DICP OpenIR
Photo-assisted methanol synthesis via CO2 reduction under ambient pressure over plasmonic Cu/ZnO catalysts
Wang, Zhou-jun1,2; Song, Hui2,3; Pang, Hong2,3; Ning, Yanxiao10; Thang Duy Dao2,6,7; Wang, Zhuan8,9; Chen, Hailong8,9; Weng, Yuxiang8,9; Fu, Qiang10; Nagao, Tadaaki2,6,7; Fang, Yunming1; Ye, Jinhua2,3,4,5
Corresponding AuthorFang, Yunming(fangym@mail.buct.edu.cn) ; Ye, Jinhua(Jinhua.YE@nims.go.jp)
KeywordPhotocatalysis Carbon dioxide Reduction Copper Surface plasmon resonance
Source PublicationAPPLIED CATALYSIS B-ENVIRONMENTAL
2019-08-05
ISSN0926-3373
DOI10.1016/j.apcatb.2019.03.003
Volume250Pages:10-16
Funding ProjectJSPS KAKENHI[JP18H02065] ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; MEXT (Japan) ; National Basic Research Program of China (973 Program)[2014CB239301] ; National Natural Science Foundation of China[21633004] ; National Natural Science Foundation of China[21776007] ; National Natural Science Foundation of China[21811530293] ; China Scholarship Council (CSC)[201606320239] ; China Scholarship Council (CSC)[201706885023] ; Fundamental Research Funds for the Central Universities[XK1802-1]
Funding OrganizationJSPS KAKENHI ; JSPS KAKENHI ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; MEXT (Japan) ; MEXT (Japan) ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; JSPS KAKENHI ; JSPS KAKENHI ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; MEXT (Japan) ; MEXT (Japan) ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; JSPS KAKENHI ; JSPS KAKENHI ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; MEXT (Japan) ; MEXT (Japan) ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; JSPS KAKENHI ; JSPS KAKENHI ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; MEXT (Japan) ; MEXT (Japan) ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities
WOS SubjectChemistry, Physical ; Engineering, Environmental ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordOCTAHEDRAL ANATASE PARTICLES ; VISIBLE-LIGHT IRRADIATION ; METAL-ORGANIC FRAMEWORKS ; CARBON-DIOXIDE REDUCTION ; GOLD NANOPARTICLES ; OXYGEN VACANCY ; ACTIVE-SITES ; HYDROGENATION ; CONVERSION ; ACTIVATION
AbstractMethanol synthesis via carbon dioxide (CO2) reduction is challenging and important because this technology can convert CO2 by solar- or wind-generated hydrogen into liquid fuel. The present work introduces the visible light as an external stimulus and for the first time demonstrates that methanol synthesis over Cu/ZnO catalysts can be effectively promoted by solar energy under atmospheric pressure. Experimental and theoretical studies document that hot electrons were photo-excited by localized surface plasmon resonance (LSPR) on Cu nanoparticles and such photo-excited hot electrons could transfer to ZnO through the metal-support interfaces. The hot electrons on Cu and ZnO synergistically facilitated the activation of reaction intermediates. Consequently, the activation energy was reduced by 40% and the methanol synthesis activity was promoted by 54%. This work provides a new strategy towards synthesis of liquid fuel via CO2 reduction under low pressure and sheds new light on the mechanism of photo-mediated catalysis.
Language英语
Funding OrganizationJSPS KAKENHI ; JSPS KAKENHI ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; MEXT (Japan) ; MEXT (Japan) ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; JSPS KAKENHI ; JSPS KAKENHI ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; MEXT (Japan) ; MEXT (Japan) ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; JSPS KAKENHI ; JSPS KAKENHI ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; MEXT (Japan) ; MEXT (Japan) ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; JSPS KAKENHI ; JSPS KAKENHI ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; World Premier International Research Center Initiative (WPI Initiative) on Materials Nanoarchitectonics (MANA) ; MEXT (Japan) ; MEXT (Japan) ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities
WOS IDWOS:000465051700002
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165623
Collection中国科学院大连化学物理研究所
Corresponding AuthorFang, Yunming; Ye, Jinhua
Affiliation1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing Key Lab Energy Environm Catalysis, Beijing 100029, Peoples R China
2.NIMS, Int Ctr Mat Nanoarchitecton WPI MANA, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
3.Hokkaido Univ, Grad Sch Chem Sci & Engn, Sapporo, Hokkaido 0600814, Japan
4.Tianjin Univ, TJU NIMS Int Collaborat Lab, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China
5.Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
6.Japan Sci & Technol Agcy JST, CREST, 4-1-8 Honcho, Kawaguchi, Saitama 3320012, Japan
7.Hokkaido Univ, Grad Sch Sci, Dept Condensed Matter Phys, Sapporo, Hokkaido 0600810, Japan
8.Chinese Acad Sci, Inst Phys, Condensed Matter Phys, Beijing 100190, Peoples R China
9.Univ Chinese Acad Sci, Sch Phys Sci, Beijing 100049, Peoples R China
10.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, IChEM, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Wang, Zhou-jun,Song, Hui,Pang, Hong,et al. Photo-assisted methanol synthesis via CO2 reduction under ambient pressure over plasmonic Cu/ZnO catalysts[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2019,250:10-16.
APA Wang, Zhou-jun.,Song, Hui.,Pang, Hong.,Ning, Yanxiao.,Thang Duy Dao.,...&Ye, Jinhua.(2019).Photo-assisted methanol synthesis via CO2 reduction under ambient pressure over plasmonic Cu/ZnO catalysts.APPLIED CATALYSIS B-ENVIRONMENTAL,250,10-16.
MLA Wang, Zhou-jun,et al."Photo-assisted methanol synthesis via CO2 reduction under ambient pressure over plasmonic Cu/ZnO catalysts".APPLIED CATALYSIS B-ENVIRONMENTAL 250(2019):10-16.
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