DICP OpenIR
The Sommerfeld ground-wave limit for a molecule adsorbed at a surface
Chen, Li1,6; Lau, Jascha A.1,2; Schwarzer, Dirk1; Meyer, Jorg3; Verma, Varun B.4; Wodtke, Alec M.1,2,5
Corresponding AuthorChen, Li(li.chen@mpibpc.mpg.de) ; Wodtke, Alec M.(alec.wodtke@mpibpc.mpg.de)
Source PublicationSCIENCE
2019-01-11
ISSN0036-8075
DOI10.1126/science.aav4278
Volume363Issue:6423Pages:158-+
Funding ProjectNetherlands Organization for Scientific Research (NWO) Vidi grant[723.014.009]
Funding OrganizationNetherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant
WOS SubjectMultidisciplinary Sciences
WOS Research AreaScience & Technology - Other Topics
WOS KeywordENERGY-TRANSFER ; MONOMOLECULAR LAYERS ; POLAR-MOLECULES ; METAL-SURFACES ; CO ; LIFETIME ; MONOLAYER ; NACL(100) ; FLUORESCENCE ; TIME
AbstractUsing a mid-infrared emission spectrometer based on a superconducting nanowire single-photon detector, we observed the dynamics of vibrational energy pooling of carbon monoxide (CO) adsorbed at the surface of a sodium chloride (NaCl) crystal. After exciting a majority of the CO molecules to their first vibrationally excited state (v = 1), we observed infrared emission from states up to v = 27. Kinetic Monte Carlo simulations showed that vibrational energy collects in a few CO molecules at the expense of those up to eight lattice sites away by selective excitation of NaCl's transverse phonons. The vibrating CO molecules behave like classical oscillating dipoles, losing their energy to NaCl lattice vibrations via the electromagnetic near-field. This is analogous to Sommerfeld's description of radio transmission along Earth's surface by ground waves.
Language英语
Funding OrganizationNetherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant ; Netherlands Organization for Scientific Research (NWO) Vidi grant
WOS IDWOS:000455320600046
PublisherAMER ASSOC ADVANCEMENT SCIENCE
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166205
Collection中国科学院大连化学物理研究所
Corresponding AuthorChen, Li; Wodtke, Alec M.
Affiliation1.Max Planck Inst Biophys Chem, Dept Dynam Surfaces, D-37077 Gottingen, Germany
2.Univ Gottingen, Inst Phys Chem, D-37077 Gottingen, Germany
3.Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
4.NIST, Boulder, CO USA
5.Univ Gottingen, Int Ctr Adv Studies Energy Convers, D-37077 Gottingen, Germany
6.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Chen, Li,Lau, Jascha A.,Schwarzer, Dirk,et al. The Sommerfeld ground-wave limit for a molecule adsorbed at a surface[J]. SCIENCE,2019,363(6423):158-+.
APA Chen, Li,Lau, Jascha A.,Schwarzer, Dirk,Meyer, Jorg,Verma, Varun B.,&Wodtke, Alec M..(2019).The Sommerfeld ground-wave limit for a molecule adsorbed at a surface.SCIENCE,363(6423),158-+.
MLA Chen, Li,et al."The Sommerfeld ground-wave limit for a molecule adsorbed at a surface".SCIENCE 363.6423(2019):158-+.
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