DICP OpenIR
Structural and bonding properties of BS-/0 and BS3-/0
Zhao, Li-Juan1; Xu, Xi-Ling1; Xu, Hong-Guang1; Feng, Gang2; Zheng, Wei-Jun1,3
Corresponding AuthorXu, Xi-Ling(xlxu@iccas.ac.cn) ; Zheng, Wei-Jun(zhengwj@iccas.ac.cn)
Source PublicationNEW JOURNAL OF CHEMISTRY
2018-10-07
ISSN1144-0546
DOI10.1039/c8nj01835a
Volume42Issue:19Pages:16021-16026
Funding ProjectNational Natural Science Foundation of China[21303214] ; Chinese Academy of Sciences[QYZDB-SSW-SLH024]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordWEIGHT BORON SULFIDES ; PHOTOELECTRON-SPECTROSCOPY ; THEORETICAL CALCULATIONS ; ELECTRONIC-STRUCTURE ; AB-INITIO ; BS2 ; SPECTRUM ; CLUSTERS ; COMPLEXES ; DENSITY
AbstractAnion photoelectron spectroscopy and theoretical calculations were used to investigate the structural, electronic, and bonding properties of BS- and BS3-. Vibrationally resolved photoelectron spectra of BS- at 355 nm and 266 nm were obtained. The electron affinity of BS is determined to be 2.32 +/- 0.05 eV. The stretching vibrational frequencies of BS- and BS were measured to be 968 cm(-1) and 1210 cm(-1), respectively. The results indicate that the B-S bond in BS-/0 can be characterized as a triple bond. The B-S bond in neutral BS is stronger than that in anionic BS-. The most stable isomer of BS3- has a C-2v symmetric planar structure with the B atom at the center interacting with the three S atoms, while that of neutral BS3 has a S-B-S-S bent structure.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences
WOS IDWOS:000447971700059
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166773
Collection中国科学院大连化学物理研究所
Corresponding AuthorXu, Xi-Ling; Zheng, Wei-Jun
Affiliation1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chongqing Univ, Sch Chem & Chem Engn, Chongqing 401331, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Li-Juan,Xu, Xi-Ling,Xu, Hong-Guang,et al. Structural and bonding properties of BS-/0 and BS3-/0[J]. NEW JOURNAL OF CHEMISTRY,2018,42(19):16021-16026.
APA Zhao, Li-Juan,Xu, Xi-Ling,Xu, Hong-Guang,Feng, Gang,&Zheng, Wei-Jun.(2018).Structural and bonding properties of BS-/0 and BS3-/0.NEW JOURNAL OF CHEMISTRY,42(19),16021-16026.
MLA Zhao, Li-Juan,et al."Structural and bonding properties of BS-/0 and BS3-/0".NEW JOURNAL OF CHEMISTRY 42.19(2018):16021-16026.
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