DICP OpenIR
Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications
Zhang, Jiangwei1,2,3; Huang, Yichao1; Li, Gao2,3; Wei, Yongge1
Corresponding AuthorLi, Gao(gaoli@dicp.ac.cn) ; Wei, Yongge(yonggewei@mail.tsinghua.edu.cn)
KeywordPolyoxometalates POMs-based materials Alkoxylation Organic functionalization Tris ligands
Source PublicationCOORDINATION CHEMISTRY REVIEWS
2019
ISSN0010-8545
DOI10.1016/j.ccr.2017.10.025
Volume378Pages:395-414
Funding ProjectNational Natural Science Foundation of China (NSFC)[21471087] ; National Natural Science Foundation of China (NSFC)[21631007] ; National Natural Science Foundation of China (NSFC)[21225103] ; National Natural Science Foundation of China (NSFC)[21701168] ; Liaoning Natural Science Foundation[20170540897] ; fund of the Thousand Youth Talents Plan
Funding OrganizationNational Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan
WOS SubjectChemistry, Inorganic & Nuclear
WOS Research AreaChemistry
WOS KeywordANDERSON-TYPE POLYOXOMETALATE ; MIXED-VALENCE ; ORGANIC HYBRID ; POST-FUNCTIONALIZATION ; HETEROGENEOUS CATALYSTS ; ORGANOIMIDO DERIVATIVES ; CONTROLLABLE SYNTHESIS ; ASSISTED SYNTHESIS ; HEXAMETALATE CORE ; BUILDING-BLOCKS
AbstractPolyoxometalates (POMs), an exceptional family of coordination clusters consisting of Mo, W, V, etc. early transition metal ions in their highest oxidation states, have received significant attention over recent years due to their structural versatility and unique and diverse chemical and physical properties. The functionalization of POMs with organic ligands provides a novel strategy to precisely incorporate POMs with advanced functional organic moieties on their surfaces and enhance their compatibility in organic media. Among the various organically functionalized synthetic strategies for POM-based organic-inorganic hybrid materials, alkoxylation of POMs stands for one of the hottest topics during the past decades, since the diverse and tunable alkoxyl ligands are able to anchor on the surface of many POMs clusters, forming novel and flexible organically functionalized POM clusters, which can be further exploited as building blocks to design various functionalized POM-based hybrids with charming catalytic properties, and biomedicine, energy, or functional materials applications. In this review, recent advances in alkoxylation chemistry of POMs from synthetic strategies, structural overviews to their functional applications have been discussed. (C) 2017 Elsevier B.V. All rights reserved.
Language英语
Funding OrganizationNational Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan
WOS IDWOS:000451498300022
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:26[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166575
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi, Gao; Wei, Yongge
Affiliation1.Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Gold Catalysis Res Ctr, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Jiangwei,Huang, Yichao,Li, Gao,et al. Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications[J]. COORDINATION CHEMISTRY REVIEWS,2019,378:395-414.
APA Zhang, Jiangwei,Huang, Yichao,Li, Gao,&Wei, Yongge.(2019).Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications.COORDINATION CHEMISTRY REVIEWS,378,395-414.
MLA Zhang, Jiangwei,et al."Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications".COORDINATION CHEMISTRY REVIEWS 378(2019):395-414.
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