DICP OpenIR
A study of FeNx/C catalysts for the selective oxidation of unsaturated alcohols by molecular oxygen
Zhang, Jinping1; Nagamatsu, Shinichi2; Du, Junmou1; Tong, Chaoli1; Fang, Huihuang1; Deng, Dehui1,3; Liu, Xi4; Asakura, Kiyotaka2; Yuan, Youzhu1
Corresponding AuthorAsakura, Kiyotaka(askr@cat.hokudai.ac.jp) ; Yuan, Youzhu(yzyuan@xmu.edu.cn)
KeywordFeNx/C catalysts Selective oxidation Unsaturated alcohol Characterization Regeneration
Source PublicationJOURNAL OF CATALYSIS
2018-11-01
ISSN0021-9517
DOI10.1016/j.jcat.2018.08.004
Volume367Pages:16-26
Funding ProjectNational Key R&D Program of China[2017YFA0206801] ; National Natural Science Foundation of China[91545115] ; National Natural Science Foundation of China[21473145] ; JST-CREST project Innovative Catalysts[JPMJCR15P4] ; Program for Innovative Research Teams in Chinese Universities[IRT_14R31]
Funding OrganizationNational Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; JST-CREST project Innovative Catalysts ; JST-CREST project Innovative Catalysts ; Program for Innovative Research Teams in Chinese Universities ; Program for Innovative Research Teams in Chinese Universities ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; JST-CREST project Innovative Catalysts ; JST-CREST project Innovative Catalysts ; Program for Innovative Research Teams in Chinese Universities ; Program for Innovative Research Teams in Chinese Universities ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; JST-CREST project Innovative Catalysts ; JST-CREST project Innovative Catalysts ; Program for Innovative Research Teams in Chinese Universities ; Program for Innovative Research Teams in Chinese Universities ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; JST-CREST project Innovative Catalysts ; JST-CREST project Innovative Catalysts ; Program for Innovative Research Teams in Chinese Universities ; Program for Innovative Research Teams in Chinese Universities
WOS SubjectChemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordEFFICIENT AEROBIC OXIDATION ; NITROGEN-DOPED CARBON ; N-C CATALYST ; ACTIVE-SITES ; GOLD NANOPARTICLES ; REDUCTION REACTION ; 2,5-DIFORMYLFURAN ; ELECTROCATALYSTS ; PERFORMANCE ; IRON
AbstractTransition-metal nitrides can exhibit catalytic performance comparable to that of noble metal catalysts in many reactions. However, investigations on the correlation of catalyst structure, performance, and stability are still highly demanded. Here, a series of metal nitrides were prepared and evaluated for the selective oxidation of alcohols by molecular oxygen. Among them, FeNx/C-T catalysts (T represents the pyrolysis temperature) display above 95% selectivity to the corresponding aldehydes in the selective oxidation of unsaturated alcohols. The optimized FeNx/C-900 catalyst gives the highest TOF of 7.0 h(-1) for the conversion of 5-hydroxymethylfurfural to 2,5-diformylfuran. A combination of characterizations and experiments suggests that Fe-N-4 species are the main active sites. In addition, we investigate the reasons for the catalyst deactivation and provide an effective approach to regenerating the catalysts. The results indicate that the deactivated catalysts can be regenerated by heat treatment under NH3/N-2 after each run. Based on these studies, a plausible reaction mechanism over the FeNx/C catalysts is proposed. (C) 2018 Elsevier Inc. All rights reserved.
Language英语
Funding OrganizationNational Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; JST-CREST project Innovative Catalysts ; JST-CREST project Innovative Catalysts ; Program for Innovative Research Teams in Chinese Universities ; Program for Innovative Research Teams in Chinese Universities ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; JST-CREST project Innovative Catalysts ; JST-CREST project Innovative Catalysts ; Program for Innovative Research Teams in Chinese Universities ; Program for Innovative Research Teams in Chinese Universities ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; JST-CREST project Innovative Catalysts ; JST-CREST project Innovative Catalysts ; Program for Innovative Research Teams in Chinese Universities ; Program for Innovative Research Teams in Chinese Universities ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; JST-CREST project Innovative Catalysts ; JST-CREST project Innovative Catalysts ; Program for Innovative Research Teams in Chinese Universities ; Program for Innovative Research Teams in Chinese Universities
WOS IDWOS:000452578700003
PublisherACADEMIC PRESS INC ELSEVIER SCIENCE
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166487
Collection中国科学院大连化学物理研究所
Corresponding AuthorAsakura, Kiyotaka; Yuan, Youzhu
Affiliation1.Xiamen Univ, Coll Chem & Chem Engn, Natl Engn Lab Green Chem Prod Alcohols Ethers Est, State Key Lab Phys Chem Solid Surfaces,iChEM, Xiamen 361005, Peoples R China
2.Hokkaido Univ, Inst Catalysis, Kita Ku, Kita 21,Nishi 10, Sapporo, Hokkaido 0010021, Japan
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, iChEM, Dalian 116023, Peoples R China
4.Synfuels China Technol Co Ltd, Beijing 101407, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Jinping,Nagamatsu, Shinichi,Du, Junmou,et al. A study of FeNx/C catalysts for the selective oxidation of unsaturated alcohols by molecular oxygen[J]. JOURNAL OF CATALYSIS,2018,367:16-26.
APA Zhang, Jinping.,Nagamatsu, Shinichi.,Du, Junmou.,Tong, Chaoli.,Fang, Huihuang.,...&Yuan, Youzhu.(2018).A study of FeNx/C catalysts for the selective oxidation of unsaturated alcohols by molecular oxygen.JOURNAL OF CATALYSIS,367,16-26.
MLA Zhang, Jinping,et al."A study of FeNx/C catalysts for the selective oxidation of unsaturated alcohols by molecular oxygen".JOURNAL OF CATALYSIS 367(2018):16-26.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhang, Jinping]'s Articles
[Nagamatsu, Shinichi]'s Articles
[Du, Junmou]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhang, Jinping]'s Articles
[Nagamatsu, Shinichi]'s Articles
[Du, Junmou]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, Jinping]'s Articles
[Nagamatsu, Shinichi]'s Articles
[Du, Junmou]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.