DICP OpenIR
Green catalytic synthesis of 5-methylfurfural by selective hydrogenolysis of 5-hydroxymethylfurfural over size-controlled Pd nanoparticle catalysts
Sun, Guohan1; An, Jiahuan1; Hu, Hong1; Li, Changzhi2; Zuo, Songlin1; Xia, Haian1
Corresponding AuthorLi, Changzhi(licz@dicp.ac.cn) ; Xia, Haian(haxia@dicp.ac.cn)
Source PublicationCATALYSIS SCIENCE & TECHNOLOGY
2019-03-07
ISSN2044-4753
DOI10.1039/c9cy00039a
Volume9Issue:5Pages:1238-1244
Funding ProjectNational Key R&D Program of China[2017YFD0601006] ; Natural Science Foundation of China[31200445] ; Natural Science Foundation of China[21878288] ; Natural Science Foundation of China[21690083] ; Natural Science Foundation of Jiangsu Province[BK20171452] ; Natural Science Foundation of Jiangsu Higher Education Institutes of China[16KJB220003]
Funding OrganizationNational Key R&D Program of China ; National Key R&D Program of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; National Key R&D Program of China ; National Key R&D Program of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; National Key R&D Program of China ; National Key R&D Program of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; National Key R&D Program of China ; National Key R&D Program of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordCONVERSION ; OXIDATION ; BIOMASS ; REDUCTION ; ACID ; 2,5-DIFORMYLFURAN ; FRUCTOSE ; DIESEL
AbstractA green approach for the conversion of 5-(hydroxymethyl) furfural (HMF) to 5-methylfurfural (MF) by using size-controlled palladium catalysts has been developed. Palladium nanoparticles (Pd NPs) with various sizes supported on activated carbon were prepared with polyvinylpyrrolidone (PVP) as the capping agent. The reaction results showed that all the PVP-assisted Pd catalysts achieved high selectivity whilst the hydrogenation ability of Pd NPs could be rationally tuned by varying the mole ratio of Pd/PVP. 2.5% Pd-PVP/C (1 : 2) presented a satisfactory activity with 80% MF yield and 90% selectivity. The reaction kinetics study showed that the transformation of HMF into MF over bifunctional PVP-assisted Pd NPs underwent an acid-catalyzed esterification followed by a Pd-catalyzed hydrogenolysis procedure. The role of formic acid in the transformation is not only as a hydrogen-donating agent but also as a reactant to form the key intermediate. This work provides a novel and environmentally-friendly method for the selective hydrogenation of bio-based HMF to MF.
Language英语
Funding OrganizationNational Key R&D Program of China ; National Key R&D Program of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; National Key R&D Program of China ; National Key R&D Program of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; National Key R&D Program of China ; National Key R&D Program of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; National Key R&D Program of China ; National Key R&D Program of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Higher Education Institutes of China ; Natural Science Foundation of Jiangsu Higher Education Institutes of China
WOS IDWOS:000460322700014
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165927
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Changzhi; Xia, Haian
Affiliation1.Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Prov Key Lab Chem & Utilizat Agroforest B, Nanjing 210037, Jiangsu, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China
Recommended Citation
GB/T 7714
Sun, Guohan,An, Jiahuan,Hu, Hong,et al. Green catalytic synthesis of 5-methylfurfural by selective hydrogenolysis of 5-hydroxymethylfurfural over size-controlled Pd nanoparticle catalysts[J]. CATALYSIS SCIENCE & TECHNOLOGY,2019,9(5):1238-1244.
APA Sun, Guohan,An, Jiahuan,Hu, Hong,Li, Changzhi,Zuo, Songlin,&Xia, Haian.(2019).Green catalytic synthesis of 5-methylfurfural by selective hydrogenolysis of 5-hydroxymethylfurfural over size-controlled Pd nanoparticle catalysts.CATALYSIS SCIENCE & TECHNOLOGY,9(5),1238-1244.
MLA Sun, Guohan,et al."Green catalytic synthesis of 5-methylfurfural by selective hydrogenolysis of 5-hydroxymethylfurfural over size-controlled Pd nanoparticle catalysts".CATALYSIS SCIENCE & TECHNOLOGY 9.5(2019):1238-1244.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Sun, Guohan]'s Articles
[An, Jiahuan]'s Articles
[Hu, Hong]'s Articles
Baidu academic
Similar articles in Baidu academic
[Sun, Guohan]'s Articles
[An, Jiahuan]'s Articles
[Hu, Hong]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Sun, Guohan]'s Articles
[An, Jiahuan]'s Articles
[Hu, Hong]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.