mol & Magnet Informat Mat, Minist Educ, 1 Gongyuan St, Linfen 041004, Shanxi, Peoples R China
3.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Jumei,Li, Ya,Liu, Zhiling,et al. Ligand-Mediated Reactivity in CO Oxidation of Niobium-Nickel Monoxide Carbonyl Complexes: The Crucial Roles of the Multiple Adsorption of CO Molecules[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS,2019,10(7):1566-1573.
APA Zhang, Jumei.,Li, Ya.,Liu, Zhiling.,Li, Gang.,Fan, Hongjun.,...&Xie, Hua.(2019).Ligand-Mediated Reactivity in CO Oxidation of Niobium-Nickel Monoxide Carbonyl Complexes: The Crucial Roles of the Multiple Adsorption of CO Molecules.JOURNAL OF PHYSICAL CHEMISTRY LETTERS,10(7),1566-1573.
MLA Zhang, Jumei,et al."Ligand-Mediated Reactivity in CO Oxidation of Niobium-Nickel Monoxide Carbonyl Complexes: The Crucial Roles of the Multiple Adsorption of CO Molecules".JOURNAL OF PHYSICAL CHEMISTRY LETTERS 10.7(2019):1566-1573.
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