DICP OpenIR
Synthesis, Characterization and Luminescent Properties of Two Copper(I) Complexes Based on 2,2 '-Biquinoline and Phosphorous Ligand
Sun Ling-Zhi1; Wang Yu1; Lin Sen1; Liu Jian-Ming2; Li Zhong-Feng1; Zhang Jiang-Wei3; Jin Qiong-Hua1
Corresponding AuthorJin Qiong-Hua(jinqh@cnu.edu.cn)
Keywordcopper crystal structures 2,2 '-biquinoline luminescence
Source PublicationCHINESE JOURNAL OF STRUCTURAL CHEMISTRY
2018-08-15
ISSN0254-5861
DOI10.14102/j.cnki.0254-5861.2011-1942
Volume37Issue:8Pages:1313-1322
Funding ProjectNational Natural Science Foundation of China[21171119] ; National Natural Science Foundation of China[81573822] ; Beijing Municipal Natural Science Foundation[2172017]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Beijing Municipal Natural Science Foundation ; Beijing Municipal Natural Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Beijing Municipal Natural Science Foundation ; Beijing Municipal Natural Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Beijing Municipal Natural Science Foundation ; Beijing Municipal Natural Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Beijing Municipal Natural Science Foundation ; Beijing Municipal Natural Science Foundation
WOS SubjectChemistry, Inorganic & Nuclear ; Crystallography
WOS Research AreaChemistry ; Crystallography
WOS KeywordSTRUCTURAL-CHARACTERIZATION ; SILVER(I) COMPLEXES ; SERIES ; ANION
AbstractThree new copper(I) complexes, namely [Cu(DPEphos)(Biq)]CF3SO3 (1) and [Cu(PPh3)(2)(Biq)]CF3SO3 (2) and [Cu(PPh3)(2)(Biq)]ClO4(3) (DPEphos = bis [2-(diphenylphosp hino)phenyl]ether, PPh3 = triphenylphosphine and Biq = 2,2'-biquinoline), are synthesized and characterized by IR, H-1 NMR, P-31 NMR, fluorescence spectra and terahertz time-domain spectroscopy (THz-TDS). Complex 1 crystallizes in triclinic, space group P (1) over bar with a = 12.6997(5), b = 13.2813(5), c = 15.3593(6) angstrom, alpha = 80.211(3)degrees, beta= 88.752(3)degrees, gamma = 70.113(3)degrees, V = 2398.85(15) angstrom(3), C55H41.2CUF3N2O2,M-r = 1018.27, Z = 2, D-c = 1.410 g/cm(3), F(000) = 1048, mu = 0.628 mm(-1), the final R = 0.0450 and wR = 0.1105 for 9419 observed reflections (I > 2 sigma(I)). Complex 2 crystallizes in monoclinic, space group C2/c with a = 19.9961(7), b = 15.9774(5), c = 17.7908(6) angstrom, beta = 119.758(4)degrees, V = 4982.8(3) angstrom(3), C56.47H47.88CuF3N2O4.47P2S, Mr = 1040.54, Z = 4, D-c = 1.387 g/cm(3), F(000) = 2154, mu = 0.606 mm(-1), the final R = 0.0430 and wR = 0.1218 for 4897 observed reflections (I > 2 sigma(I)). Complex 3 crystallizes in monoclinic, space group C2/c with a = 19.7534(8), b = 15.0797(5), c = 17.8097(7) angstrom, beta = 116.400(5)degrees, V = 4751.8(3) angstrom(3), C-56 H(45)C1CuN(3)O(4)P(2), M-r= 984.88, Z = 4, D-c= 1.377 g/cm(3), F(000) = 2040, mu = 0.635 mm(-1), the final R = 0.0731 and wR = 0.2180 for 4670 observed reflections (I > 2 sigma(I)). In the emission spectra, shifts of emission peak are derived from ligand-centered (pi-pi*) transition.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Beijing Municipal Natural Science Foundation ; Beijing Municipal Natural Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Beijing Municipal Natural Science Foundation ; Beijing Municipal Natural Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Beijing Municipal Natural Science Foundation ; Beijing Municipal Natural Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Beijing Municipal Natural Science Foundation ; Beijing Municipal Natural Science Foundation
WOS IDWOS:000454083000015
PublisherCHINESE JOURNAL STRUCTURAL CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166339
Collection中国科学院大连化学物理研究所
Corresponding AuthorJin Qiong-Hua
Affiliation1.Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China
2.Peking Univ, Sch Math Sci, Beijing 100871, Peoples R China
3.Chinese Acad Sci, Gold Catalysis Res Ctr, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Sun Ling-Zhi,Wang Yu,Lin Sen,et al. Synthesis, Characterization and Luminescent Properties of Two Copper(I) Complexes Based on 2,2 '-Biquinoline and Phosphorous Ligand[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2018,37(8):1313-1322.
APA Sun Ling-Zhi.,Wang Yu.,Lin Sen.,Liu Jian-Ming.,Li Zhong-Feng.,...&Jin Qiong-Hua.(2018).Synthesis, Characterization and Luminescent Properties of Two Copper(I) Complexes Based on 2,2 '-Biquinoline and Phosphorous Ligand.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,37(8),1313-1322.
MLA Sun Ling-Zhi,et al."Synthesis, Characterization and Luminescent Properties of Two Copper(I) Complexes Based on 2,2 '-Biquinoline and Phosphorous Ligand".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 37.8(2018):1313-1322.
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