DICP OpenIR
Constructing Mononuclear Palladium Catalysts by Precoordination/Solvothermal Polymerization: Recyclable Catalyst for Regioselective Oxidative Heck Reactions
Li, Wen-Hao1; Li, Cun-Yao2,3; Xiong, Huan-Yan1; Liu, Yang4; Huang, Wen-Yong1; Ji, Guang-Jun2,3; Jiang, Zheng4; Tang, Hai-Tao1; Pan, Ying-Ming1; Ding, Yun-Jie2,3
Corresponding AuthorTang, Hai-Tao(httang@gxnu.edu.cn) ; Pan, Ying-Ming(panym@mailbox.gxnu.edu.cn) ; Ding, Yun-Jie(dyj@dicp.ac.cn)
KeywordHeck reaction heterogeneous catalysis N-heterocyclic carbenes palladium regioselectivity
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2019-02-18
ISSN1433-7851
DOI10.1002/anie.201814493
Volume58Issue:8Pages:2448-2453
Funding ProjectNational Natural Science Foundation of China[21861006] ; National Natural Science Foundation of China[91845101] ; Guangxi Natural Science Foundation of China[2016GXNSFEA380001] ; Guangxi Natural Science Foundation of China[2016GXNSFGA380005] ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources[CMEMR2017-A02] ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources[CMEMR2017-A07]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordHIGH SELECTIVITY ; ACTIVATION ; OLEFINS ; REACTIVITY ; CONVERSION ; LIGAND ; OXYGEN
AbstractHeterogeneous, metal, single-site catalysts often exhibit higher catalytic performance than other catalysts because of their maximized atom efficiency of 100 %. Reported herein is a precoordination/solvothermal polymerization strategy to fabricate a stable mononuclear Pd-metalized porous organic polymer catalyst (Pd@POP). Pd@POP was easy to use in regioselective organic reactions because the internal structure of this Pd@POP can be easily modified. The catalyst was used to solve the intractable regioselectivity problems of Heck reactions. Pd@POP-9 can efficiently activate the ends of olefins, thereby leading to high selectivity for substitution at the external position. To understand the reason underlying the high selectivity and activity of the catalyst, the systemic characterization of Pd@POP-9 and density-functional theory calculations were conducted. This Heck reaction is the first to be catalyzed by a recyclable mononuclear metal catalyst with unprecedented catalytic activity and regioselectivity.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; Guangxi Natural Science Foundation of China ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources ; State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources
WOS IDWOS:000458417700047
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166141
Collection中国科学院大连化学物理研究所
Corresponding AuthorTang, Hai-Tao; Pan, Ying-Ming; Ding, Yun-Jie
Affiliation1.Guangxi Normal Univ, Sch Chem & Pharmaceut Sci, State Key Lab Chem & Mol Engn Med Resources, Guilin 541004, Peoples R China
2.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
4.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
Recommended Citation
GB/T 7714
Li, Wen-Hao,Li, Cun-Yao,Xiong, Huan-Yan,et al. Constructing Mononuclear Palladium Catalysts by Precoordination/Solvothermal Polymerization: Recyclable Catalyst for Regioselective Oxidative Heck Reactions[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(8):2448-2453.
APA Li, Wen-Hao.,Li, Cun-Yao.,Xiong, Huan-Yan.,Liu, Yang.,Huang, Wen-Yong.,...&Ding, Yun-Jie.(2019).Constructing Mononuclear Palladium Catalysts by Precoordination/Solvothermal Polymerization: Recyclable Catalyst for Regioselective Oxidative Heck Reactions.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(8),2448-2453.
MLA Li, Wen-Hao,et al."Constructing Mononuclear Palladium Catalysts by Precoordination/Solvothermal Polymerization: Recyclable Catalyst for Regioselective Oxidative Heck Reactions".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.8(2019):2448-2453.
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