DICP OpenIR
High performance ambient-air-stable FAPbI(3) perovskite solar cells with molecule-passivated Ruddlesden-Popper/3D heterostructured film
Niu, Tianqi1; Lu, Jing1; Tang, Ming-Chun2,3; Barrit, Dounya2,3; Smilgies, Detlef-M.4; Yang, Zhou1; Li, Jianbo1; Fan, Yuanyuan1; Luo, Tao1; McCulloch, Iain2,3; Amassian, Aram2,3; Liu, Shengzhong (Frank)1,5; Zhao, Kui1
Corresponding AuthorAmassian, Aram(aram.amassian@kaust.edu.sa) ; Liu, Shengzhong (Frank)(szliu@dicp.ac.cn) ; Zhao, Kui(zhaok@snnu.edu.cn)
Source PublicationENERGY & ENVIRONMENTAL SCIENCE
2018-12-01
ISSN1754-5692
DOI10.1039/c8ee02542h
Volume11Issue:12Pages:3358-3366
Funding ProjectNational Key Research and Development Program of China[2017YFA0204800] ; National Key Research and Development Program of China[2016YFA0202403] ; National Natural Science Foundation of China[61604092] ; National Natural Science Foundation of China[61674098] ; National University Research Fund[GK201802005] ; 111 Project[B14041] ; National 1000 Talents Plan program[1110010341] ; King Abdullah University for Science and Technology (KAUST) ; NSF Award[DMR-1332208]
Funding OrganizationNational Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National University Research Fund ; National University Research Fund ; 111 Project ; 111 Project ; National 1000 Talents Plan program ; National 1000 Talents Plan program ; King Abdullah University for Science and Technology (KAUST) ; King Abdullah University for Science and Technology (KAUST) ; NSF Award ; NSF Award ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National University Research Fund ; National University Research Fund ; 111 Project ; 111 Project ; National 1000 Talents Plan program ; National 1000 Talents Plan program ; King Abdullah University for Science and Technology (KAUST) ; King Abdullah University for Science and Technology (KAUST) ; NSF Award ; NSF Award ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National University Research Fund ; National University Research Fund ; 111 Project ; 111 Project ; National 1000 Talents Plan program ; National 1000 Talents Plan program ; King Abdullah University for Science and Technology (KAUST) ; King Abdullah University for Science and Technology (KAUST) ; NSF Award ; NSF Award ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National University Research Fund ; National University Research Fund ; 111 Project ; 111 Project ; National 1000 Talents Plan program ; National 1000 Talents Plan program ; King Abdullah University for Science and Technology (KAUST) ; King Abdullah University for Science and Technology (KAUST) ; NSF Award ; NSF Award
WOS SubjectChemistry, Multidisciplinary ; Energy & Fuels ; Engineering, Chemical ; Environmental Sciences
WOS Research AreaChemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology
WOS KeywordLEAD IODIDE PEROVSKITES ; HALIDE PEROVSKITES ; ELECTRON-ACCEPTOR ; DEGRADATION ; EFFICIENCY ; STABILITY ; TRIHALIDE ; DYNAMICS ; SNO2 ; TIN
AbstractAmbient stability remains a critical hurdle for commercialization of perovskite solar cells. Two-dimensional Ruddlesden-Popper (RP) perovskite solar cells exhibit excellent stability but suffer from low photovoltaic performance so far. Herein, a RP/3D heterostructure passivated by semiconducting molecules is reported, which systematically addresses both charge dynamics and degradation mechanisms in concert for cesium-free FAPbI(3) solar cells, delivering a power-conversion efficiency as high as 20.62% and remarkable long-term ambient stability with a t(80) lifetime exceeding 2880 hours without encapsulation. In situ characterizations were carried out to gain insight into structural evolution and crystal growth mechanisms during spin coating. Comprehensive film and device characterizations were performed to understand the influences of the RP perovskite and molecule passivation on the film quality, photovoltaic performance and degradation mechanisms. This enables fabrication of a superior quality film with significantly improved optoelectronic properties, which lead to higher charge collection efficiency. The underlying mitigated degradation mechanisms of the passivated RP/3D devices were further elucidated. The understanding of the necessity of addressing both the charge dynamics and degradation mechanisms of solar cells will guide the future design and fabrication of chemically stable, high-efficiency photovoltaic devices.
