DICP OpenIR
Multi- functional nanowall arrays with unrestricted Li plus transport channels and an integrated conductive network for high- areal- capacity Li- S batteries
Yang, Xiaofei1,2,3; Yu, Ying2,3; Lin, Xiaoting1; Liang, Jianneng1; Adair, Keegan1; Zhao, Yang1; Wang, Changhong1; Li, Xia1; Sun, Qian1; Zhang, Hongzhang2,4; Li, Xianfeng4; Li, Ruying1; Zhang, Huamin2,4; Sun, Xueliang1
Corresponding AuthorZhang, Hongzhang(zhanghz@dicp.ac.cn) ; Zhang, Huamin() ; Sun, Xueliang()
Source PublicationJOURNAL OF MATERIALS CHEMISTRY A
2018-12-07
ISSN2050-7488
DOI10.1039/c8ta08188c
Volume6Issue:45Pages:22958-22965
Funding ProjectNatural Science and Engineering Research Council of Canada (NSERC) ; Canada Research Chair Program (CRC) ; Canada Foundation for Innovation (CFI) ; University of Western Ontario (UWO) ; National Natural Science Foundation of China[51403209] ; National Natural Science Foundation of China[51677176] ; National Natural Science Foundation of China[51673199] ; National Natural Science Foundation of China[21406221] ; National Natural Science Foundation of China[51177156/E0712] ; Youth Innovation Promotion Association[2015148] ; Natural Sciences Foundation of Liaoning Province of China[2013020126] ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics[201307] ; China Scholarship Council
Funding OrganizationNatural Science and Engineering Research Council of Canada (NSERC) ; Natural Science and Engineering Research Council of Canada (NSERC) ; Canada Research Chair Program (CRC) ; Canada Research Chair Program (CRC) ; Canada Foundation for Innovation (CFI) ; Canada Foundation for Innovation (CFI) ; University of Western Ontario (UWO) ; University of Western Ontario (UWO) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; Natural Sciences Foundation of Liaoning Province of China ; Natural Sciences Foundation of Liaoning Province of China ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; China Scholarship Council ; China Scholarship Council ; Natural Science and Engineering Research Council of Canada (NSERC) ; Natural Science and Engineering Research Council of Canada (NSERC) ; Canada Research Chair Program (CRC) ; Canada Research Chair Program (CRC) ; Canada Foundation for Innovation (CFI) ; Canada Foundation for Innovation (CFI) ; University of Western Ontario (UWO) ; University of Western Ontario (UWO) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; Natural Sciences Foundation of Liaoning Province of China ; Natural Sciences Foundation of Liaoning Province of China ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; China Scholarship Council ; China Scholarship Council ; Natural Science and Engineering Research Council of Canada (NSERC) ; Natural Science and Engineering Research Council of Canada (NSERC) ; Canada Research Chair Program (CRC) ; Canada Research Chair Program (CRC) ; Canada Foundation for Innovation (CFI) ; Canada Foundation for Innovation (CFI) ; University of Western Ontario (UWO) ; University of Western Ontario (UWO) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; Natural Sciences Foundation of Liaoning Province of China ; Natural Sciences Foundation of Liaoning Province of China ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; China Scholarship Council ; China Scholarship Council ; Natural Science and Engineering Research Council of Canada (NSERC) ; Natural Science and Engineering Research Council of Canada (NSERC) ; Canada Research Chair Program (CRC) ; Canada Research Chair Program (CRC) ; Canada Foundation for Innovation (CFI) ; Canada Foundation for Innovation (CFI) ; University of Western Ontario (UWO) ; University of Western Ontario (UWO) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; Natural Sciences Foundation of Liaoning Province of China ; Natural Sciences Foundation of Liaoning Province of China ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; China Scholarship Council ; China Scholarship Council
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Energy & Fuels ; Materials Science
WOS KeywordLITHIUM-SULFUR BATTERY ; CARBON NANOTUBE GROWTH ; LONG-CYCLE STABILITY ; CATHODE MATERIAL ; ELECTRODE MATERIALS ; COMPOSITE CATHODES ; RATE PERFORMANCE ; BASE-GROWTH ; POLYSULFIDE ; NANOPARTICLES
AbstractThe rational design of cathode hosts with superior polysulfide (PS) confinement properties, excellent Li+/e(-) transport and improved cyclability is of the utmost importance for high-areal-capacity lithium-sulfur (Li-S) batteries. Herein, multi-functional nanowall arrays (MNWAs) combining the aforementioned properties are fabricated to improve the electrochemical performance of Li-S batteries with high areal sulfur loadings. The integrated conductive networks and top-down vertically aligned Li+ transport channels are beneficial to Li+/e(-) transport, resulting in high rate performance with a discharge capacity of 620 mA h g(-1) at a high current density of 9.6 mA cm(-2) for 4 mg cm(-2) sulfur-loaded S/MNWA electrodes. Additionally, the strong PS shuttling suppression via the synergetic effects of physical confinement and chemical adsorption leads to Li-S batteries with a sulfur loading of 10 mg cm(-2) capable of delivering a high areal capacity of 12.4 mA h cm(-2) with a high capacity retention of nearly 85% for over 100 cycles. What's more, the Li-S batteries assembled with 4 mg cm(-2) sulfur-loaded S/MNWA electrodes show an ultra-low capacity decay of 0.07% per cycle over 400 cycles at 3.2 mA cm(-2).
