DICP OpenIR
Ultralow Loading Cobalt-Based Nanocatalyst for Benign and Efficient Aerobic Oxidation of Allylic Alcohols and Biobased Olefins
Zhao, Xin1; Zhou, Yan1; Huang, Kuan2; Li, Changzhi3; Tao, Duan-Jian1
Corresponding AuthorLi, Changzhi(licz@dicp.ac.cn) ; Tao, Duan-Jian(djtao@jxnu.edu.cn)
KeywordAllylic oxidation Co/N-C catalyst Biobased olefin alpha-Pinene Cinnamyl alcohol
Source PublicationACS SUSTAINABLE CHEMISTRY & ENGINEERING
2019-01-21
ISSN2168-0485
DOI10.1021/acssuschemeng.8b03678
Volume7Issue:2Pages:1901-1908
Funding ProjectNational Natural Science Foundation of China[21566011] ; National Natural Science Foundation of China[31570560] ; National Natural Science Foundation of China[21690080] ; National Natural Science Foundation of China[21690083] ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars[20162BCB23026] ; Programs of Jiangxi Province Department of Education[GJJ160272] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020100] ; National Key R&D Program of China[2016YFA0202801]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Programs of Jiangxi Province Department of Education ; Programs of Jiangxi Province Department of Education ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Programs of Jiangxi Province Department of Education ; Programs of Jiangxi Province Department of Education ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Programs of Jiangxi Province Department of Education ; Programs of Jiangxi Province Department of Education ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Programs of Jiangxi Province Department of Education ; Programs of Jiangxi Province Department of Education ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China
WOS SubjectChemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Engineering
WOS KeywordSELECTIVE OXIDATION ; ALPHA-PINENE ; ACTIVE-SITES ; CATALYST ; OXYGEN ; ZIF-8
AbstractThe synthesis of alpha,beta-unsaturated ketones from aerobic oxidation of allylic alcohols and biobased olefins serves as an important topic in green and sustainable chemistry. In this work, we report the utilization of a sacrificial template ZIF-8 for preparation of mesoporous Co-0.05/N-C material with an ultralow cobalt loading of 0.05 wt %, in which the excellent catalytic performance in aerobic oxidation of alpha-pinene and cinnamyl alcohol was achieved with an 85% yield of verbenone and a yield of cinnamaldehyde, respectively. The results of control experiments and several characterization investigations further illustrate that the sacrificial template ZIF-8 plays a key role to disperse well metallic cobalt in the Co-0.05/N-C-800 catalyst and an appropriate cobalt content of 0.05 wt % is beneficial for benign and efficient aerobic oxidation of various allylic alcohols and biobased olefins. In addition, the Co0.05/N-C-800 catalyst also exhibited good stability and reusability for recovering and reusing at least six times without obvious decrease in catalytic activity. The presented efficient nanocatalyst thus triggers facile synthesis of a series of alpha,beta-unsaturated aldehydes/ketones in high yields.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Programs of Jiangxi Province Department of Education ; Programs of Jiangxi Province Department of Education ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Programs of Jiangxi Province Department of Education ; Programs of Jiangxi Province Department of Education ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Programs of Jiangxi Province Department of Education ; Programs of Jiangxi Province Department of Education ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars ; Programs of Jiangxi Province Department of Education ; Programs of Jiangxi Province Department of Education ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key R&D Program of China ; National Key R&D Program of China
WOS IDWOS:000456631800009
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166245
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Changzhi; Tao, Duan-Jian
Affiliation1.Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China
2.Nanchang Univ, Sch Resources Environm & Chem Engn, Minist Educ, Key Lab Poyang Lake Environm & Resource Utilizat, Nanchang 330031, Jiangxi, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Xin,Zhou, Yan,Huang, Kuan,et al. Ultralow Loading Cobalt-Based Nanocatalyst for Benign and Efficient Aerobic Oxidation of Allylic Alcohols and Biobased Olefins[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2019,7(2):1901-1908.
APA Zhao, Xin,Zhou, Yan,Huang, Kuan,Li, Changzhi,&Tao, Duan-Jian.(2019).Ultralow Loading Cobalt-Based Nanocatalyst for Benign and Efficient Aerobic Oxidation of Allylic Alcohols and Biobased Olefins.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,7(2),1901-1908.
MLA Zhao, Xin,et al."Ultralow Loading Cobalt-Based Nanocatalyst for Benign and Efficient Aerobic Oxidation of Allylic Alcohols and Biobased Olefins".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7.2(2019):1901-1908.
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