DICP OpenIR
Revealing Activity Trends of Metal Diborides Toward pH-Universal Hydrogen Evolution Electrocatalysts with Pt-Like Activity
Li, Qiuju1; Zou, Xu1; Ai, Xuan1; Chen, Hui1; Sun, Lei2; Zou, Xiaoxin1
Corresponding AuthorZou, Xiaoxin(xxzou@jlu.edu.cn)
Keywordd-band center electrocatalysis hydrogen evolution reaction metal diboride non-Pt catalysts
Source PublicationADVANCED ENERGY MATERIALS
2019-02-01
ISSN1614-6832
DOI10.1002/aenm.201803369
Volume9Issue:5Pages:8
Funding ProjectNational Key R&D Program of China[2017YFA0207800] ; National Natural Science Foundation of China (NSFC)[21771079] ; Jilin Province Science and Technology Development Plan[20170101141JC] ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation[161011] ; Postdoctoral Innovative Talent Support Program[BX20180120] ; China Postdoctoral Science Foundation[2018M641771] ; National Natural Science Foundation of China[21621001] ; 111 Project[B17020]
Funding OrganizationNational Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Jilin Province Science and Technology Development Plan ; Jilin Province Science and Technology Development Plan ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation ; Fok Ying Tung Education Foundation ; Postdoctoral Innovative Talent Support Program ; Postdoctoral Innovative Talent Support Program ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Jilin Province Science and Technology Development Plan ; Jilin Province Science and Technology Development Plan ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation ; Fok Ying Tung Education Foundation ; Postdoctoral Innovative Talent Support Program ; Postdoctoral Innovative Talent Support Program ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Jilin Province Science and Technology Development Plan ; Jilin Province Science and Technology Development Plan ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation ; Fok Ying Tung Education Foundation ; Postdoctoral Innovative Talent Support Program ; Postdoctoral Innovative Talent Support Program ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Jilin Province Science and Technology Development Plan ; Jilin Province Science and Technology Development Plan ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation ; Fok Ying Tung Education Foundation ; Postdoctoral Innovative Talent Support Program ; Postdoctoral Innovative Talent Support Program ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS Research AreaChemistry ; Energy & Fuels ; Materials Science ; Physics
WOS KeywordTOTAL-ENERGY CALCULATIONS ; WATER ; NANOTUBES ; CATALYSIS ; DISSOCIATION ; ADSORPTION ; NANOSHEETS ; NANOWIRES ; POINTS
AbstractUnderstanding of catalytic trends is an important prerequisite for providing rational guidance toward the prediction of advanced catalysts as well as the development of original materials design principles. A combined theoretical and experimental study that reveals the periodic trends in electrocatalytic activity for the hydrogen evolution reaction (HER) from Group IV B to Group VIII metal diborides is reported here. Theoretical results demonstrate a general linear relationship between the catalytic activity and d-band center of metal diboride, meaning that the latter can serve as a descriptor of activity. And theoretical results also predict ruthenium diboride as the most competitive, nonplatinum candidate among metal diborides for HER because this material has a suitable d-band center and a high density of efficient active sites. Furthermore, the experimental results validate the theoretical activity trends and identify ruthenium diboride as an efficient, pH-universal electrocatalyst with Pt-like activity for HER under both acidic and alkaline media.
Language英语
Funding OrganizationNational Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Jilin Province Science and Technology Development Plan ; Jilin Province Science and Technology Development Plan ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation ; Fok Ying Tung Education Foundation ; Postdoctoral Innovative Talent Support Program ; Postdoctoral Innovative Talent Support Program ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Jilin Province Science and Technology Development Plan ; Jilin Province Science and Technology Development Plan ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation ; Fok Ying Tung Education Foundation ; Postdoctoral Innovative Talent Support Program ; Postdoctoral Innovative Talent Support Program ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Jilin Province Science and Technology Development Plan ; Jilin Province Science and Technology Development Plan ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation ; Fok Ying Tung Education Foundation ; Postdoctoral Innovative Talent Support Program ; Postdoctoral Innovative Talent Support Program ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Jilin Province Science and Technology Development Plan ; Jilin Province Science and Technology Development Plan ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation ; Fok Ying Tung Education Foundation ; Postdoctoral Innovative Talent Support Program ; Postdoctoral Innovative Talent Support Program ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project
WOS IDWOS:000459624100010
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166013
Collection中国科学院大连化学物理研究所
Corresponding AuthorZou, Xiaoxin
Affiliation1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China
2.Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Li, Qiuju,Zou, Xu,Ai, Xuan,et al. Revealing Activity Trends of Metal Diborides Toward pH-Universal Hydrogen Evolution Electrocatalysts with Pt-Like Activity[J]. ADVANCED ENERGY MATERIALS,2019,9(5):8.
APA Li, Qiuju,Zou, Xu,Ai, Xuan,Chen, Hui,Sun, Lei,&Zou, Xiaoxin.(2019).Revealing Activity Trends of Metal Diborides Toward pH-Universal Hydrogen Evolution Electrocatalysts with Pt-Like Activity.ADVANCED ENERGY MATERIALS,9(5),8.
MLA Li, Qiuju,et al."Revealing Activity Trends of Metal Diborides Toward pH-Universal Hydrogen Evolution Electrocatalysts with Pt-Like Activity".ADVANCED ENERGY MATERIALS 9.5(2019):8.
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