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Synthesis of spiropyrrolidine oxindoles through Rh(II)-catalyzed olefination/cyclization of diazooxindoles and vinyl azides
Yi, Ruxia1,2; Qian, Leilei1,2; Wan, Boshun1
Corresponding AuthorWan, Boshun(bswan@dicp.ac.cn)
KeywordRhodium catalyst Vinyl azides Diazo compounds Spiropyrrolidine oxindoles Olefination [1+1+3] annulation
Source PublicationCHINESE JOURNAL OF CATALYSIS
2019-02-01
ISSN0253-9837
DOI10.1016/S1872-2067(18)63200-0
Volume40Issue:2Pages:177-183
Funding ProjectNational Natural Science Foundation of China[21572225]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordMICHAEL ADDITION/CYCLIZATION ; ENANTIOSELECTIVE SYNTHESIS ; EFFICIENT SYNTHESIS ; INDOLE ALKALOIDS ; CONSTRUCTION ; CYCLOADDITION ; ISATIN ; KETIMINES ; CASCADE
AbstractA simple and efficient process involving the Rh(II)-catalyzed [1+1+3] annulation of diazooxindoles and vinyl azides has been developed for the synthesis of spiropyrrolidine oxindoles with potential biological activity and significant synthetic applications. This process involves a novel rhodium-catalyzed olefination of diazo compounds, followed by annulation with vinyl azides. This method is compatible with a broad range of substrates and affords moderate to good yields under mild reaction conditions. (C) 2019, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China
WOS IDWOS:000457815900006
PublisherSCIENCE PRESS
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Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166157
Collection中国科学院大连化学物理研究所
Corresponding AuthorWan, Boshun
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Yi, Ruxia,Qian, Leilei,Wan, Boshun. Synthesis of spiropyrrolidine oxindoles through Rh(II)-catalyzed olefination/cyclization of diazooxindoles and vinyl azides[J]. CHINESE JOURNAL OF CATALYSIS,2019,40(2):177-183.
APA Yi, Ruxia,Qian, Leilei,&Wan, Boshun.(2019).Synthesis of spiropyrrolidine oxindoles through Rh(II)-catalyzed olefination/cyclization of diazooxindoles and vinyl azides.CHINESE JOURNAL OF CATALYSIS,40(2),177-183.
MLA Yi, Ruxia,et al."Synthesis of spiropyrrolidine oxindoles through Rh(II)-catalyzed olefination/cyclization of diazooxindoles and vinyl azides".CHINESE JOURNAL OF CATALYSIS 40.2(2019):177-183.
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