DICP OpenIR
Efficient synthesis of 5-hydroxymethylfurfural from mannose with a reusable MCM-41-supported tin catalyst
Jia, Songyan1; He, Xinjun1; Ma, Jiao1; Wang, Kangjun1; Xu, Zhanwei2; Zhang, Z. Conrad2
Corresponding AuthorJia, Songyan(jiasongyan@126.com) ; Zhang, Z. Conrad(zczhang@yahoo.com)
Source PublicationCATALYSIS SCIENCE & TECHNOLOGY
2018-11-07
ISSN2044-4753
DOI10.1039/c8cy01630e
Volume8Issue:21Pages:5526-5534
Funding ProjectNatural Science Foundation of Liaoning Province (China)[2015020633] ; Department of Education of Liaoning Province (China)[L2015421] ; National Natural Science Foundation of China[21306186] ; National Natural Science Foundation of China[21721004] ; National Natural Science Foundation of China[21706255] ; CAS/SAFEA International Partnership Program for Creative Research Teams
Funding OrganizationNatural Science Foundation of Liaoning Province (China) ; Natural Science Foundation of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Natural Science Foundation of Liaoning Province (China) ; Natural Science Foundation of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Natural Science Foundation of Liaoning Province (China) ; Natural Science Foundation of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Natural Science Foundation of Liaoning Province (China) ; Natural Science Foundation of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordALUMINUM SALT CATALYST ; IONIC LIQUID ; HETEROGENEOUS CATALYST ; ONE-POT ; SELECTIVE DEHYDRATION ; GLUCOSE CONVERSION ; ALDOL CONDENSATION ; MESOPOROUS MCM-41 ; LEVULINIC ACID ; CYCLIC-KETONES
AbstractThe synthesis of furan compounds by renewable carbohydrates has emerged as an important path toward biomass utilization. 5-Hydroxymethylfurfural (5-HMF) and furfural are two typical furan products from cellulosic and hemicellulosic materials, of which the primary components (hexoses and pentoses) undergo selective dehydration. It is worth noting that hemicellulose is rich in not only pentoses but also hexoses, indicating the feasibility of producing 5-HMF and furfural simultaneously. However, research on the production of 5-HMF from hemicellulose-derived hexoses remains lacking. Mannose, a major hexose component of hemicellulose, has been previously found to be a suitable feedstock for 5-HMF production in the presence of homogeneous catalysts, such as metal salts. In this work, Cr-, Al- and Sn/MCM-41 catalysts were prepared by a simple impregnation method and characterized. The conversion of mannose into 5-HMF was evaluated in dimethyl sulfoxide (DMSO) solvent. It was found that the as-synthesized Sn/MCM-41 catalyst showed a superior activity to Cr/MCM-41 and Al/MCM-41. Mannose could be effectively converted into 5-HMF with a yield of approximate to 45% and approximate to 88% conversion at 150 degrees C after 60 min, which were comparable to reported results over heterogeneous catalysts. The as-synthesized Sn/MCM-41 catalyst was also efficient for the conversion of glucose and fructose with reasonable 5-HMF yields. The Sn/MCM-41 catalyst could be reused for eight consecutive cycles without significant loss of catalytic activity.
Language英语
Funding OrganizationNatural Science Foundation of Liaoning Province (China) ; Natural Science Foundation of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Natural Science Foundation of Liaoning Province (China) ; Natural Science Foundation of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Natural Science Foundation of Liaoning Province (China) ; Natural Science Foundation of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Natural Science Foundation of Liaoning Province (China) ; Natural Science Foundation of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams
WOS IDWOS:000448661800016
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/166797
Collection中国科学院大连化学物理研究所
Corresponding AuthorJia, Songyan; Zhang, Z. Conrad
Affiliation1.Shenyang Univ Chem Technol, Coll Chem Engn, Shenyang 110142, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Jia, Songyan,He, Xinjun,Ma, Jiao,et al. Efficient synthesis of 5-hydroxymethylfurfural from mannose with a reusable MCM-41-supported tin catalyst[J]. CATALYSIS SCIENCE & TECHNOLOGY,2018,8(21):5526-5534.
APA Jia, Songyan,He, Xinjun,Ma, Jiao,Wang, Kangjun,Xu, Zhanwei,&Zhang, Z. Conrad.(2018).Efficient synthesis of 5-hydroxymethylfurfural from mannose with a reusable MCM-41-supported tin catalyst.CATALYSIS SCIENCE & TECHNOLOGY,8(21),5526-5534.
MLA Jia, Songyan,et al."Efficient synthesis of 5-hydroxymethylfurfural from mannose with a reusable MCM-41-supported tin catalyst".CATALYSIS SCIENCE & TECHNOLOGY 8.21(2018):5526-5534.
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