DICP OpenIR
Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials
Lin, Yangming1,2; Sun, Xiaoyan2; Su, Dang Sheng2,3; Centi, Gabriele4,5; Perathoner, Siglinda6
Corresponding AuthorLin, Yangming(yang-ming.lin@cec.mpg.de) ; Su, Dang Sheng(dssu@dicp.ac.cn) ; Perathoner, Siglinda(perathon@unime.it)
Source PublicationCHEMICAL SOCIETY REVIEWS
2018-11-21
ISSN0306-0012
DOI10.1039/c8cs00684a
Volume47Issue:22Pages:8438-8473
Funding ProjectStrategic Priority Research Program of the Chinese Academy of Sciences[XDA09030103] ; Italian MIUR through the PRIN Project[2015K7FZLH SMARTNESS] ; Max Planck Society
Funding OrganizationStrategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Italian MIUR through the PRIN Project ; Italian MIUR through the PRIN Project ; Max Planck Society ; Max Planck Society ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Italian MIUR through the PRIN Project ; Italian MIUR through the PRIN Project ; Max Planck Society ; Max Planck Society ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Italian MIUR through the PRIN Project ; Italian MIUR through the PRIN Project ; Max Planck Society ; Max Planck Society ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Italian MIUR through the PRIN Project ; Italian MIUR through the PRIN Project ; Max Planck Society ; Max Planck Society
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordOXYGEN REDUCTION REACTION ; METAL-FREE CATALYSTS ; ONION-LIKE CARBON ; OXIDATIVE DEHYDROGENATION REACTIONS ; GRAPHENE-BASED MATERIALS ; NITROGEN-DOPED GRAPHENE ; ELECTROCHEMICAL ENERGY-STORAGE ; MODIFIED ANNEALED NANODIAMOND ; STEAM-FREE DEHYDROGENATION ; HETEROGENEOUS CATALYSIS
AbstractHybrid sp(2)/sp(3) nanocarbons, in particular sp(3)-hybridized ultra-dispersed nanodiamonds and derivative materials, such as the sp(3)/sp(2)-hybridized bucky nanodiamonds and sp(2)-hybridized onion-like carbons, represent a rather interesting class of catalysts still under consideration. Their characteristics, properties and catalytic reactivity are presented, with an analysis of the state-of-the-art of their use in gas- and liquid-phase reactions, including photo- and electro-catalysis. It is remarked that intrinsic differences exist between these and other nanostructured carbon catalysts. The analysis shows how different features make nanocarbons unique with respect to other types of catalysts and are the bases for an advanced design of nanocarbon-type catalysts. The aspects discussed regard the presence of hybrid sp(2)/sp(3) configurations, nano-engineering related to the role of defects and vacancies in their catalytic behaviour, the creation of active sites by modification in the charge density at carbon atoms or C-C bonds, the generation of strained C-C bonds by curvature and other mechanisms, and the formation of semiconducting areas and defect sites at the interface with supported nanoparticles. The advanced strategies for identifying and quantifying active sites of carbon catalysts are highlighted.
Language英语
Funding OrganizationStrategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Italian MIUR through the PRIN Project ; Italian MIUR through the PRIN Project ; Max Planck Society ; Max Planck Society ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Italian MIUR through the PRIN Project ; Italian MIUR through the PRIN Project ; Max Planck Society ; Max Planck Society ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Italian MIUR through the PRIN Project ; Italian MIUR through the PRIN Project ; Max Planck Society ; Max Planck Society ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Italian MIUR through the PRIN Project ; Italian MIUR through the PRIN Project ; Max Planck Society ; Max Planck Society
WOS IDWOS:000449968700008
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166645
Collection中国科学院大连化学物理研究所
Corresponding AuthorLin, Yangming; Su, Dang Sheng; Perathoner, Siglinda
Affiliation1.Max Planck Inst Chem Energiekonvers, Stiftstr 34-36, D-45470 Mulheim, Germany
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian, Peoples R China
4.Univ Messina, ERIC Aisbl, Vle F Stagno DAlcontres 31, I-98166 Messina, Italy
5.CASPE INSTM, Depts MIFT Ind Chem, Vle F Stagno DAlcontres 31, I-98166 Messina, Italy
6.Univ Messina, Depts ChiBioFarAm Ind Chem, Vle F Stagno DAlcontres 31, I-98166 Messina, Italy
Recommended Citation
GB/T 7714
Lin, Yangming,Sun, Xiaoyan,Su, Dang Sheng,et al. Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials[J]. CHEMICAL SOCIETY REVIEWS,2018,47(22):8438-8473.
APA Lin, Yangming,Sun, Xiaoyan,Su, Dang Sheng,Centi, Gabriele,&Perathoner, Siglinda.(2018).Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials.CHEMICAL SOCIETY REVIEWS,47(22),8438-8473.
MLA Lin, Yangming,et al."Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials".CHEMICAL SOCIETY REVIEWS 47.22(2018):8438-8473.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Lin, Yangming]'s Articles
[Sun, Xiaoyan]'s Articles
[Su, Dang Sheng]'s Articles
Baidu academic
Similar articles in Baidu academic
[Lin, Yangming]'s Articles
[Sun, Xiaoyan]'s Articles
[Su, Dang Sheng]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Lin, Yangming]'s Articles
[Sun, Xiaoyan]'s Articles
[Su, Dang Sheng]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.