DICP OpenIR
Biomass-Derived Graphene-like Carbon: Efficient Metal-Free Carbocatalysts for Epoxidation
Wen, Guodong1; Gu, Qingqing1; Liu, Yuefeng2; Schloegl, Robert3; Wang, Congxin2; Tian, Zhijian2; Su, Dang Sheng1,2
Corresponding AuthorWen, Guodong(wengd@imr.ac.cn) ; Su, Dang Sheng(dssu@imr.ac.cn)
Keywordbiomass carbocatalysts epoxidations graphene metal-free processes
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2018-12-17
ISSN1433-7851
DOI10.1002/anie.201809970
Volume57Issue:51Pages:16898-16902
Funding ProjectNational Natural Science Foundation of China[21503241] ; National Natural Science Foundation of China[21411130120] ; National Natural Science Foundation of China[51521091] ; National Natural Science Foundation of China[21473223] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordHYDROTHERMAL CARBON ; AEROBIC OXIDATION ; ACTIVE-SITES ; LIQUID-PHASE ; CYCLOHEXANE ; STYRENE ; OXYGEN ; NANOCARBONS ; CATALYSIS ; NANOTUBES
AbstractN-doped graphene-like layered carbon (NG) could be synthesized via a metal-free pyrolysis route from glucose, fructose, and 5-hydroxymethylfurfural (5-HMF), which are cheap and widely available biomass or biomass derivatives. A well-developed thin-layer structure with large lateral dimensions could be obtained when 5-HMF was used as the precursor. More importantly, the 5-HMF-derived NG gave superior performance in epoxidation reactions compared with the conventional carbon catalysts and the performance of 5-HMF derived NG was even similar to that of a cobalt catalyst. Characterizations by TEM and XPS accompanied by EPR analysis revealed that the enhanced catalytic properties for NG arise from its high activation ability for both alkenes and O-2, which are attributed to the graphitic layered structure and graphitic N species, respectively.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences
WOS IDWOS:000453348900057
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166427
Collection中国科学院大连化学物理研究所
Corresponding AuthorWen, Guodong; Su, Dang Sheng
Affiliation1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
3.Max Planck Gesell, Fritz Haber Inst, Faradayweg 4-6, D-14195 Berlin, Germany
Recommended Citation
GB/T 7714
Wen, Guodong,Gu, Qingqing,Liu, Yuefeng,et al. Biomass-Derived Graphene-like Carbon: Efficient Metal-Free Carbocatalysts for Epoxidation[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(51):16898-16902.
APA Wen, Guodong.,Gu, Qingqing.,Liu, Yuefeng.,Schloegl, Robert.,Wang, Congxin.,...&Su, Dang Sheng.(2018).Biomass-Derived Graphene-like Carbon: Efficient Metal-Free Carbocatalysts for Epoxidation.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(51),16898-16902.
MLA Wen, Guodong,et al."Biomass-Derived Graphene-like Carbon: Efficient Metal-Free Carbocatalysts for Epoxidation".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.51(2018):16898-16902.
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