DICP OpenIR
Modulation synthesis of multi-shelled cobalt-iron oxides as efficient catalysts for peroxymonosulfate-mediated organics degradation
Zhu, Kaixin1,2; Jin, Changzi3; Zhao, Chunxiao1,4; Hu, Ruisheng4; Klencsar, Zoltan5; Sundaram, Ganeshraja Ayyakannu1; Sranko, David F.6; Ge, Rile1; Wang, Junhu1
Corresponding AuthorWang, Junhu(wangjh@dicp.ac.cn)
KeywordCobalt-iron oxides Multi-shelled morphology Peroxymonosulfate Organics degradation
Source PublicationCHEMICAL ENGINEERING JOURNAL
2019-03-01
ISSN1385-8947
DOI10.1016/j.cej.2018.11.018
Volume359Pages:1537-1549
Funding ProjectNational Natural Science Foundation of China[21476232] ; National Natural Science Foundation of China[21403220] ; National Natural Science Foundation of China[2161101071] ; Ministry of Science and Technology of China[2016YFA0202804] ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences[2016PT023] ; Chinese-Hungarian bilateral project[NKFIH TET_15-1-2016-0120] ; National Research, Development and Innovation Office[NKFIH PD 121318]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; Chinese-Hungarian bilateral project ; Chinese-Hungarian bilateral project ; National Research, Development and Innovation Office ; National Research, Development and Innovation Office ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; Chinese-Hungarian bilateral project ; Chinese-Hungarian bilateral project ; National Research, Development and Innovation Office ; National Research, Development and Innovation Office ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; Chinese-Hungarian bilateral project ; Chinese-Hungarian bilateral project ; National Research, Development and Innovation Office ; National Research, Development and Innovation Office ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; Chinese-Hungarian bilateral project ; Chinese-Hungarian bilateral project ; National Research, Development and Innovation Office ; National Research, Development and Innovation Office
WOS SubjectEngineering, Environmental ; Engineering, Chemical
WOS Research AreaEngineering
WOS KeywordFENTON-LIKE OXIDATION ; HOLLOW SPHERES ; HETEROGENEOUS ACTIVATION ; GENERAL-SYNTHESIS ; ORANGE II ; NANOPARTICLES ; COFE2O4 ; SPINEL ; GRAPHENE ; CO3O4
AbstractSimple-controlled synthesis of multiple porous and monodisperse cobalt-iron oxides were realized by varying the prepared conditions via a template-assisted glycol solvothermal process. The obtained materials were characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, Mossbauer spectroscopy and nitrogen adsorption/desorption measurement. It was found that the amounts of metal precursors and the Co:Fe ratio significantly influenced the morphology, the crystallinity, as well as the textural and electronic properties of the cobalt-iron products. The different cobalt-iron oxides with various shells were employed into the catalytic activation of peroxymonosulfate (PMS) for Orange II degradation, among which, multishelled cobalt ferrite microsphere was certified to perform the best activity due to the coefficient contribution of higher content of octahedral Co2+, more exposed active sites and the reservoir effect. Sulfate and hydroxyl radicals were crucial reactive species in Orange II degradation, proved by the scavenger quenching test. This work shows that cobalt-iron oxide microspheres with such architecture make differences in the PMS-mediated aqueous organics degradation system, which extends the perspective and application of such functional oxides in the environmental field.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; Chinese-Hungarian bilateral project ; Chinese-Hungarian bilateral project ; National Research, Development and Innovation Office ; National Research, Development and Innovation Office ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; Chinese-Hungarian bilateral project ; Chinese-Hungarian bilateral project ; National Research, Development and Innovation Office ; National Research, Development and Innovation Office ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; Chinese-Hungarian bilateral project ; Chinese-Hungarian bilateral project ; National Research, Development and Innovation Office ; National Research, Development and Innovation Office ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; CAS President's International Fellowship Initiative (PIFI) programme - Chinese Academy of Sciences ; Chinese-Hungarian bilateral project ; Chinese-Hungarian bilateral project ; National Research, Development and Innovation Office ; National Research, Development and Innovation Office
WOS IDWOS:000454137400148
PublisherELSEVIER SCIENCE SA
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166363
Collection中国科学院大连化学物理研究所
Corresponding AuthorWang, Junhu
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Div Fossil Energy Convers, Dalian 116023, Peoples R China
4.Inner Mongolia Univ, Sch Chem & Chem Engn, Hohhot 010021, Peoples R China
5.Hungarian Acad Sci, Ctr Energy Res, Inst Energy Secur & Environm Safety, Nucl Anal & Radiog Dept, Konkoly Thege Miklos Ut 29-33, H-1121 Budapest, Hungary
6.Hungarian Acad Sci, Ctr Energy Res, Surface Chem & Catalysis Dept, Konkoly Thege Miklos Ut 29-33, H-1121 Budapest, Hungary
Recommended Citation
GB/T 7714
Zhu, Kaixin,Jin, Changzi,Zhao, Chunxiao,et al. Modulation synthesis of multi-shelled cobalt-iron oxides as efficient catalysts for peroxymonosulfate-mediated organics degradation[J]. CHEMICAL ENGINEERING JOURNAL,2019,359:1537-1549.
APA Zhu, Kaixin.,Jin, Changzi.,Zhao, Chunxiao.,Hu, Ruisheng.,Klencsar, Zoltan.,...&Wang, Junhu.(2019).Modulation synthesis of multi-shelled cobalt-iron oxides as efficient catalysts for peroxymonosulfate-mediated organics degradation.CHEMICAL ENGINEERING JOURNAL,359,1537-1549.
MLA Zhu, Kaixin,et al."Modulation synthesis of multi-shelled cobalt-iron oxides as efficient catalysts for peroxymonosulfate-mediated organics degradation".CHEMICAL ENGINEERING JOURNAL 359(2019):1537-1549.
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