DICP OpenIR
Facile construction of hydrogenated azepino[3,2,1-hi]indoles by Rh(iii)-catalyzed C-H activation/[5+2] annulation of N-cyanoacetylindolines with sulfoxonium ylides
Hu, Panjie1; Zhang, Ying1; Liu, Bingxian1; Li, Xingwei1,2
Corresponding AuthorLiu, Bingxian(liubx1120@163.com) ; Li, Xingwei(xwli@dicp.ac.cn)
Source PublicationORGANIC CHEMISTRY FRONTIERS
2018-11-21
ISSN2052-4129
DOI10.1039/c8qo00861b
Volume5Issue:22Pages:3263-3266
Funding ProjectNSFC[21525208] ; NSFC[21472186] ; Henan Normal University[5101034011009] ; Henan Normal University[qd16111]
Funding OrganizationNSFC ; NSFC ; Henan Normal University ; Henan Normal University ; NSFC ; NSFC ; Henan Normal University ; Henan Normal University ; NSFC ; NSFC ; Henan Normal University ; Henan Normal University ; NSFC ; NSFC ; Henan Normal University ; Henan Normal University
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordCASCADE OXIDATIVE ANNULATION ; ALPHA,BETA-UNSATURATED ALDEHYDES ; BOND FUNCTIONALIZATION ; INTERNAL ALKYNES ; ACTIVATION ; ARENES ; DERIVATIVES ; CYCLIZATION ; CLEAVAGE ; KETONES
AbstractRhodium(iii)-catalyzed regio- and chemoselective [5 + 2] annulation between N-(cyanoacetyl)indolines and sulfoxonium ylides has been realized, leading to efficient construction of seven-membered rings under mild conditions. This reaction proceeded via C-H activation with sulfoxonium ylides as carbene synthons.
Language英语
Funding OrganizationNSFC ; NSFC ; Henan Normal University ; Henan Normal University ; NSFC ; NSFC ; Henan Normal University ; Henan Normal University ; NSFC ; NSFC ; Henan Normal University ; Henan Normal University ; NSFC ; NSFC ; Henan Normal University ; Henan Normal University
WOS IDWOS:000449412800010
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166667
Collection中国科学院大连化学物理研究所
Corresponding AuthorLiu, Bingxian; Li, Xingwei
Affiliation1.Henan Normal Univ, Henan Key Lab Organ Funct Mol & Drug Innovat, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Hu, Panjie,Zhang, Ying,Liu, Bingxian,et al. Facile construction of hydrogenated azepino[3,2,1-hi]indoles by Rh(iii)-catalyzed C-H activation/[5+2] annulation of N-cyanoacetylindolines with sulfoxonium ylides[J]. ORGANIC CHEMISTRY FRONTIERS,2018,5(22):3263-3266.
APA Hu, Panjie,Zhang, Ying,Liu, Bingxian,&Li, Xingwei.(2018).Facile construction of hydrogenated azepino[3,2,1-hi]indoles by Rh(iii)-catalyzed C-H activation/[5+2] annulation of N-cyanoacetylindolines with sulfoxonium ylides.ORGANIC CHEMISTRY FRONTIERS,5(22),3263-3266.
MLA Hu, Panjie,et al."Facile construction of hydrogenated azepino[3,2,1-hi]indoles by Rh(iii)-catalyzed C-H activation/[5+2] annulation of N-cyanoacetylindolines with sulfoxonium ylides".ORGANIC CHEMISTRY FRONTIERS 5.22(2018):3263-3266.
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