DICP OpenIR
Rational approach to guest confinement inside MOF cavities for low-temperature catalysis
Wang, Tiesheng1,2,3; Gao, Lijun4; Hou, Jingwei1,5; Herou, Servann J. A.6,7,8; Griffiths, James T.1; Li, Weiwei1; Dong, Jinhu4; Gao, Song5; Titirici, Maria-Magdalena6,7,8; Kumar, R. Vasant1; Cheetham, Anthony K.1,9; Bao, Xinhe4; Fu, Qiang4; Smoukov, Stoyan K.1,6,7,10
Corresponding AuthorFu, Qiang(qfu@dicp.ac.cn) ; Smoukov, Stoyan K.(s.smoukov@qmul.ac.uk)
Source PublicationNATURE COMMUNICATIONS
2019-03-22
ISSN2041-1723
DOI10.1038/s41467-019-08972-x
Volume10Pages:9
Funding ProjectEuropean Research Council (ERC)[280078] ; National Natural Science Foundation of China[21688102] ; National Natural Science Foundation of China[21825203] ; Ministry of Science and Technology of China[2016YFA0200200] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020000] ; China Scholarship Council (CSC) ; EPSRC[EP/L011700/1] ; EPSRC[EP/N004272/1] ; EPSRC[EP/L015889/1] ; EPSRC[1566990] ; Isaac Newton Trust[13.38(k)]
Funding OrganizationEuropean Research Council (ERC) ; European Research Council (ERC) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; EPSRC ; EPSRC ; Isaac Newton Trust ; Isaac Newton Trust ; European Research Council (ERC) ; European Research Council (ERC) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; EPSRC ; EPSRC ; Isaac Newton Trust ; Isaac Newton Trust ; European Research Council (ERC) ; European Research Council (ERC) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; EPSRC ; EPSRC ; Isaac Newton Trust ; Isaac Newton Trust ; European Research Council (ERC) ; European Research Council (ERC) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; EPSRC ; EPSRC ; Isaac Newton Trust ; Isaac Newton Trust
WOS SubjectMultidisciplinary Sciences
WOS Research AreaScience & Technology - Other Topics
WOS KeywordMETAL-ORGANIC FRAMEWORKS ; CO OXIDATION ; SURFACE-CHEMISTRY ; HETEROGENEOUS CATALYSIS ; POURBAIX DIAGRAMS ; CARBON-MONOXIDE ; RUTHENIUM ; HYDROGENATION ; NANOPARTICLES ; SYSTEMS
AbstractGeometric or electronic confinement of guests inside nanoporous hosts promises to deliver unusual catalytic or opto-electronic functionality from existing materials but is challenging to obtain particularly using metastable hosts, such as metal-organic frameworks (MOFs). Reagents (e.g. precursor) may be too large for impregnation and synthesis conditions may also destroy the hosts. Here we use thermodynamic Pourbaix diagrams (favorable redox and pH conditions) to describe a general method for metal-compound guest synthesis by rationally selecting reaction agents and conditions. Specifically we demonstrate a MOF-confined RuO2 catalyst (RuO2@MOF-808-P) with exceptionally high catalytic CO oxidation below 150 degrees C as compared to the conventionally made SiO2-supported RuO2 (RuO2/SiO2). This can be caused by weaker interactions between CO/O and the MOF-encapsulated RuO2 surface thus avoiding adsorption-induced catalytic surface passivation. We further describe applications of the Pourbaix-enabled guest synthesis (PEGS) strategy with tutorial examples for the general synthesis of arbitrary guests (e.g. metals, oxides, hydroxides, sulfides).
Language英语
Funding OrganizationEuropean Research Council (ERC) ; European Research Council (ERC) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; EPSRC ; EPSRC ; Isaac Newton Trust ; Isaac Newton Trust ; European Research Council (ERC) ; European Research Council (ERC) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; EPSRC ; EPSRC ; Isaac Newton Trust ; Isaac Newton Trust ; European Research Council (ERC) ; European Research Council (ERC) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; EPSRC ; EPSRC ; Isaac Newton Trust ; Isaac Newton Trust ; European Research Council (ERC) ; European Research Council (ERC) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; China Scholarship Council (CSC) ; China Scholarship Council (CSC) ; EPSRC ; EPSRC ; Isaac Newton Trust ; Isaac Newton Trust
WOS IDWOS:000461995800011
PublisherNATURE PUBLISHING GROUP
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165711
Collection中国科学院大连化学物理研究所
Corresponding AuthorFu, Qiang; Smoukov, Stoyan K.
Affiliation1.Univ Cambridge, Dept Mat Sci & Met, Cambridge CB3 0FS, England
2.Univ Cambridge, EPSRC Ctr Doctoral Training Sensor Technol & Appl, Cambridge CB3 0AS, England
3.Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
4.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM, State Key Lab Catalysis, Dalian 116023, Peoples R China
5.Univ New South Wales, UNESCO Ctr Membrane Sci & Technol, Sch Chem Engn, Sydney, NSW 2052, Australia
6.Queen Mary Univ London, Sch Engn & Mat Sci, London E1 4NS, England
7.Queen Mary Univ London, Mat Res Inst, London E1 4NS, England
8.Imperial Coll London, Dept Chem Engn, London SW7 2AZ, England
9.Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117574, Singapore
10.Sofia Univ, Fac Chem & Pharm, Dept Chem & Pharmaceut Engn, Sofia 1164, Bulgaria
Recommended Citation
GB/T 7714
Wang, Tiesheng,Gao, Lijun,Hou, Jingwei,et al. Rational approach to guest confinement inside MOF cavities for low-temperature catalysis[J]. NATURE COMMUNICATIONS,2019,10:9.
APA Wang, Tiesheng.,Gao, Lijun.,Hou, Jingwei.,Herou, Servann J. A..,Griffiths, James T..,...&Smoukov, Stoyan K..(2019).Rational approach to guest confinement inside MOF cavities for low-temperature catalysis.NATURE COMMUNICATIONS,10,9.
MLA Wang, Tiesheng,et al."Rational approach to guest confinement inside MOF cavities for low-temperature catalysis".NATURE COMMUNICATIONS 10(2019):9.
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