DICP OpenIR
Rhodamine-naphthalimide demonstrated a distinct aggregation-induced emission mechanism: elimination of dark-states via dimer interactions (EDDI)
Qi, Qingkai1; Huang, Lu2,3; Yang, Runqing4; Li, Jin1; Qiao, Qinglong1; Xu, Bin4; Tian, Wenjing4; Liu, Xiaogang2; Xu, Zhaochao1
Corresponding AuthorTian, Wenjing() ; Liu, Xiaogang() ; Xu, Zhaochao(zcxu@dicp.ac.cn)
Source PublicationCHEMICAL COMMUNICATIONS
2019-02-04
ISSN1359-7345
DOI10.1039/c8cc09212e
Volume55Issue:10Pages:1446-1449
Funding ProjectNSF of China[21878286] ; NSF of China[21708039] ; NSF of China[21502189] ; CPSF[2017M611278] ; CPSF[2018T110234] ; DICP[DMTO201603] ; DICP[TMSR201601] ; DICP[2015YB07] ; SUTD[T1SRCI17126] ; SUTD[IDD21700101] ; SUTD[IDG31800104]
Funding OrganizationNSF of China ; NSF of China ; CPSF ; CPSF ; DICP ; DICP ; SUTD ; SUTD ; NSF of China ; NSF of China ; CPSF ; CPSF ; DICP ; DICP ; SUTD ; SUTD ; NSF of China ; NSF of China ; CPSF ; CPSF ; DICP ; DICP ; SUTD ; SUTD ; NSF of China ; NSF of China ; CPSF ; CPSF ; DICP ; DICP ; SUTD ; SUTD
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordINTRAMOLECULAR CHARGE-TRANSFER ; FLUORESCENCE ; LUMINESCENCE ; 2,5-DIPHENYL-1,4-DISTYRYLBENZENE ; DERIVATIVES ; ORGANOGEL ; CRYSTAL ; SWITCH
AbstractRhodamine B-naphthalimide (RhB-Naph) demonstrated a distinct aggregation-induced emission (AIE) mechanism, different from the restriction of intramolecular rotations or vibrations as in traditional AIE molecules. The monomers of RhB-Naph were non-emissive, due to the presence of a dark S-1 state. Upon molecular aggregation, intermolecular interactions significantly altered the electronic properties of RhB-Naph, leading to the formation of a bright S-1 state and endowing RhB-Naph with notable AIE properties. Besides, we demonstrated that RhB-Naph enabled the development of a solid-state three-color fluorescent switch upon multi-external stimuli.
Language英语
Funding OrganizationNSF of China ; NSF of China ; CPSF ; CPSF ; DICP ; DICP ; SUTD ; SUTD ; NSF of China ; NSF of China ; CPSF ; CPSF ; DICP ; DICP ; SUTD ; SUTD ; NSF of China ; NSF of China ; CPSF ; CPSF ; DICP ; DICP ; SUTD ; SUTD ; NSF of China ; NSF of China ; CPSF ; CPSF ; DICP ; DICP ; SUTD ; SUTD
WOS IDWOS:000458546700016
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166023
Collection中国科学院大连化学物理研究所
Corresponding AuthorTian, Wenjing; Liu, Xiaogang; Xu, Zhaochao
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China
2.Singapore Univ Technol & Design, 8 Somapah Rd, Singapore 487372, Singapore
3.Minjiang Univ, Fuzhou 350108, Fujian, Peoples R China
4.Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Jilin, Peoples R China
Recommended Citation
GB/T 7714
Qi, Qingkai,Huang, Lu,Yang, Runqing,et al. Rhodamine-naphthalimide demonstrated a distinct aggregation-induced emission mechanism: elimination of dark-states via dimer interactions (EDDI)[J]. CHEMICAL COMMUNICATIONS,2019,55(10):1446-1449.
APA Qi, Qingkai.,Huang, Lu.,Yang, Runqing.,Li, Jin.,Qiao, Qinglong.,...&Xu, Zhaochao.(2019).Rhodamine-naphthalimide demonstrated a distinct aggregation-induced emission mechanism: elimination of dark-states via dimer interactions (EDDI).CHEMICAL COMMUNICATIONS,55(10),1446-1449.
MLA Qi, Qingkai,et al."Rhodamine-naphthalimide demonstrated a distinct aggregation-induced emission mechanism: elimination of dark-states via dimer interactions (EDDI)".CHEMICAL COMMUNICATIONS 55.10(2019):1446-1449.
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