DICP OpenIR
Reversible Hydrogen Uptake/Release over a Sodium Phenoxide-Cyclohexanolate Pair
Yu, Yang1,2; He, Teng1; Wu, Anan3; Pei, Qijun1,2; Karkamkar, Abhijeet4; Autrey, Tom4; Chen, Ping1,5,6
Corresponding AuthorHe, Teng(heteng@dicp.ac.cn) ; Wu, Anan(ananwu@xmu.edu.cn) ; Chen, Ping(pchen@dicp.ac.cn)
Keywordhydrogen storage materials metalation organic hydrides thermodynamic modification
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2019-03-04
ISSN1433-7851
DOI10.1002/anie.201810945
Volume58Issue:10Pages:3102-3107
Funding ProjectNational Natural Science Foundation of China[21875246] ; National Natural Science Foundation of China[51671178] ; National Natural Science Foundation of China[51472237] ; DICP[DICP ZZBS201616] ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology[2016YFE0118300] ; National Science Foundation of China (NSFC)[21773193] ; Fundamental Research Funds for the Central Universities[20720160031] ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; U.S. Department of Energy[DE-AC05-76RL01830] ; iChEM2011
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; National Science Foundation of China (NSFC) ; National Science Foundation of China (NSFC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; U.S. Department of Energy ; U.S. Department of Energy ; iChEM2011 ; iChEM2011 ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; National Science Foundation of China (NSFC) ; National Science Foundation of China (NSFC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; U.S. Department of Energy ; U.S. Department of Energy ; iChEM2011 ; iChEM2011 ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; National Science Foundation of China (NSFC) ; National Science Foundation of China (NSFC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; U.S. Department of Energy ; U.S. Department of Energy ; iChEM2011 ; iChEM2011 ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; National Science Foundation of China (NSFC) ; National Science Foundation of China (NSFC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; U.S. Department of Energy ; U.S. Department of Energy ; iChEM2011 ; iChEM2011
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordACCEPTORLESS DEHYDROGENATION ; NITROGEN-HETEROCYCLES ; CHEMICAL HYDRIDES ; STORAGE MATERIALS ; N-HETEROCYCLES ; SYSTEM ; DISSOCIATION ; PERFORMANCE ; CATALYSIS ; RELEASE
AbstractHydrogen uptake and release in arene-cycloalkane pairs provide an attractive opportunity for on-board and off-board hydrogen storage. However, the efficiency of arene-cycloalkane pairs currently is limited by unfavorable thermodynamics for hydrogen release. It is shown here that the thermodynamics can be optimized by replacement of H in the -OH group of cyclohexanol and phenol with alkali or alkaline earth metals. The enthalpy change upon dehydrogenation decreases substantially, which correlates with the delocalization of the oxygen electron to the benzene ring in phenoxides. Theoretical calculations reveal that replacement of H with a metal leads to a reduction of the HOMO-LUMO energy gap and elongation of the C-H bond in the alpha site in cyclohexanolate, which indicates that the cyclohexanol is activated upon metal substitution. The experimental results demonstrate that sodium phenoxide-cyclohexanolate, an air- and water-stable pair, can desorb hydrogen at ca. 413 K and 373 K in the solid form and in an aqueous solution, respectively. Hydrogenation, on the other hand, is accomplished at temperatures as low as 303 K.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; National Science Foundation of China (NSFC) ; National Science Foundation of China (NSFC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; U.S. Department of Energy ; U.S. Department of Energy ; iChEM2011 ; iChEM2011 ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; National Science Foundation of China (NSFC) ; National Science Foundation of China (NSFC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; U.S. Department of Energy ; U.S. Department of Energy ; iChEM2011 ; iChEM2011 ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; National Science Foundation of China (NSFC) ; National Science Foundation of China (NSFC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; U.S. Department of Energy ; U.S. Department of Energy ; iChEM2011 ; iChEM2011 ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DICP ; DICP ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; Sino-Japanese Research Cooperative Program of the Ministry of Science and Technology ; National Science Foundation of China (NSFC) ; National Science Foundation of China (NSFC) ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; Hydrogen Materials-Advanced Research Consortium (HyMARC), as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office ; U.S. Department of Energy ; U.S. Department of Energy ; iChEM2011 ; iChEM2011
WOS IDWOS:000459709300024
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/165965
Collection中国科学院大连化学物理研究所
Corresponding AuthorHe, Teng; Wu, Anan; Chen, Ping
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Xiamen Univ, Fujian Prov Key Lab Theoret & Computat Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
4.Pacific Northwest Natl Lab, Richland, WA 99352 USA
5.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
6.Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat iChEM 2011, Xiamen 361005, Fujian, Peoples R China
Recommended Citation
GB/T 7714
Yu, Yang,He, Teng,Wu, Anan,et al. Reversible Hydrogen Uptake/Release over a Sodium Phenoxide-Cyclohexanolate Pair[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(10):3102-3107.
APA Yu, Yang.,He, Teng.,Wu, Anan.,Pei, Qijun.,Karkamkar, Abhijeet.,...&Chen, Ping.(2019).Reversible Hydrogen Uptake/Release over a Sodium Phenoxide-Cyclohexanolate Pair.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(10),3102-3107.
MLA Yu, Yang,et al."Reversible Hydrogen Uptake/Release over a Sodium Phenoxide-Cyclohexanolate Pair".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.10(2019):3102-3107.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Yu, Yang]'s Articles
[He, Teng]'s Articles
[Wu, Anan]'s Articles
Baidu academic
Similar articles in Baidu academic
[Yu, Yang]'s Articles
[He, Teng]'s Articles
[Wu, Anan]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Yu, Yang]'s Articles
[He, Teng]'s Articles
[Wu, Anan]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.