DICP OpenIR
Rhodium(III)-Catalyzed Enantioselective Coupling of Indoles and 7-Azabenzonorbornadienes by C-H Activation/Desymmetrization
Yang, Xifa2; Zheng, Guangfan1; Li, Xingwei1,2
Corresponding AuthorZheng, Guangfan(zhenggf@snnu.edu.cn) ; Li, Xingwei(lixw@snnu.edu.cn)
KeywordC-H activation desymmetrization heterocycles rhodium synthetic methods
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2019-01-02
ISSN1433-7851
DOI10.1002/anie.201811998
Volume58Issue:1Pages:322-326
Funding ProjectNSFC[21525208] ; NSFC[21472186] ; SNNU
Funding OrganizationNSFC ; NSFC ; SNNU ; SNNU ; NSFC ; NSFC ; SNNU ; SNNU ; NSFC ; NSFC ; SNNU ; SNNU ; NSFC ; NSFC ; SNNU ; SNNU
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordRING-OPENING REACTIONS ; CHIRAL CYCLOPENTADIENYL LIGANDS ; BOND-FORMING REACTIONS ; HETEROBICYCLIC ALKENES ; ACTIVATION ; ARENES ; CATALYSTS ; AZABENZONORBORNADIENES ; HYDROARYLATIONS ; COMPLEXES
AbstractChiral rhodium(III) cyclopentadienyl catalysts ((CpRhIII)-Rh-X) play significant roles in asymmetric arene C-H activation. Rh/Ir-catalyzed couplings of arenes and strained rings have been well-studied, but they have been limited to racemic systems. Reported in this work is the (CpRhIII)-Rh-x/AgSbF6-catalyzed enantioselective desymmetrizative C-C coupling of N-pyrimidylindoles and 7-azabenzonorbornadienes with high efficiency and enantioselectivity. The role of AgSbF6 has been established by mechanistic studies. AgSbF6 enhances the catalytic activity by suppressing the C3-H activation of the indoles, activation which would otherwise lead to catalytically inactive species.
Language英语
Funding OrganizationNSFC ; NSFC ; SNNU ; SNNU ; NSFC ; NSFC ; SNNU ; SNNU ; NSFC ; NSFC ; SNNU ; SNNU ; NSFC ; NSFC ; SNNU ; SNNU
WOS IDWOS:000455818400051
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166175
Collection中国科学院大连化学物理研究所
Corresponding AuthorZheng, Guangfan; Li, Xingwei
Affiliation1.Shaanxi Normal Univ SNNU, Sch Chem & Chem Engn, MOE, Key Lab Appl Surface & Colloid Chem, Xian 710062, Shaanxi, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Yang, Xifa,Zheng, Guangfan,Li, Xingwei. Rhodium(III)-Catalyzed Enantioselective Coupling of Indoles and 7-Azabenzonorbornadienes by C-H Activation/Desymmetrization[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(1):322-326.
APA Yang, Xifa,Zheng, Guangfan,&Li, Xingwei.(2019).Rhodium(III)-Catalyzed Enantioselective Coupling of Indoles and 7-Azabenzonorbornadienes by C-H Activation/Desymmetrization.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(1),322-326.
MLA Yang, Xifa,et al."Rhodium(III)-Catalyzed Enantioselective Coupling of Indoles and 7-Azabenzonorbornadienes by C-H Activation/Desymmetrization".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.1(2019):322-326.
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