Language英语
Funding OrganizationNational Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National University Research Fund ; National University Research Fund ; 111 Project ; 111 Project ; National 1000 Talents Plan program ; National 1000 Talents Plan program ; King Abdullah University for Science and Technology (KAUST) ; King Abdullah University for Science and Technology (KAUST) ; NSF Award ; NSF Award ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National University Research Fund ; National University Research Fund ; 111 Project ; 111 Project ; National 1000 Talents Plan program ; National 1000 Talents Plan program ; King Abdullah University for Science and Technology (KAUST) ; King Abdullah University for Science and Technology (KAUST) ; NSF Award ; NSF Award ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National University Research Fund ; National University Research Fund ; 111 Project ; 111 Project ; National 1000 Talents Plan program ; National 1000 Talents Plan program ; King Abdullah University for Science and Technology (KAUST) ; King Abdullah University for Science and Technology (KAUST) ; NSF Award ; NSF Award ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National University Research Fund ; National University Research Fund ; 111 Project ; 111 Project ; National 1000 Talents Plan program ; National 1000 Talents Plan program ; King Abdullah University for Science and Technology (KAUST) ; King Abdullah University for Science and Technology (KAUST) ; NSF Award ; NSF Award
WOS IDWOS:000452317700004
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166483
Collection中国科学院大连化学物理研究所
Corresponding AuthorAmassian, Aram; Liu, Shengzhong (Frank); Zhao, Kui
Affiliation1.Shaanxi Normal Univ, Shaanxi Key Lab Adv Energy Devices, Shaanxi Engn Lab Adv Energy Technol,Minist Educ, Sch Mat Sci & Engn,Key Lab Appl Surface & Colloid, Xian 710119, Shaanxi, Peoples R China
2.King Abdullah Univ Sci & Technol, KAUST Solar Ctr KSC, Thuwal 239556900, Saudi Arabia
3.King Abdullah Univ Sci & Technol, Phys Sci & Engn Div PSE, Thuwal 239556900, Saudi Arabia
4.Cornell Univ, Cornell High Energy Synchrotron Source, Ithaca, NY 14850 USA
5.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Niu, Tianqi,Lu, Jing,Tang, Ming-Chun,et al. High performance ambient-air-stable FAPbI(3) perovskite solar cells with molecule-passivated Ruddlesden-Popper/3D heterostructured film[J]. ENERGY & ENVIRONMENTAL SCIENCE,2018,11(12):3358-3366.
APA Niu, Tianqi.,Lu, Jing.,Tang, Ming-Chun.,Barrit, Dounya.,Smilgies, Detlef-M..,...&Zhao, Kui.(2018).High performance ambient-air-stable FAPbI(3) perovskite solar cells with molecule-passivated Ruddlesden-Popper/3D heterostructured film.ENERGY & ENVIRONMENTAL SCIENCE,11(12),3358-3366.
MLA Niu, Tianqi,et al."High performance ambient-air-stable FAPbI(3) perovskite solar cells with molecule-passivated Ruddlesden-Popper/3D heterostructured film".ENERGY & ENVIRONMENTAL SCIENCE 11.12(2018):3358-3366.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Niu, Tianqi]'s Articles
[Lu, Jing]'s Articles
[Tang, Ming-Chun]'s Articles
Baidu academic
Similar articles in Baidu academic
[Niu, Tianqi]'s Articles
[Lu, Jing]'s Articles
[Tang, Ming-Chun]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Niu, Tianqi]'s Articles
[Lu, Jing]'s Articles
[Tang, Ming-Chun]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.