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Palladium-Catalyzed Propargylic [n+2] Cycloaddition: An Efficient Strategy for Construction of Benzo-Fused Medium-Sized Heterocycles
Liu, Zhen-Ting1,2; Hu, Xiang-Ping1
Corresponding AuthorHu, Xiang-Ping(xiangping@dicp.ac.cn)
KeywordA regioselective palladium-catalyzed formal [n+2] cycloaddition of propargylic esters as C-2-synthons with various linker-tethered bisphenols for the construction of medium-sized heterocycles bearing an exocyclic double bond has been developed The reaction features mild conditions and broad substrate scopes as well as readily available substrates and catalysts Under optimal conditions various medium-sized heterocycles from eight to eleven-membered rings can be afforded in good to excellent yields and regioselectivities with high Z-selectivity for the exocyclic double bond palladium medium-sized ring propargylic ester bisphenol cycloaddition
Source PublicationADVANCED SYNTHESIS & CATALYSIS
2019-02-19
ISSN1615-4150
DOI10.1002/adsc.201801359
Volume361Issue:4Pages:836-841
Funding ProjectNational Natural Science Foundation of China[21572226] ; National Natural Science Foundation of China[21772196] ; Dalian Institute of Chemical Physics[DICP ZZBS201707]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics
WOS SubjectChemistry, Applied ; Chemistry, Organic
WOS Research AreaChemistry
WOS Keyword1,3-DIPOLAR 3+6 CYCLOADDITION ; RING-EXPANSION ; AZOMETHINE YLIDES ; ENANTIOSELECTIVE SYNTHESIS ; CONVERGENT STRATEGIES ; ALLYLIC COMPOUNDS ; ACCESS ; ANNULATION ; DERIVATIVES ; CYCLIZATION
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics
WOS IDWOS:000459822800024
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165783
Collection中国科学院大连化学物理研究所
Corresponding AuthorHu, Xiang-Ping
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Liu, Zhen-Ting,Hu, Xiang-Ping. Palladium-Catalyzed Propargylic [n+2] Cycloaddition: An Efficient Strategy for Construction of Benzo-Fused Medium-Sized Heterocycles[J]. ADVANCED SYNTHESIS & CATALYSIS,2019,361(4):836-841.
APA Liu, Zhen-Ting,&Hu, Xiang-Ping.(2019).Palladium-Catalyzed Propargylic [n+2] Cycloaddition: An Efficient Strategy for Construction of Benzo-Fused Medium-Sized Heterocycles.ADVANCED SYNTHESIS & CATALYSIS,361(4),836-841.
MLA Liu, Zhen-Ting,et al."Palladium-Catalyzed Propargylic [n+2] Cycloaddition: An Efficient Strategy for Construction of Benzo-Fused Medium-Sized Heterocycles".ADVANCED SYNTHESIS & CATALYSIS 361.4(2019):836-841.
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