Language英语
Funding OrganizationNatural Science and Engineering Research Council of Canada (NSERC) ; Natural Science and Engineering Research Council of Canada (NSERC) ; Canada Research Chair Program (CRC) ; Canada Research Chair Program (CRC) ; Canada Foundation for Innovation (CFI) ; Canada Foundation for Innovation (CFI) ; University of Western Ontario (UWO) ; University of Western Ontario (UWO) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; Natural Sciences Foundation of Liaoning Province of China ; Natural Sciences Foundation of Liaoning Province of China ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; China Scholarship Council ; China Scholarship Council ; Natural Science and Engineering Research Council of Canada (NSERC) ; Natural Science and Engineering Research Council of Canada (NSERC) ; Canada Research Chair Program (CRC) ; Canada Research Chair Program (CRC) ; Canada Foundation for Innovation (CFI) ; Canada Foundation for Innovation (CFI) ; University of Western Ontario (UWO) ; University of Western Ontario (UWO) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; Natural Sciences Foundation of Liaoning Province of China ; Natural Sciences Foundation of Liaoning Province of China ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; China Scholarship Council ; China Scholarship Council ; Natural Science and Engineering Research Council of Canada (NSERC) ; Natural Science and Engineering Research Council of Canada (NSERC) ; Canada Research Chair Program (CRC) ; Canada Research Chair Program (CRC) ; Canada Foundation for Innovation (CFI) ; Canada Foundation for Innovation (CFI) ; University of Western Ontario (UWO) ; University of Western Ontario (UWO) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; Natural Sciences Foundation of Liaoning Province of China ; Natural Sciences Foundation of Liaoning Province of China ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; China Scholarship Council ; China Scholarship Council ; Natural Science and Engineering Research Council of Canada (NSERC) ; Natural Science and Engineering Research Council of Canada (NSERC) ; Canada Research Chair Program (CRC) ; Canada Research Chair Program (CRC) ; Canada Foundation for Innovation (CFI) ; Canada Foundation for Innovation (CFI) ; University of Western Ontario (UWO) ; University of Western Ontario (UWO) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Youth Innovation Promotion Association ; Youth Innovation Promotion Association ; Natural Sciences Foundation of Liaoning Province of China ; Natural Sciences Foundation of Liaoning Province of China ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; Youth Innovation Foundation of the Dalian Institute of Chemical Physics ; China Scholarship Council ; China Scholarship Council
WOS IDWOS:000451738200061
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166515
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhang, Hongzhang; Zhang, Huamin; Sun, Xueliang
Affiliation1.Univ Western Ontario, Dept Mech & Mat Engn, London, ON N6A 5B9, Canada
2.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
4.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Yang, Xiaofei,Yu, Ying,Lin, Xiaoting,et al. Multi- functional nanowall arrays with unrestricted Li plus transport channels and an integrated conductive network for high- areal- capacity Li- S batteries[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(45):22958-22965.
APA Yang, Xiaofei.,Yu, Ying.,Lin, Xiaoting.,Liang, Jianneng.,Adair, Keegan.,...&Sun, Xueliang.(2018).Multi- functional nanowall arrays with unrestricted Li plus transport channels and an integrated conductive network for high- areal- capacity Li- S batteries.JOURNAL OF MATERIALS CHEMISTRY A,6(45),22958-22965.
MLA Yang, Xiaofei,et al."Multi- functional nanowall arrays with unrestricted Li plus transport channels and an integrated conductive network for high- areal- capacity Li- S batteries".JOURNAL OF MATERIALS CHEMISTRY A 6.45(2018):22958-22965.
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