DICP OpenIR
Controllable and scalable synthesis of hollow-structured porous aromatic polymer for selective adsorption and separation of HMF from reaction mixture of fructose dehydration
Zhang, Yuan-Bao1; Luo, Qun-Xing1; Lu, Mei-Heng2,4; Luo, Dan1; Liu, Zhong-Wen1; Liu, Zhao-Tie1,3
Corresponding AuthorLuo, Qun-Xing(qxluo@snnu.edu.cn)
Keyword5-Hydroxymethylfurfural Fructose dehydration Hollow porous aromatic polymer Adsorptive separation pi-pi interaction
Source PublicationCHEMICAL ENGINEERING JOURNAL
2019-02-15
ISSN1385-8947
DOI10.1016/j.cej.2018.10.029
Volume358Pages:467-479
Funding ProjectNational Natural Science Foundation of China[21706155] ; National Natural Science Foundation of China[21776170] ; Program for Changjiang Scholars and Innovative Research Team in University[IRT_14R33] ; China Postdoctoral Science Foundation[2016M600762] ; Postdoctoral Science Foundation of Shaanxi Province[2017BSHEDZZ52]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Postdoctoral Science Foundation of Shaanxi Province ; Postdoctoral Science Foundation of Shaanxi Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Postdoctoral Science Foundation of Shaanxi Province ; Postdoctoral Science Foundation of Shaanxi Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Postdoctoral Science Foundation of Shaanxi Province ; Postdoctoral Science Foundation of Shaanxi Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Postdoctoral Science Foundation of Shaanxi Province ; Postdoctoral Science Foundation of Shaanxi Province
WOS SubjectEngineering, Environmental ; Engineering, Chemical
WOS Research AreaEngineering
WOS KeywordLIQUID-PHASE ADSORPTION ; CONJUGATED MICROPOROUS POLYMER ; RENEWABLE CHEMICALS INDUSTRY ; GENERAL TREATMENT ; RECOVERY ; BIOMASS ; CLASSIFICATION ; SYSTEMS ; CARBON ; SUGAR
AbstractThe hollow-structured porous aromatic polymers (H-PAP) with cavity diameter from 228 +/- 11 to 464 +/- 15 nm were controllably prepared through surface coating and template-etching method under scalable synthesis conditions from standard scale to 20-fold scale-up. It is found that the fill factor (f) of reactor is an important parameter for determining the scalability of synthesis. Benefiting from the favorable textural properties, chemical and thermal stability, surface hydrophobicity and pi electrons, the well-developed H-PAP as adsorbent was investigated in selective adsorption of 5-hydroxymethylfurfural (HMF) under static batch mode from the single-component and multi-component aqueous solutions. The H-PAP shows an exclusive adsorption for HMF, without adsorption of fructose, levulinic acid (LA) and formic acid (FA), and can be recycled three times without significant decrease in adsorption capacity. Structure-performance relationship points out that the apparent amount of HMF adsorbed on H-PAP is related to micropore surface area, micropore volume and cavity diameter, while HMF selectivity depends on surface hydrophobicity. In the case of HMF adsorption from the real reaction mixture of acid-catalyzed fructose dehydration, the HMF constituent with high purity (ca.94.4%) can be recovered. Combining the adsorption isotherms with DFT calculation reveals adsorption mechanism that HMF adsorption on H-PAP proceeds initially via pi -pi stacking interaction, and then assembles into regular array around spherical surface to form monolayer coverage following modified Langmuir model, and finally diffuses into interior cavity until adsorption saturation.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Postdoctoral Science Foundation of Shaanxi Province ; Postdoctoral Science Foundation of Shaanxi Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Postdoctoral Science Foundation of Shaanxi Province ; Postdoctoral Science Foundation of Shaanxi Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Postdoctoral Science Foundation of Shaanxi Province ; Postdoctoral Science Foundation of Shaanxi Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program for Changjiang Scholars and Innovative Research Team in University ; Program for Changjiang Scholars and Innovative Research Team in University ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; Postdoctoral Science Foundation of Shaanxi Province ; Postdoctoral Science Foundation of Shaanxi Province
WOS IDWOS:000450105700046
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166719
Collection中国科学院大连化学物理研究所
Corresponding AuthorLuo, Qun-Xing
Affiliation1.Shaanxi Normal Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710119, Shaanxi, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
3.Shaanxi Univ Sci & Technol, Coll Chem & Chem Engn, Xian 710021, Shaanxi, Peoples R China
4.Shenyang Univ Chem Technol, Coll Appl Chem, Shenyang 110142, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Yuan-Bao,Luo, Qun-Xing,Lu, Mei-Heng,et al. Controllable and scalable synthesis of hollow-structured porous aromatic polymer for selective adsorption and separation of HMF from reaction mixture of fructose dehydration[J]. CHEMICAL ENGINEERING JOURNAL,2019,358:467-479.
APA Zhang, Yuan-Bao,Luo, Qun-Xing,Lu, Mei-Heng,Luo, Dan,Liu, Zhong-Wen,&Liu, Zhao-Tie.(2019).Controllable and scalable synthesis of hollow-structured porous aromatic polymer for selective adsorption and separation of HMF from reaction mixture of fructose dehydration.CHEMICAL ENGINEERING JOURNAL,358,467-479.
MLA Zhang, Yuan-Bao,et al."Controllable and scalable synthesis of hollow-structured porous aromatic polymer for selective adsorption and separation of HMF from reaction mixture of fructose dehydration".CHEMICAL ENGINEERING JOURNAL 358(2019):467-479.
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