DICP OpenIR
Highly effective transformation of carbohydrates to 5-Hydroxymethylfurfural with Al- montmorillonite as catalystr
Cao, Jingjie1; Ma, Mingwei1; Liu, Jinchan1; Yang, Yongquan1; Liu, Hui1; Xu, Xingliang2; Huang, Jiahui3; Yue, Huijuan1; Tian, Ge1; Feng, Shouhua1
Corresponding AuthorTian, Ge(tiange@jlu.edu.cn)
KeywordBiomass Energy Carbohydrates 5-hydroxymethylfurfural Catalysis
Source PublicationAPPLIED CATALYSIS A-GENERAL
2019-02-05
ISSN0926-860X
DOI10.1016/j.apcata.2018.12.011
Volume571Pages:96-101
Funding ProjectNational Natural Science Foundation of China[21771086] ; Science and Technology Research Program of the Education Department of Jilin Province, China[JJKH20170778KJ] ; Natural Science Foundation of Jilin Province, China[20180101293JC]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; Natural Science Foundation of Jilin Province, China
WOS SubjectChemistry, Physical ; Environmental Sciences
WOS Research AreaChemistry ; Environmental Sciences & Ecology
WOS KeywordGLUCOSE CONVERSION ; BETA ZEOLITE ; SN-BETA ; ACID ; DEHYDRATION ; FRUCTOSE ; BIOMASS ; LEWIS ; CLAY ; WATER
AbstractAluminum ion-exchanged Ca-montmorillonite with different concentrations of aluminum ion were prepared and applied in the conversion of carbohydrates to 5-hydroxymethylfurfural (HMF). It was found that two types of acid sites were present in the catalyst, Lewis acid sites for isomerization of glucose and Bronsted acid sites for dehydration of fructose. With Al-mont-10 as catalyst, the yield of HMF converted from glucose was 80.4% in a biphase system (THF: NaCl solution) at 180 degrees C for 2.5 h. Further, the catalyst also shows excellent catalytic performance in the conversion of starch and inulin, and the yield of HMF reached 60.1% and 81.6% under identical conditions, respectively.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Science and Technology Research Program of the Education Department of Jilin Province, China ; Natural Science Foundation of Jilin Province, China ; Natural Science Foundation of Jilin Province, China
WOS IDWOS:000457661200010
PublisherELSEVIER SCIENCE BV
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166067
Collection中国科学院大连化学物理研究所
Corresponding AuthorTian, Ge
Affiliation1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun, Jilin, Peoples R China
2.Shandong Agr Univ, Coll Chem & Mat Sci, Tai An, Shandong, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
Recommended Citation
GB/T 7714
Cao, Jingjie,Ma, Mingwei,Liu, Jinchan,et al. Highly effective transformation of carbohydrates to 5-Hydroxymethylfurfural with Al- montmorillonite as catalystr[J]. APPLIED CATALYSIS A-GENERAL,2019,571:96-101.
APA Cao, Jingjie.,Ma, Mingwei.,Liu, Jinchan.,Yang, Yongquan.,Liu, Hui.,...&Feng, Shouhua.(2019).Highly effective transformation of carbohydrates to 5-Hydroxymethylfurfural with Al- montmorillonite as catalystr.APPLIED CATALYSIS A-GENERAL,571,96-101.
MLA Cao, Jingjie,et al."Highly effective transformation of carbohydrates to 5-Hydroxymethylfurfural with Al- montmorillonite as catalystr".APPLIED CATALYSIS A-GENERAL 571(2019):96-101.
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