DICP OpenIR
Thiol-ene polymerization for hierarchically porous hybrid materials by adding degradable polycaprolactone for adsorption of bisphenol A
Zhang, Haiyang1,2; Ma, Shujuan1,2; Li, Ya1,2; Ou, Junjie1,3; Wei, Yinmao2; Ye, Mingliang1,3
Corresponding AuthorOu, Junjie(junjieou@dicp.ac.cn) ; Wei, Yinmao(ymwei@nwu.edu.cn)
KeywordHierarchically porous hybrid materials Polyhedral oligomeric silsesquioxanes Degradable polymer Bisphenol A
Source PublicationJOURNAL OF HAZARDOUS MATERIALS
2019-04-05
ISSN0304-3894
DOI10.1016/j.jhazmat.2018.12.113
Volume367Pages:465-472
Funding ProjectChina State Key Basic Research Program Grant[2016YFA0501402] ; National Science Fund for Distinguished Young Scholars[21525524] ; National Natural Sciences Foundation of China[21575141] ; CAS-Weigao Research & Development Program[[2017]-009]
Funding OrganizationChina State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program
WOS SubjectEngineering, Environmental ; Environmental Sciences
WOS Research AreaEngineering ; Environmental Sciences & Ecology
WOS KeywordPOLYHEDRAL OLIGOMERIC SILSESQUIOXANE ; MONOLITHIC COLUMNS ; SURFACE-AREA ; POLYMERS ; LIGHT ; CHEMISTRY ; ZEOLITES ; REMOVAL ; CARBON
AbstractHierarchically porous materials with multiple pore structures have the potential application in catalysis, separation or bioengineering. A concept was introduced to design and fabricate hierarchically porous hybrid materials (HPHMs) simultaneously containing mesopores and macropores. The proof-of-concept design was demonstrated by fabrication of several kinds of hybrid materials by adding degradable polycaprolactone (PCL) additive, which was simple and easy-operating. The specific surface areas of HPHMs prepared with polyhedral oligomeric vinylsilsesquioxanes (vinylPOSS) and 1,4-dithiothreitol (DTT) could reach 727 m(2)/g by adding 25% PCL additive, while the HPHMs were imperforate prior to degradation of PCL. The characterization further indicated that the macropores could be controlled by the amount of PCL additive. Moreover, the porous properties of HPHMs were influenced by the molecular weight of PCL. Other dithiols compounds were also successful in preparing HPHMs with high specific surface areas over 400 m2/g. Due to hydrophobic interaction and hydrogen bond interaction, the HPHM exhibited good adsorption ability for bisphenol A (BPA) in aqueous solution. Adsorption equilibrium could be achieved within 30 min, and the adsorption capacity was up to 157.4 mg/g. Meanwhile, the removal efficiency was found to be 95.37% for BPA.
Language英语
Funding OrganizationChina State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program ; China State Key Basic Research Program Grant ; China State Key Basic Research Program Grant ; National Science Fund for Distinguished Young Scholars ; National Science Fund for Distinguished Young Scholars ; National Natural Sciences Foundation of China ; National Natural Sciences Foundation of China ; CAS-Weigao Research & Development Program ; CAS-Weigao Research & Development Program
WOS IDWOS:000459845000052
PublisherELSEVIER SCIENCE BV
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165789
Collection中国科学院大连化学物理研究所
Corresponding AuthorOu, Junjie; Wei, Yinmao
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China
2.Northwest Univ, Coll Chem & Mat Sci, Minist Educ, Key Lab Synthet & Nat Funct Mol Chem, Xian 710069, Shaanxi, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Haiyang,Ma, Shujuan,Li, Ya,et al. Thiol-ene polymerization for hierarchically porous hybrid materials by adding degradable polycaprolactone for adsorption of bisphenol A[J]. JOURNAL OF HAZARDOUS MATERIALS,2019,367:465-472.
APA Zhang, Haiyang,Ma, Shujuan,Li, Ya,Ou, Junjie,Wei, Yinmao,&Ye, Mingliang.(2019).Thiol-ene polymerization for hierarchically porous hybrid materials by adding degradable polycaprolactone for adsorption of bisphenol A.JOURNAL OF HAZARDOUS MATERIALS,367,465-472.
MLA Zhang, Haiyang,et al."Thiol-ene polymerization for hierarchically porous hybrid materials by adding degradable polycaprolactone for adsorption of bisphenol A".JOURNAL OF HAZARDOUS MATERIALS 367(2019):465-472.
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