DICP OpenIR
Effects of hyperthermal atomic oxygen on a cyanate ester and its carbon fiber-reinforced composite
Wang, Heilong1,2; Qian, Min3; Murray, Vanessa J.4; Wu, Bohan5; Yang, Yang6; Dong, Aiyi7; Che, Li1,7; Minton, Timothy K.4
Corresponding AuthorWu, Bohan(bohanwoo@hotmail.com) ; Che, Li(liche@dlmu.edu.cn) ; Minton, Timothy K.(tminton@montana.edu)
KeywordCyanate ester carbon fiber atomic oxygen low Earth orbit
Source PublicationHIGH PERFORMANCE POLYMERS
2019-05-01
ISSN0954-0083
DOI10.1177/0954008318788401
Volume31Issue:4Pages:472-482
Funding ProjectNational Science Foundation of China[21473015] ; National Science Foundation of China[21203016] ; National Science Foundation of China[41574101] ; National Excellent Doctoral Thesis Author Special Fund Project[201222] ; Fundamental Research Funds for the Central Universities[3132018233] ; Fundamental Research Funds for the Central Universities[3132018232] ; Shanghai Sailing Program[17YF1403300]
Funding OrganizationNational Science Foundation of China ; National Science Foundation of China ; National Excellent Doctoral Thesis Author Special Fund Project ; National Excellent Doctoral Thesis Author Special Fund Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shanghai Sailing Program ; Shanghai Sailing Program ; National Science Foundation of China ; National Science Foundation of China ; National Excellent Doctoral Thesis Author Special Fund Project ; National Excellent Doctoral Thesis Author Special Fund Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shanghai Sailing Program ; Shanghai Sailing Program ; National Science Foundation of China ; National Science Foundation of China ; National Excellent Doctoral Thesis Author Special Fund Project ; National Excellent Doctoral Thesis Author Special Fund Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shanghai Sailing Program ; Shanghai Sailing Program ; National Science Foundation of China ; National Science Foundation of China ; National Excellent Doctoral Thesis Author Special Fund Project ; National Excellent Doctoral Thesis Author Special Fund Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shanghai Sailing Program ; Shanghai Sailing Program
WOS SubjectPolymer Science
WOS Research AreaPolymer Science
WOS KeywordHIGH DIELECTRIC-CONSTANT ; SCATTERING DYNAMICS ; SPACE ENVIRONMENT ; POLYMERS ; RESISTANCE ; EROSION ; GRAPHITE ; DURABILITY ; DEPOSITION ; POLYIMIDE
AbstractThe durability of cyanate ester (CE) to hyperthermal atomic oxygen (AO) attack in low Earth orbit may be enhanced by the addition of carbon fiber to form a carbon fiber-reinforced cyanate ester composite (CFCE). To investigate the durability of CFCE relative to CE, samples were exposed to a pulsed hyperthermal AO beam in two distinct types of experiments. In one type of experiment, samples were exposed to the beam, with pre- and post-characterization of mass (microbalance), surface topography (scanning electron microscopy (SEM)), and surface chemistry (X-ray photoelectron spectroscopy (XPS)). In the second type of experiment, the beam was directed at a sample surface, and volatile products that scattered from the surface were detected in situ with the use of a rotatable mass spectrometer detector. CFCE exhibited less mass loss than pure CE with a given AO fluence, confirming that the incorporation of carbon fiber adds AO resistance to CE. Erosion yields of CE and CFCE were 2.63 +/- 0.16 x 10(-24) and 1.46 +/- 0.08 x 10(-24) cm(3) O-atom(-1), respectively. The reduced reactivity of CFCE in comparison to CE was manifested in less oxidation of the CFCE surface in XPS measurements and reduced CO, CO2, and OH reaction products in beam-surface scattering experiments. The surface topographical images collected by SEM implied different surface deterioration processes for CE and CFCE. A change of surface topography with increasing AO fluence for CE indicated a threshold AO fluence, above which the erosion mechanism changed qualitatively. CFCE showed almost intact carbon fibers after relatively low AO fluences, and while the fibers eventually eroded, they did not erode as rapidly as the CE component of the composite.
Language英语
Funding OrganizationNational Science Foundation of China ; National Science Foundation of China ; National Excellent Doctoral Thesis Author Special Fund Project ; National Excellent Doctoral Thesis Author Special Fund Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shanghai Sailing Program ; Shanghai Sailing Program ; National Science Foundation of China ; National Science Foundation of China ; National Excellent Doctoral Thesis Author Special Fund Project ; National Excellent Doctoral Thesis Author Special Fund Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shanghai Sailing Program ; Shanghai Sailing Program ; National Science Foundation of China ; National Science Foundation of China ; National Excellent Doctoral Thesis Author Special Fund Project ; National Excellent Doctoral Thesis Author Special Fund Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shanghai Sailing Program ; Shanghai Sailing Program ; National Science Foundation of China ; National Science Foundation of China ; National Excellent Doctoral Thesis Author Special Fund Project ; National Excellent Doctoral Thesis Author Special Fund Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shanghai Sailing Program ; Shanghai Sailing Program
WOS IDWOS:000462336400011
PublisherSAGE PUBLICATIONS LTD
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165725
Collection中国科学院大连化学物理研究所
Corresponding AuthorWu, Bohan; Che, Li; Minton, Timothy K.
Affiliation1.Dalian Maritime Univ, Coll Environm Sci & Engn, 1 Linghai Rd, Dalian 116026, Liaoning, Peoples R China
2.Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian, Liaoning, Peoples R China
3.East China Univ Sci & Technol, Sch Sci, Dept Phys, Shanghai, Peoples R China
4.Montana State Univ, Dept Chem & Biochem, Bozeman, MT 59717 USA
5.Beijing Inst Spacecraft Environm Engn, Beijing 100094, Peoples R China
6.Aerosp Res Inst Mat & Proc Technol, Beijing, Peoples R China
7.Dalian Maritime Univ, Coll Sci, Dalian, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Wang, Heilong,Qian, Min,Murray, Vanessa J.,et al. Effects of hyperthermal atomic oxygen on a cyanate ester and its carbon fiber-reinforced composite[J]. HIGH PERFORMANCE POLYMERS,2019,31(4):472-482.
APA Wang, Heilong.,Qian, Min.,Murray, Vanessa J..,Wu, Bohan.,Yang, Yang.,...&Minton, Timothy K..(2019).Effects of hyperthermal atomic oxygen on a cyanate ester and its carbon fiber-reinforced composite.HIGH PERFORMANCE POLYMERS,31(4),472-482.
MLA Wang, Heilong,et al."Effects of hyperthermal atomic oxygen on a cyanate ester and its carbon fiber-reinforced composite".HIGH PERFORMANCE POLYMERS 31.4(2019):472-482.
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