DICP OpenIR
Organocopper(III) Compounds with Well-defined Structures Undergo Reductive Elimination to Form C-C or C-Heteroatom Bonds
Liu, Liang; Xi, Zhenfeng
Corresponding AuthorLiu, Liang(liang.liu@pku.edu.cn) ; Xi, Zhenfeng(zfxi@pku.edu.cn)
Keywordstructure elucidation copper reactive intermediate organocopper(III) organocuprate(III) reductive elimination
Source PublicationCHINESE JOURNAL OF CHEMISTRY
2018-12-01
ISSN1001-604X
DOI10.1002/cjoc.201800365
Volume36Issue:12Pages:1213-1221
Funding ProjectNational Natural Science Foundation of China[21690061]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordTRANSITION-METAL-COMPLEXES ; CROSS-COUPLING REACTIONS ; N-CONFUSED PORPHYRINS ; RAPID INJECTION NMR ; X-RAY-STRUCTURE ; H BOND ; TRIFLUOROMETHYL COMPLEXES ; CONJUGATE ADDITION ; CATALYTIC CYCLE ; COPPER(III) INTERMEDIATE
AbstractReductive elimination around Cu(III) atom arises an increasing attention, since this organometallic pathway has been often proposed in a range of Cu-based reactions. However, due to limited organocopper(III) compounds with well-defined structures, this elementary reaction still remains an extremely challenging issue. In this review, structurally well-defined organocopper(III) compounds are mainly divided into three classes based on their ligands: perfluoromethyl Cu(III) compounds, macrocyclic ligand-based aryl-Cu(III) compounds, and spiro organocopper(III) compounds chelated by bidentate ligands. The majority of organocopper(III) compounds display the typical square planar geometry. There also exist a few penta-coordinated organocopper(III) complexes, which share a weak apical Cu-L bond. In order to form a cis Cu(III)-C and Cu(III)-Nu bonding geometry required for reductive elimination, the re-arrangement of coordination modes around tetra-coordinated Cu(III) atoms is necessary. For the aryl-Cu(III) cationic complexes with one Cu(III)-C bond, the re-arrangement is triggered by the coordination of the fifth ligand (solvent or nucleophiles), while for the tetra-carbon-coordinated organocuprate(III) compounds, the process might be realized via the cleavage of one Cu(III)-C bond by attack of electrophiles. Stoichiometric and catalytic reactions involving well-defined organocopper(III) compounds to form C-C or C-heteroatom bonds are discussed to support their intermediacy.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China
WOS IDWOS:000450017200020
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166689
Collection中国科学院大连化学物理研究所
Corresponding AuthorLiu, Liang; Xi, Zhenfeng
AffiliationPeking Univ, Key Lab Bioorgan Chem & Mol Engn, BNLMS, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Liu, Liang,Xi, Zhenfeng. Organocopper(III) Compounds with Well-defined Structures Undergo Reductive Elimination to Form C-C or C-Heteroatom Bonds[J]. CHINESE JOURNAL OF CHEMISTRY,2018,36(12):1213-1221.
APA Liu, Liang,&Xi, Zhenfeng.(2018).Organocopper(III) Compounds with Well-defined Structures Undergo Reductive Elimination to Form C-C or C-Heteroatom Bonds.CHINESE JOURNAL OF CHEMISTRY,36(12),1213-1221.
MLA Liu, Liang,et al."Organocopper(III) Compounds with Well-defined Structures Undergo Reductive Elimination to Form C-C or C-Heteroatom Bonds".CHINESE JOURNAL OF CHEMISTRY 36.12(2018):1213-1221.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, Liang]'s Articles
[Xi, Zhenfeng]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, Liang]'s Articles
[Xi, Zhenfeng]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, Liang]'s Articles
[Xi, Zhenfeng]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.