DICP OpenIR
Production of 1,2-Cyclohexanedicarboxylates from Diacetone Alcohol and Fumarates
Hu, Yancheng1; Yuan, Lin1,2; Zhang, Xiuli1,3; Zhou, Han1,3; Wang, Pan1,3; Li, Guangyi1; Wang, Aiqin1; Cong, Yu1; Zhang, Tao1; Liang, Xinmiao1,3; Li, Wei4; Li, Ning1,5
Corresponding AuthorLi, Wei(liwei820927@nefu.edu.cn) ; Li, Ning(lining@dicp.ac.cn)
KeywordPlasticizers Diacetone alcohol Fumarates Dehydration/Diels-Alder reaction Hydrogenation 1,2-Cyclohexanedicarboxylate
Source PublicationACS SUSTAINABLE CHEMISTRY & ENGINEERING
2019-02-04
ISSN2168-0485
DOI10.1021/acssuschemeng.8b04310
Volume7Issue:3Pages:2980-2988
Funding ProjectNational Natural Science Foundation of China[21690082] ; National Natural Science Foundation of China[21776273] ; National Natural Science Foundation of China[21721004] ; National Natural Science Foundation of China[21801239] ; DNL Cooperation Fund, CAS[DNL180301] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020100] ; National Key Projects for Fundamental Research and Development of China[2016YFA0202801] ; Dalian Science Foundation for Distinguished Young Scholars[201511005]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars
WOS SubjectChemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Engineering
WOS KeywordSUSTAINABLE PRODUCTION ; CATALYTIC CONVERSION ; PLATFORM CHEMICALS ; MALEIC-ANHYDRIDE ; ETHYLENE-GLYCOL ; BIOMASS ; ACID ; PINACOL ; FUELS ; CONDENSATION
Abstract1,2-Cyclohexanedicarboxylates, which are one of the most commonly used plasticizers in the poly(vinyl chloride) (PVC) industry, are generally prepared via the oxidation/esterification/hydrogenation of o-xylene (or naphthalene). Herein, we develop an alternative route toward cyclohexane-based plasticizers using diacetone alcohol and fumarates as the starting materials. The process includes a mild Raney Ni-catalyzed hydrogenation of diacetone alcohol, an one-step dehydration/Diels-Alder reaction of resulting 2-methyl-2,4-pentandiol and fumarates in a choline chloride (ChCl) based deep eutectic solvent (DES), and a further Pd/C-catalyzed hydrogenation. The toxicological tests indicate that the as-synthesized di(2-ethylhexyl) 3,5-dimethylcyclohexane-1,2-dicarboxylate can serve as a safe plasticizer for PVC materials.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; Dalian Science Foundation for Distinguished Young Scholars ; Dalian Science Foundation for Distinguished Young Scholars
WOS IDWOS:000458086100015
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166069
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Wei; Li, Ning
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Key Lab Separat Sci Analyt Chem, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China
4.Northeast Forestry Univ, Key Lab Biobased Mat Sci & Technol, Minist Educ, Hexing Rd 26, Harbin 150040, Heilongjiang, Peoples R China
5.Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Hu, Yancheng,Yuan, Lin,Zhang, Xiuli,et al. Production of 1,2-Cyclohexanedicarboxylates from Diacetone Alcohol and Fumarates[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2019,7(3):2980-2988.
APA Hu, Yancheng.,Yuan, Lin.,Zhang, Xiuli.,Zhou, Han.,Wang, Pan.,...&Li, Ning.(2019).Production of 1,2-Cyclohexanedicarboxylates from Diacetone Alcohol and Fumarates.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,7(3),2980-2988.
MLA Hu, Yancheng,et al."Production of 1,2-Cyclohexanedicarboxylates from Diacetone Alcohol and Fumarates".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7.3(2019):2980-2988.
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