DICP OpenIR
Li3Cr(MoO4)(3): a NASICON-type high specific capacity cathode material for lithium ion batteries
Feng, Kai1; Wang, Fuxiang1; Zhang, Hongzhang2,3; Li, Xianfeng2,3; Zhang, Huamin2,3
Corresponding AuthorZhang, Hongzhang(zhanghz@dicp.ac.cn) ; Li, Xianfeng(lixianfeng@dicp.ac.cn)
Source PublicationJOURNAL OF MATERIALS CHEMISTRY A
2018-10-21
ISSN2050-7488
DOI10.1039/c8ta07782g
Volume6Issue:39Pages:19107-19112
Funding ProjectNational Natural Science Foundation of China[21501171] ; National Natural Science Foundation of China[51403209] ; National Natural Science Foundation of China[51677176] ; National Natural Science Foundation of China[51673199] ; National Natural Science Foundation of China[21406221] ; Chinese Academy of Sciences[FCLT201602] ; Youth Innovation Promotion Association of CAS[2015148] ; Youth Innovation Foundation of DICP[ZZBS201615] ; Dalian Science and Technology Star Program[2016RQ026] ; Key Laboratory of Functional Crystals and Laser Technology ; Technical Institute of Physics and Chemistry
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Foundation of DICP ; Youth Innovation Foundation of DICP ; Dalian Science and Technology Star Program ; Dalian Science and Technology Star Program ; Key Laboratory of Functional Crystals and Laser Technology ; Key Laboratory of Functional Crystals and Laser Technology ; Technical Institute of Physics and Chemistry ; Technical Institute of Physics and Chemistry ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Foundation of DICP ; Youth Innovation Foundation of DICP ; Dalian Science and Technology Star Program ; Dalian Science and Technology Star Program ; Key Laboratory of Functional Crystals and Laser Technology ; Key Laboratory of Functional Crystals and Laser Technology ; Technical Institute of Physics and Chemistry ; Technical Institute of Physics and Chemistry ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Foundation of DICP ; Youth Innovation Foundation of DICP ; Dalian Science and Technology Star Program ; Dalian Science and Technology Star Program ; Key Laboratory of Functional Crystals and Laser Technology ; Key Laboratory of Functional Crystals and Laser Technology ; Technical Institute of Physics and Chemistry ; Technical Institute of Physics and Chemistry ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Foundation of DICP ; Youth Innovation Foundation of DICP ; Dalian Science and Technology Star Program ; Dalian Science and Technology Star Program ; Key Laboratory of Functional Crystals and Laser Technology ; Key Laboratory of Functional Crystals and Laser Technology ; Technical Institute of Physics and Chemistry ; Technical Institute of Physics and Chemistry
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Energy & Fuels ; Materials Science
WOS KeywordRECHARGEABLE BATTERIES ; INSERTION PROPERTIES ; POSITIVE-ELECTRODE ; LIFEPO4 ; DIFFUSION ; ENERGY ; LITI2(PO4)(3) ; TRANSITION ; STABILITY ; DEFECTS
AbstractMolybdate cathode materials have attracted a lot of attention due to their rich crystal structure, stable skeleton structure and moderate electronic conductivity. In this paper, a new NASICON-type material Li3Cr(MoO4)(3) has been studied for the first time as a cathode material for lithium ion batteries with high specific capacity. Comprehensive studies by X-ray diffraction, UV-vis-IR diffuse reflection, bond valence sum maps calculation, cyclic voltammetry, electrochemical impedance spectroscopy and the Four-Probe method show that Li3Cr(MoO4)(3) possesses a narrow band gap, high electronic conductivity and fast lithium ion transport channels, and delivers a high specific capacity (200 mA h g(-1)) and rate performance. Electrochemical mechanism studies indicate that both the Mo6+/5+ and Cr3+/Cr2+ reactions contribute to the high specific capacity.
Language英语
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Foundation of DICP ; Youth Innovation Foundation of DICP ; Dalian Science and Technology Star Program ; Dalian Science and Technology Star Program ; Key Laboratory of Functional Crystals and Laser Technology ; Key Laboratory of Functional Crystals and Laser Technology ; Technical Institute of Physics and Chemistry ; Technical Institute of Physics and Chemistry ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Foundation of DICP ; Youth Innovation Foundation of DICP ; Dalian Science and Technology Star Program ; Dalian Science and Technology Star Program ; Key Laboratory of Functional Crystals and Laser Technology ; Key Laboratory of Functional Crystals and Laser Technology ; Technical Institute of Physics and Chemistry ; Technical Institute of Physics and Chemistry ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Foundation of DICP ; Youth Innovation Foundation of DICP ; Dalian Science and Technology Star Program ; Dalian Science and Technology Star Program ; Key Laboratory of Functional Crystals and Laser Technology ; Key Laboratory of Functional Crystals and Laser Technology ; Technical Institute of Physics and Chemistry ; Technical Institute of Physics and Chemistry ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Foundation of DICP ; Youth Innovation Foundation of DICP ; Dalian Science and Technology Star Program ; Dalian Science and Technology Star Program ; Key Laboratory of Functional Crystals and Laser Technology ; Key Laboratory of Functional Crystals and Laser Technology ; Technical Institute of Physics and Chemistry ; Technical Institute of Physics and Chemistry
WOS IDWOS:000448412000039
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166789
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhang, Hongzhang; Li, Xianfeng
Affiliation1.Yantai Univ, Coll Chem & Engn, Shandong Collaborat Innovat Ctr Light Hydrocarbon, Yantai 264005, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Energy Storage, Zhongshan Rd 457, Dalian 116023, Peoples R China
3.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Feng, Kai,Wang, Fuxiang,Zhang, Hongzhang,et al. Li3Cr(MoO4)(3): a NASICON-type high specific capacity cathode material for lithium ion batteries[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(39):19107-19112.
APA Feng, Kai,Wang, Fuxiang,Zhang, Hongzhang,Li, Xianfeng,&Zhang, Huamin.(2018).Li3Cr(MoO4)(3): a NASICON-type high specific capacity cathode material for lithium ion batteries.JOURNAL OF MATERIALS CHEMISTRY A,6(39),19107-19112.
MLA Feng, Kai,et al."Li3Cr(MoO4)(3): a NASICON-type high specific capacity cathode material for lithium ion batteries".JOURNAL OF MATERIALS CHEMISTRY A 6.39(2018):19107-19112.
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