DICP OpenIR
Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity
Liu, Jiayi1,5; Li, Xuning1; Liu, Biao2; Zhao, Chunxiao1,4; Kuang, Zhichong1,5; Hu, Ruisheng4; Liu, Bin3; Ao, Zhimin2; Wang, Junhu1
Corresponding AuthorLiu, Bin(LiuBin@ntu.edu.sg) ; Ao, Zhimin(zhimin.ao@gdut.edu.cn) ; Wang, Junhu(wangjh@dicp.ac.cn)
Keywordsecondary building units shape-controlled Prussian blue analogue DFT calculation Fenton reaction
Source PublicationACS APPLIED MATERIALS & INTERFACES
2018-11-07
ISSN1944-8244
DOI10.1021/acsami.8b12686
Volume10Issue:44Pages:38051-38056
Funding ProjectNational Natural Science Foundation of China[21476232] ; National Natural Science Foundation of China[21607029] ; National Natural Science Foundation of China[21777033] ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics[N-16-07] ; China Ministry of Science and Technology[2016YFA0202804] ; Science and Technology Program of Guangdong Province[2017B020216003] ; Science and Technology Program of Guangzhou City[201707010359] ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology
WOS SubjectNanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS Research AreaScience & Technology - Other Topics ; Materials Science
WOS KeywordPRUSSIAN BLUE ANALOGS ; POROUS COORDINATION POLYMERS ; BISPHENOL-A ; HYDROGEN STORAGE ; CO ; PEROXYMONOSULFATE ; DEGRADATION ; FE ; ACTIVATION ; MECHANISM
AbstractControllable synthesis of metal-organic frameworks with well-defined morphology, composition, and size is of great importance toward understanding their structure-property relationship in various applications. Herein, we demonstrate a general strategy to modulate the relative growth rate of the secondary building units (SBUs) along different crystal facets for the synthesis of Fe-Co, Mn0.5Fe0.5-Co, and Mn-Co Prussian blue analogues (PBAs) with tunable morphologies. The same growth rate of SBUs along the {100}, {110}, and {111} surfaces at 0 degrees C results in the formation of spherical PBA particles, while the lowest growth rate of SBUs along the {100} surface resulting from the highest surface energy with increasing reaction temperature induces the formation of PBA cubes. Fenton reaction was used as the model reaction to probe the structure-catalytic activity relation for the as-synthesized catalysts. The cubic Fe-Co PBA was found to exhibit the best catalytic performance with reaction rate constant 6 times higher than that of the spherical counterpart. Via density functional theory calculations, the abundant enclosed {100} facets in cubic Fe-Co PBA were identified to have the highest surface energy and favor high Fenton reaction activity.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology
WOS IDWOS:000449887600031
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166723
Collection中国科学院大连化学物理研究所
Corresponding AuthorLiu, Bin; Ao, Zhimin; Wang, Junhu
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116023, Peoples R China
2.Guangdong Univ Technol, Sch Environm Sci & Engn, Inst Environm Hlth & Pollut Control, Guangzhou Key Lab Environm Catalysis & Pollut Con, Guangzhou 510006, Guangdong, Peoples R China
3.Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore
4.Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China
5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Liu, Jiayi,Li, Xuning,Liu, Biao,et al. Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(44):38051-38056.
APA Liu, Jiayi.,Li, Xuning.,Liu, Biao.,Zhao, Chunxiao.,Kuang, Zhichong.,...&Wang, Junhu.(2018).Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity.ACS APPLIED MATERIALS & INTERFACES,10(44),38051-38056.
MLA Liu, Jiayi,et al."Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity".ACS APPLIED MATERIALS & INTERFACES 10.44(2018):38051-38056.
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