DICP OpenIR
C-C Bonds Cleavage of Biomass-Derived Glycerol to Methane and Ethylene Glycol in Aqueous Phase Over Highly Dispersed Ru-Based Catalysts
Huang, Qian-Qian1,2; Yu, Wei-Qiang1; Luo, Xiao-Lin1,2; Gao, Jin1; Xu, Jie1
Corresponding AuthorYu, Wei-Qiang(yuweiqiang@dicp.ac.cn) ; Xu, Jie(xujie@dicp.ac.cn)
Keywordcarbothermal reduction highly dispersed Ru NPs glycerol hydrogenolysis C-C bond cleavage
Source PublicationASIAN JOURNAL OF ORGANIC CHEMISTRY
2018-10-01
ISSN2193-5807
DOI10.1002/ajoc.201800505
Volume7Issue:10Pages:2039-2044
Funding ProjectNational Natural Science Foundation of China[21790331] ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration[XDA21030400] ; Dalian Young Star of Science and Technology Project[2017RQ115]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Dalian Young Star of Science and Technology Project ; Dalian Young Star of Science and Technology Project ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Dalian Young Star of Science and Technology Project ; Dalian Young Star of Science and Technology Project ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Dalian Young Star of Science and Technology Project ; Dalian Young Star of Science and Technology Project ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Dalian Young Star of Science and Technology Project ; Dalian Young Star of Science and Technology Project
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordORDERED MESOPOROUS CARBON ; FISCHER-TROPSCH SYNTHESIS ; METAL NANOPARTICLES ; NI CATALYSTS ; HYDROGENOLYSIS ; HYDROGENATION ; DEACTIVATION ; PERFORMANCE ; SUPPORT ; HYDRODEOXYGENATION
AbstractAn alternative method for the conversion of crude glycerol was proposed to produce renewable energy methane and high-value chemical ethylene glycol through preferential cleavage of C-C bonds, catalyzed by highly dispersed Ru-based catalysts prepared by carbothermal reduction. It was found that the Ru particles size could be tuned by adjusting the reduction temperature, and the size firstly decreased then increased with raising of the temperature of carbothermal reduction. This resulted in the opposite tendency of catalytic performance against the Ru particle sizes in hydrogenolysis of glycerol, in which the glycerol conversion and yield of C-C bond cleavage increased firstly and then decreased. Ru catalysts carbothermal reduced at 450 degrees C possessed highly dispersed Ru nanoparticles with uniform particle sizes about 1.0nm that showed high hydrogenation activity and selectivity of C-C bond cleavage as well as good stability that could be recycled in aqueous phase hydrogenolysis of glycerol.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Dalian Young Star of Science and Technology Project ; Dalian Young Star of Science and Technology Project ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Dalian Young Star of Science and Technology Project ; Dalian Young Star of Science and Technology Project ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Dalian Young Star of Science and Technology Project ; Dalian Young Star of Science and Technology Project ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Dalian Young Star of Science and Technology Project ; Dalian Young Star of Science and Technology Project
WOS IDWOS:000447542200009
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166785
Collection中国科学院大连化学物理研究所
Corresponding AuthorYu, Wei-Qiang; Xu, Jie
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Huang, Qian-Qian,Yu, Wei-Qiang,Luo, Xiao-Lin,et al. C-C Bonds Cleavage of Biomass-Derived Glycerol to Methane and Ethylene Glycol in Aqueous Phase Over Highly Dispersed Ru-Based Catalysts[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2018,7(10):2039-2044.
APA Huang, Qian-Qian,Yu, Wei-Qiang,Luo, Xiao-Lin,Gao, Jin,&Xu, Jie.(2018).C-C Bonds Cleavage of Biomass-Derived Glycerol to Methane and Ethylene Glycol in Aqueous Phase Over Highly Dispersed Ru-Based Catalysts.ASIAN JOURNAL OF ORGANIC CHEMISTRY,7(10),2039-2044.
MLA Huang, Qian-Qian,et al."C-C Bonds Cleavage of Biomass-Derived Glycerol to Methane and Ethylene Glycol in Aqueous Phase Over Highly Dispersed Ru-Based Catalysts".ASIAN JOURNAL OF ORGANIC CHEMISTRY 7.10(2018):2039-2044.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Huang, Qian-Qian]'s Articles
[Yu, Wei-Qiang]'s Articles
[Luo, Xiao-Lin]'s Articles
Baidu academic
Similar articles in Baidu academic
[Huang, Qian-Qian]'s Articles
[Yu, Wei-Qiang]'s Articles
[Luo, Xiao-Lin]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Huang, Qian-Qian]'s Articles
[Yu, Wei-Qiang]'s Articles
[Luo, Xiao-Lin]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.