DICP OpenIR
The Structure of Hexaaluminate and Application in High-Temperature Reaction
Zhu, Yanyan1; Yue, Zongyang1; Bian, Wen1; Liu, Ruilin1; Ma, Xiaoxun1; Wang, Xiaodong2
Corresponding AuthorZhu, Yanyan(yanyanzhu2006@126.com) ; Wang, Xiaodong(xdwang@dicp.ac.cn)
Keywordhexaaluminate metal substitution high-temperature catalysts oxygen carriers catalytic combustion N2O decomposition chemical looping relationship between structure and reaction performance
Source PublicationPROGRESS IN CHEMISTRY
2018-12-15
ISSN1005-281X
DOI10.7536/PC180406
Volume30Issue:12Pages:1992-2002
Funding ProjectNational Natural Science Foundation of China[21303137] ; National Natural Science Foundation of China[21536009] ; National Natural Science Foundation of China[21676269] ; Cyrus Tang Foundation
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Cyrus Tang Foundation ; Cyrus Tang Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Cyrus Tang Foundation ; Cyrus Tang Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Cyrus Tang Foundation ; Cyrus Tang Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Cyrus Tang Foundation ; Cyrus Tang Foundation
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordALUMINATE SINGLE-CRYSTALS ; CATALYTIC COMBUSTION ; BARIUM HEXAALUMINATE ; SYNTHESIS GAS ; SUBSTITUTED HEXAALUMINATE ; CRYSTALLOGRAPHIC SITES ; PARTIAL OXIDATION ; OXYGEN CARRIER ; BETA-ALUMINA ; METHANE
AbstractHexaaluminate materials exhibit remarkable thermal stability due to their peculiar layered structure. The Al3+ ions in the hexaaluminate lattice can be substituted by transition or noble metals, giving rise to redox centers for a variety of reactions. Oxygen in the mirror plane of hexaaluminate is loosely packed, making it a preferential diffusion route of oxygen. All of these favor the application of hexaaluminate in high-temperature oxygen-involved reaction. In this review, the structure of hexaaluminate is firstly introduced. Furthermore, the effect of structure type (magnetoplumbite and beta-Al2O3) and metal substitution on the microstructure of hexaaluminate (especially metal chemical state) are crefully described. Then we discuss recent advances of hexaaluminate in high-temperature oxygen-involved reactions, such as, catalytic combustion of CH4, process-gas N2O abatement, decomposition of N2O as a propellant, CH4 chemical looping combustion and reforming, with a special emphasis on the relationship between the microstucture and reaction performance. At last, a brief summary and an outlook are given.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Cyrus Tang Foundation ; Cyrus Tang Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Cyrus Tang Foundation ; Cyrus Tang Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Cyrus Tang Foundation ; Cyrus Tang Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Cyrus Tang Foundation ; Cyrus Tang Foundation
WOS IDWOS:000456019900017
PublisherCHINESE ACAD SCIENCES
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166253
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhu, Yanyan; Wang, Xiaodong
Affiliation1.Northwest Univ, Sch Chem Engn,Int Sci & Technol Cooperat Base MOS, Chem Engn Res Ctr,Collaborat Innovat Ctr Dev Ener, Minist Educ Adv Use Technol Shanbei Energy,Shaanx, Xian 710069, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhu, Yanyan,Yue, Zongyang,Bian, Wen,et al. The Structure of Hexaaluminate and Application in High-Temperature Reaction[J]. PROGRESS IN CHEMISTRY,2018,30(12):1992-2002.
APA Zhu, Yanyan,Yue, Zongyang,Bian, Wen,Liu, Ruilin,Ma, Xiaoxun,&Wang, Xiaodong.(2018).The Structure of Hexaaluminate and Application in High-Temperature Reaction.PROGRESS IN CHEMISTRY,30(12),1992-2002.
MLA Zhu, Yanyan,et al."The Structure of Hexaaluminate and Application in High-Temperature Reaction".PROGRESS IN CHEMISTRY 30.12(2018):1992-2002.
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