DICP OpenIR
Selective activation of C-H bond into C=0 bond of phenols in para-position via aerobic oxidation
Yang, Shilei1; Xu, Guoqiang1; Shi, Song2; Xin, Hongchuan1; Gao, Jin2; An, Zengjian1
Corresponding AuthorXin, Hongchuan(xinhc@qibebt.ac.cn) ; Gao, Jin(gaojin@dicp.ac.cn) ; An, Zengjian(anzj@qibebt.ac.cn)
KeywordSelective activation C-H bond C=O bond Phenols Aerobic oxidation
Source PublicationCATALYSIS COMMUNICATIONS
2019-04-01
ISSN1566-7367
DOI10.1016/j.catcom.2019.02.017
Volume123Pages:105-108
Funding ProjectDalian National Laboratory For Clean Energy (DNL) ; CAS ; DICP QIBEBT[DICP & QIBEBT UN201703] ; Major Program of Shandong Province Natural Science Foundation[ZR2017ZCO633]
Funding OrganizationDalian National Laboratory For Clean Energy (DNL) ; Dalian National Laboratory For Clean Energy (DNL) ; CAS ; CAS ; DICP QIBEBT ; DICP QIBEBT ; Major Program of Shandong Province Natural Science Foundation ; Major Program of Shandong Province Natural Science Foundation ; Dalian National Laboratory For Clean Energy (DNL) ; Dalian National Laboratory For Clean Energy (DNL) ; CAS ; CAS ; DICP QIBEBT ; DICP QIBEBT ; Major Program of Shandong Province Natural Science Foundation ; Major Program of Shandong Province Natural Science Foundation ; Dalian National Laboratory For Clean Energy (DNL) ; Dalian National Laboratory For Clean Energy (DNL) ; CAS ; CAS ; DICP QIBEBT ; DICP QIBEBT ; Major Program of Shandong Province Natural Science Foundation ; Major Program of Shandong Province Natural Science Foundation ; Dalian National Laboratory For Clean Energy (DNL) ; Dalian National Laboratory For Clean Energy (DNL) ; CAS ; CAS ; DICP QIBEBT ; DICP QIBEBT ; Major Program of Shandong Province Natural Science Foundation ; Major Program of Shandong Province Natural Science Foundation
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordAQUEOUS HYDROGEN-PEROXIDE ; COPPER(II) CHLORIDE ; H2O2-BASED OXIDATION ; CATALYZED OXIDATION ; 2,3,6-TRIMETHYLPHENOL ; 2,3,5-TRIMETHYLBENZOQUINONE ; TRIMETHYL-1,4-BENZOQUINONE ; 2,3,5-TRIMETHYLPHENOL ; BENZOQUINONES ; ALKYLPHENOLS
AbstractAn efficient method for the oxidation of phenols to 1,4-benzoquinones catalyzed by cuprous(I) chloride was achieved in a solution of acetonitrile and water using molecular dioxygen as an oxidant. Particularly, the inert phenols, such as phenol and mono-alkyl substituted phenols, were effectively oxidized to 1,4-benzoquinones via the selective activation of C-H bond in para-position into C=O bond under mild conditions. The catalyst shows high activity for unsubstituted or alkyl substituted phenols, but no effect on substituted phenols with electron withdrawing groups. This study offers an aerobic method for the selective oxidation of aromatic phenols to 1,4-benzoquinones.
Language英语
Funding OrganizationDalian National Laboratory For Clean Energy (DNL) ; Dalian National Laboratory For Clean Energy (DNL) ; CAS ; CAS ; DICP QIBEBT ; DICP QIBEBT ; Major Program of Shandong Province Natural Science Foundation ; Major Program of Shandong Province Natural Science Foundation ; Dalian National Laboratory For Clean Energy (DNL) ; Dalian National Laboratory For Clean Energy (DNL) ; CAS ; CAS ; DICP QIBEBT ; DICP QIBEBT ; Major Program of Shandong Province Natural Science Foundation ; Major Program of Shandong Province Natural Science Foundation ; Dalian National Laboratory For Clean Energy (DNL) ; Dalian National Laboratory For Clean Energy (DNL) ; CAS ; CAS ; DICP QIBEBT ; DICP QIBEBT ; Major Program of Shandong Province Natural Science Foundation ; Major Program of Shandong Province Natural Science Foundation ; Dalian National Laboratory For Clean Energy (DNL) ; Dalian National Laboratory For Clean Energy (DNL) ; CAS ; CAS ; DICP QIBEBT ; DICP QIBEBT ; Major Program of Shandong Province Natural Science Foundation ; Major Program of Shandong Province Natural Science Foundation
WOS IDWOS:000463124300021
PublisherELSEVIER SCIENCE BV
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165775
Collection中国科学院大连化学物理研究所
Corresponding AuthorXin, Hongchuan; Gao, Jin; An, Zengjian
Affiliation1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Yang, Shilei,Xu, Guoqiang,Shi, Song,et al. Selective activation of C-H bond into C=0 bond of phenols in para-position via aerobic oxidation[J]. CATALYSIS COMMUNICATIONS,2019,123:105-108.
APA Yang, Shilei,Xu, Guoqiang,Shi, Song,Xin, Hongchuan,Gao, Jin,&An, Zengjian.(2019).Selective activation of C-H bond into C=0 bond of phenols in para-position via aerobic oxidation.CATALYSIS COMMUNICATIONS,123,105-108.
MLA Yang, Shilei,et al."Selective activation of C-H bond into C=0 bond of phenols in para-position via aerobic oxidation".CATALYSIS COMMUNICATIONS 123(2019):105-108.
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