DICP OpenIR
Efficient photoredox conversion of alcohol to aldehyde and H-2 by heterointerface engineering of bimetal-semiconductor hybrids
Han, Chuang1,2; Tang, Zi-Rong2; Liu, Junxue3; Jin, Shengye3; Xu, Yi-Jun1,2
Corresponding AuthorJin, Shengye(sjin@dicp.ac.cn) ; Xu, Yi-Jun(yjxu@fzu.edu.cn)
Source PublicationCHEMICAL SCIENCE
2019-03-28
ISSN2041-6520
DOI10.1039/c8sc05813j
Volume10Issue:12Pages:3514-3522
Funding ProjectNational Natural Science Foundation of China (NSFC)[21872029] ; National Natural Science Foundation of China (NSFC)[U1463204] ; National Natural Science Foundation of China (NSFC)[21173045] ; Award Program for Minjiang Scholar Professorship ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant[2017J07002] ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment[2014A05] ; 1st Program of Fujian Province for Top Creative Young Talents
Funding OrganizationNational Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Award Program for Minjiang Scholar Professorship ; Award Program for Minjiang Scholar Professorship ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; 1st Program of Fujian Province for Top Creative Young Talents ; 1st Program of Fujian Province for Top Creative Young Talents ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Award Program for Minjiang Scholar Professorship ; Award Program for Minjiang Scholar Professorship ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; 1st Program of Fujian Province for Top Creative Young Talents ; 1st Program of Fujian Province for Top Creative Young Talents ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Award Program for Minjiang Scholar Professorship ; Award Program for Minjiang Scholar Professorship ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; 1st Program of Fujian Province for Top Creative Young Talents ; 1st Program of Fujian Province for Top Creative Young Talents ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Award Program for Minjiang Scholar Professorship ; Award Program for Minjiang Scholar Professorship ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; 1st Program of Fujian Province for Top Creative Young Talents ; 1st Program of Fujian Province for Top Creative Young Talents
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordCORE-SHELL NANOSTRUCTURES ; PHOTOCATALYTIC HYDROGEN GENERATION ; LOW-TEMPERATURE SYNTHESIS ; ONE-POT SYNTHESIS ; PLASMON ENHANCEMENT ; NONEPITAXIAL GROWTH ; TIO2 NANOSHEETS ; SINGLE-PARTICLE ; VISIBLE REGION ; SOLAR-ENERGY
AbstractControllable and precise design of bimetal- or multimetal-semiconductor nanostructures with efficient light absorption, charge separation and utilization is strongly desired for photoredox catalysis applications in solar energy conversion. Taking advantage of Au nanorods, Pt nanoparticles, and CdS as the plasmonic metal, nonplasmonic co-catalyst and semiconductor respectively, we report a steerable approach to engineer the heterointerface of bimetal-semiconductor hybrids. We show that the ingredient composition and spatial distribution between the bimetal and semiconductor significantly influence the redox catalytic activity. CdS deposited anisotropic Pt-tipped Au nanorods, which feature improved light absorption, structure-enhanced electric field distribution and spatially regulated multichannel charge transfer, show distinctly higher photoactivity than blank CdS and other metal-CdS hybrids for simultaneous H-2 and value-added aldehyde production from one redox cycle.
Language英语
Funding OrganizationNational Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Award Program for Minjiang Scholar Professorship ; Award Program for Minjiang Scholar Professorship ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; 1st Program of Fujian Province for Top Creative Young Talents ; 1st Program of Fujian Province for Top Creative Young Talents ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Award Program for Minjiang Scholar Professorship ; Award Program for Minjiang Scholar Professorship ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; 1st Program of Fujian Province for Top Creative Young Talents ; 1st Program of Fujian Province for Top Creative Young Talents ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Award Program for Minjiang Scholar Professorship ; Award Program for Minjiang Scholar Professorship ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; 1st Program of Fujian Province for Top Creative Young Talents ; 1st Program of Fujian Province for Top Creative Young Talents ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Award Program for Minjiang Scholar Professorship ; Award Program for Minjiang Scholar Professorship ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Natural Science Foundation (NSF) of Fujian Province for Distinguished Young Investigator Rolling Grant ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; Independent Research Project of the State Key Laboratory of Photocatalysis on Energy and Environment ; 1st Program of Fujian Province for Top Creative Young Talents ; 1st Program of Fujian Province for Top Creative Young Talents
WOS IDWOS:000463759100005
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165635
Collection中国科学院大连化学物理研究所
Corresponding AuthorJin, Shengye; Xu, Yi-Jun
Affiliation1.Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
2.Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350116, Fujian, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Han, Chuang,Tang, Zi-Rong,Liu, Junxue,et al. Efficient photoredox conversion of alcohol to aldehyde and H-2 by heterointerface engineering of bimetal-semiconductor hybrids[J]. CHEMICAL SCIENCE,2019,10(12):3514-3522.
APA Han, Chuang,Tang, Zi-Rong,Liu, Junxue,Jin, Shengye,&Xu, Yi-Jun.(2019).Efficient photoredox conversion of alcohol to aldehyde and H-2 by heterointerface engineering of bimetal-semiconductor hybrids.CHEMICAL SCIENCE,10(12),3514-3522.
MLA Han, Chuang,et al."Efficient photoredox conversion of alcohol to aldehyde and H-2 by heterointerface engineering of bimetal-semiconductor hybrids".CHEMICAL SCIENCE 10.12(2019):3514-3522.
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