DICP OpenIR
Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes
Lei, Xin1,2; Kong, Xiangtao1; Zhao, Zhi1; Zhang, Bingbing1,2; Dai, Dongxu1; Yang, Xueming1; Jiang, Ling1
Corresponding AuthorJiang, Ling(ljiang@dicp.ac.cn)
Source PublicationPHYSICAL CHEMISTRY CHEMICAL PHYSICS
2018-10-28
ISSN1463-9076
DOI10.1039/c8cp03672a
Volume20Issue:40Pages:9
Funding ProjectNational Natural Science Foundation of China[21673231] ; National Natural Science Foundation of China[21688102] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17000000] ; Hundred Talents Program of Chinese Academy of Sciences
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS KeywordPHOTOELECTRON-SPECTROSCOPY ; VIBRATIONAL SPECTROSCOPY ; BONDED CLUSTERS ; DIMER ; ANION ; NUCLEATION ; MOLECULES ; CHEMISTRY ; DIANIONS ; SPECTRUM
AbstractCryogenic ion-trap infrared photodissociation spectroscopy combined with a dielectric barrier discharge source was constructed to establish the general trends in the stepwise growth motif of trimethylamine (TMA)(n)(+) complexes. The results showed a strong preference for the formation of a stable charge-shared NN type (TMA)(2)(+) ion core over the proton-transferred CHN type ion core, evidencing that the source condition has a remarkable effect on the kinetic stability of isomers. A maximum of four TMA molecules are located perpendicularly to the NN axis of the charge-shared (TMA)(2)(+) ion core. In the n = 7 and 8 clusters, the subsequent two TMA molecules are located at each end of the NN axis of the (TMA)(2)(+) ion core, completing the first coordination shell. Starting at n = 9, the additional TMA molecules form a second solvation shell, and the cluster spectra show similarities to the solution phase spectrum of aqueous TMA.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences ; Hundred Talents Program of Chinese Academy of Sciences
WOS IDWOS:000448345800003
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166765
Collection中国科学院大连化学物理研究所
Corresponding AuthorJiang, Ling
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Lei, Xin,Kong, Xiangtao,Zhao, Zhi,et al. Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2018,20(40):9.
APA Lei, Xin.,Kong, Xiangtao.,Zhao, Zhi.,Zhang, Bingbing.,Dai, Dongxu.,...&Jiang, Ling.(2018).Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,20(40),9.
MLA Lei, Xin,et al."Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 20.40(2018):9.
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